Chemical Properties of Ethyl formate (CAS 109-94-4)

InChI

InChI=1S/C3H6O2/c1-2-5-3-4/h3H,2H2,1H3

InChI Key

WBJINCZRORDGAQ-UHFFFAOYSA-N

Formula

C3H6O2

SMILES

CCOC=O

Molecular Weight¹

74.08

CAS

109-94-4

Other Names

• Aethylformiat
• Areginal
• Ethyl ester of formic acid
• Ethyle (formiate d')
• Ethylester kyseliny mravenci
• Ethylformiaat
• Ethylformic ester
• Etile (formiato di)
• Formic acid ethyl ester
• Formic ether
• HCOOC2H5
• Mrowczan etylu
• NSC 406578
• UN 1190
• ethyl methanoate
• formic acid, ethyl ester
• methanoic acid, ethyl ester

• ω : Acentric Factor.
• PAff : Proton affinity (kJ/mol).
• BasG : Gas basicity (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• μ : Dipole Moment (debye).
• η : Dynamic viscosity (Pa×s).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fH°_liquid : Liquid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• NFPA Fire : NFPA Fire Rating.
• NFPA Health : NFPA Health Rating.
• P_c : Critical Pressure (kPa).
• P_triple : Triple Point Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• n₀ : Refractive Index.
• ρ_c : Critical density (kg/m³).
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I_p : Polar retention indices.
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• λ_gas : Gas thermal conductivity (W/m×K).
• λ_liquid : Liquid thermal conductivity (W/m×K).
• T_fus : Normal melting (fusion) point (K).
• T_triple : Triple Point Temperature (K).
• U_Qi : UNIQUAC Qi Parameter.
• U_Ri : UNIQUAC Ri Parameter.
• V_c : Critical Volume (m³/kmol).
• Z_c : Critical Compressibility.
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	[0.2820; 0.2850]
ω	0.2830		PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
ω	0.2820		ChemSep v8.3 pure component data Compiled value
ω	0.2850		KDB
PAff	799.40	kJ/mol	NIST
BasG	768.40	kJ/mol	NIST
μ	[1.93; 2.00]	debye
μ	1.93	debye	ChemSep v8.3 pure component data Compiled value
μ	2.00	debye	KDB
η	0.0004000	Pa×s	Densities and Viscosities of 1-Butyl-3-methylimidazolium Tetrafluoroborate + Molecular Solvent Binary Mixtures
ΔfG°	-303.10	kJ/mol	ChemSep v8.3 pure component data Compiled value
ΔfH°gas	[-398.00; -361.70]	kJ/mol
ΔfH°gas	-388.30	kJ/mol	ChemSep v8.3 pure component data Compiled value
ΔfH°gas	-371.50	kJ/mol	KDB
ΔfH°gas	-361.70	kJ/mol	NIST
ΔfH°gas	-398.00	kJ/mol	NIST
ΔfH°liquid	[-430.50; -394.20]	kJ/mol
ΔfH°liquid	-394.20 ± 0.80	kJ/mol	NIST
ΔfH°liquid	-430.50	kJ/mol	NIST
ΔfusH°	9.58	kJ/mol	Joback Calculated Property
ΔvapH°	[30.10; 32.50]	kJ/mol
ΔvapH°	32.11	kJ/mol	NIST
ΔvapH°	32.20	kJ/mol	NIST
ΔvapH°	32.50	kJ/mol	NIST
ΔvapH°	30.10 ± 0.01	kJ/mol	NIST
IE	[10.61; 10.62]	eV
IE	10.61 ± 0.01	eV	NIST
IE	10.61 ± 0.05	eV	NIST
IE	10.61 ± 0.05	eV	NIST
IE	Outlier 10.62	eV	NIST
IE	10.61 ± 0.01	eV	NIST
IE	10.61	eV	NIST
log10WS	[0.15; 0.15]
log10WS	0.15		Aq. Solubility Prediction
log10WS	0.15		Estimated Solubility
logPoct/wat	0.179		Crippen Calculated Property
McVol	60.570	ml/mol	McGowan Calculated Property
NFPA Fire	3		KDB
NFPA Health	2		KDB
Pc	[4737.00; 4981.00]	kPa
Pc	4740.00	kPa	IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Pc	4742.01	kPa	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Pc	4740.00	kPa	ChemSep v8.3 pure component data Compiled value
Pc	4740.00	kPa	KDB
Pc	4738.00 ± 101.32	kPa	NIST
Pc	4737.00 ± 40.00	kPa	NIST
Pc	4981.00 ± 202.65	kPa	NIST
Pc	4930.00 ± 202.65	kPa	NIST
Ptriple	0.02	kPa	ChemSep v8.3 pure component data Compiled value
ρc	[314.83; 323.20]	kg/m3
ρc	323.20 ± 5.19	kg/m3	NIST
ρc	323.20 ± 3.70	kg/m3	NIST
ρc	314.83 ± 5.93	kg/m3	NIST
Inp	[455.00; 545.00]
Inp	457.00		NIST
Inp	501.00		NIST
Inp	463.00		NIST
Inp	474.00		NIST
Inp	465.00		NIST
Inp	469.00		NIST
Inp	468.00		NIST
Inp	495.00		NIST
Inp	456.00		NIST
Inp	487.00		NIST
Inp	455.00		NIST
Inp	468.00		NIST
Inp	495.00		NIST
Inp	481.00		NIST
Inp	530.00		NIST
Inp	481.00		NIST
Inp	530.00		NIST
Inp	502.00		NIST
Inp	504.00		NIST
Inp	502.00		NIST
Inp	478.00		NIST
Inp	500.00		NIST
Inp	530.00		NIST
Inp	495.00		NIST
Inp	510.00		NIST
Inp	495.00		NIST
Inp	530.00		NIST
Inp	495.00		NIST
Inp	487.00		NIST
Inp	521.00		NIST
Inp	502.00		NIST
Inp	502.00		NIST
Inp	521.00		NIST
Inp	Outlier 545.00		NIST
Inp	502.00		NIST
Inp	501.00		NIST
Inp	495.00		NIST
Inp	487.00		NIST
Inp	Outlier 545.00		NIST
Inp	502.00		NIST
Inp	481.00		NIST
Ip	[800.00; 849.10]
Ip	842.00		NIST
Ip	820.00		NIST
Ip	847.00		NIST
Ip	832.00		NIST
Ip	825.00		NIST
Ip	825.00		NIST
Ip	848.00		NIST
Ip	837.00		NIST
Ip	822.00		NIST
Ip	849.10		NIST
Ip	820.00		NIST
Ip	814.00		NIST
Ip	811.00		NIST
Ip	821.00		NIST
Ip	834.00		NIST
Ip	820.00		NIST
Ip	800.00		NIST
Ip	825.00		NIST
Ip	806.00		NIST
Ip	804.00		NIST
Ip	830.00		NIST
Ip	806.00		NIST
Ip	810.00		NIST
Ip	822.00		NIST
Ip	823.00		NIST
Ip	849.10		NIST
Tboil	[325.85; 328.15]	K
Tboil	327.33	K	Solutions of alkyl methanoates and alkanes: Simultaneous modeling of phase equilibria and mixing properties. Estimation of behavior by UNIFAC with recalculation of parameters
Tboil	327.29	K	Isobaric Vapor-Liquid Equilibria and Excess Quantities for Binary Mixtures of an Ethyl Ester + tert-Butanol and a New Approach to VLE Data Processing
Tboil	327.33	K	Isobaric Vapor-Liquid Equilibrium Data and Excess Properties of Binary Systems Comprised of Alkyl Methanoates + Hexane
Tboil	327.32	K	Isobaric Vapor Liquid Equilibrium of Binary Mixtures of Vinyl Acetate and Ethyl Formate with Cumene at 97.3 kPa
Tboil	327.47	K	ChemSep v8.3 pure component data Compiled value
Tboil	327.50	K	KDB
Tboil	327.45 ± 0.40	K	NIST
Tboil	Outlier 326.20	K	NIST
Tboil	327.70	K	NIST
Tboil	327.50	K	NIST
Tboil	327.15 ± 0.30	K	NIST
Tboil	327.35 ± 0.20	K	NIST
Tboil	327.65 ± 2.00	K	NIST
Tboil	327.45 ± 1.00	K	NIST
Tboil	327.45 ± 2.00	K	NIST
Tboil	327.30 ± 0.40	K	NIST
Tboil	327.30 ± 0.50	K	NIST
Tboil	327.15 ± 2.00	K	NIST
Tboil	Outlier 326.35 ± 1.00	K	NIST
Tboil	327.30 ± 0.20	K	NIST
Tboil	327.40 ± 0.60	K	NIST
Tboil	327.00 ± 2.00	K	NIST
Tboil	Outlier 325.85 ± 2.00	K	NIST
Tboil	327.30 ± 0.50	K	NIST
Tboil	327.30 ± 0.50	K	NIST
Tboil	327.30 ± 0.50	K	NIST
Tboil	326.55 ± 1.00	K	NIST
Tboil	327.45 ± 2.00	K	NIST
Tboil	327.20 ± 0.30	K	NIST
Tboil	327.45 ± 0.50	K	NIST
Tboil	327.50 ± 0.50	K	NIST
Tboil	326.65 ± 2.00	K	NIST
Tboil	327.47 ± 0.50	K	NIST
Tboil	327.10 ± 2.00	K	NIST
Tboil	328.00 ± 2.00	K	NIST
Tboil	327.35 ± 2.00	K	NIST
Tboil	328.15 ± 2.00	K	NIST
Tboil	328.05 ± 2.00	K	NIST
Tboil	328.05 ± 2.00	K	NIST
Tc	[503.20; 511.80]	K
Tc	508.40	K	IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Tc	508.40	K	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tc	508.50	K	ChemSep v8.3 pure component data Compiled value
Tc	508.50	K	KDB
Tc	508.40	K	NIST
Tc	508.50 ± 1.00	K	NIST
Tc	508.50 ± 1.00	K	NIST
Tc	506.30 ± 2.00	K	NIST
Tc	511.80 ± 2.00	K	NIST
Tc	Outlier 503.20 ± 4.00	K	NIST
Tfus	[192.65; 193.75]	K
Tfus	192.65	K	Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Tfus	193.55	K	ChemSep v8.3 pure component data Compiled value
Tfus	193.50	K	KDB
Tfus	192.75	K	Aq. Solubility Prediction
Tfus	193.55 ± 0.50	K	NIST
Tfus	193.00 ± 2.00	K	NIST
Tfus	193.75 ± 0.40	K	NIST
Tfus	192.65 ± 0.30	K	NIST
Ttriple	193.55	K	ChemSep v8.3 pure component data Compiled value
UQi	2.58		ChemSep v8.3 pure component data Compiled value
URi	2.82		ChemSep v8.3 pure component data Compiled value
Vc	[0.229; 0.229]	m3/kmol
Vc	0.229	m3/kmol	IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Vc	0.229	m3/kmol	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Vc	0.229	m3/kmol	ChemSep v8.3 pure component data Compiled value
Vc	0.229	m3/kmol	KDB
Zc	[0.2567360; 0.2570000]
Zc	0.2570000		IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Zc	0.2570000		ChemSep v8.3 pure component data Compiled value
Zc	0.2567360		KDB

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[144.30; 158.20]	J/mol×K	[290.00; 298.15]
Cp,liquid	158.20	J/mol×K	290.00	NIST
Cp,liquid	148.10	J/mol×K	294.70	NIST
Cp,liquid	148.10	J/mol×K	294.70	NIST
Cp,liquid	144.30	J/mol×K	298.15	NIST
η	[0.0003000; 0.0004020]	Pa×s	[293.15; 323.15]
η	0.0004020	Pa×s	293.15	Density and Viscosity Correlation for Several Common Fragrance and Flavor Esters
η	0.0003810	Pa×s	298.15	Density and Viscosity Correlation for Several Common Fragrance and Flavor Esters
η	0.0003660	Pa×s	303.15	Viscosity, Density, and Refractive Index of Some (Ester + Hydrocarbon) Binary Mixtures at 303.15 K and 313.15 K
η	0.0003620	Pa×s	303.15	Density and Viscosity Correlation for Several Common Fragrance and Flavor Esters
η	0.0003730	Pa×s	303.15	Physical Properties of Binary Mixtures of Ethyl Formate with Benzene, Isopropyl Benzene, Isobutyl Benzene, and Butylbenzene at (303.15, 308.15, and 313.15) K
η	0.0003450	Pa×s	308.15	Density and Viscosity Correlation for Several Common Fragrance and Flavor Esters
η	0.0003450	Pa×s	308.15	Physical Properties of Binary Mixtures of Ethyl Formate with Benzene, Isopropyl Benzene, Isobutyl Benzene, and Butylbenzene at (303.15, 308.15, and 313.15) K
η	0.0003390	Pa×s	313.15	Viscosity, Density, and Refractive Index of Some (Ester + Hydrocarbon) Binary Mixtures at 303.15 K and 313.15 K
η	0.0003290	Pa×s	313.15	Density and Viscosity Correlation for Several Common Fragrance and Flavor Esters
η	0.0003240	Pa×s	313.15	Physical Properties of Binary Mixtures of Ethyl Formate with Benzene, Isopropyl Benzene, Isobutyl Benzene, and Butylbenzene at (303.15, 308.15, and 313.15) K
η	0.0003140	Pa×s	318.15	Density and Viscosity Correlation for Several Common Fragrance and Flavor Esters
η	0.0003000	Pa×s	323.15	Density and Viscosity Correlation for Several Common Fragrance and Flavor Esters
ΔvapH	[29.80; 35.80]	kJ/mol	[274.50; 412.50]
ΔvapH	35.80	kJ/mol	274.50	NIST
ΔvapH	31.60 ± 0.10	kJ/mol	304.00	NIST
ΔvapH	31.40	kJ/mol	313.00	NIST
ΔvapH	30.90 ± 0.10	kJ/mol	313.00	NIST
ΔvapH	29.91	kJ/mol	327.50	NIST
ΔvapH	29.80 ± 0.10	kJ/mol	328.00	NIST
ΔvapH	29.90	kJ/mol	412.50	NIST
Pvap	101.32	kPa	327.33	Isobaric Vapor-Liquid Equilibrium Data and Excess Properties of Binary Systems Comprised of Alkyl Methanoates + Hexane
n0	[1.35520; 1.35800]		[298.15; 303.15]
n0	1.35800		298.15	Thermodynamic study of (alkyl esters + a,x-alkyl dihalides) I: HE and V E for 25 binary mixtures {xCu-1H2u-1CO2C2H5 + (1-x)a,x-ClCH2(CH2)v-2CH2Cl}, where u = 1 to 5, a = 1 and v = x = 2 to 6
n0	1.35520		303.15	Excess Volumes of Binary Solutions of Methyl Formate, Ethyl Formate, Propyl Formate, and Benzyl Acetate with Bromo-, Chloro-, and Nitrobenzenes at (303.15, 308.15, and 313.15) K
ρl	[876.00; 927.00]	kg/m3	[289.00; 323.15]
ρl	927.00	kg/m3	289.00	KDB
ρl	923.40	kg/m3	291.15	Experimentation and thermodynamic representations of binaries containing compounds of low boiling points: Pentane and alkylmethanoates
ρl	916.60	kg/m3	293.15	Densities and Viscosities of Binary Mixtures Containing Ethyl Formate and 2-Alkanols: Friction Theory and Free Volume Theory
ρl	914.35	kg/m3	298.15	Experimentation and thermodynamic representations of binaries containing compounds of low boiling points: Pentane and alkylmethanoates
ρl	910.10	kg/m3	298.15	Densities and Viscosities of Binary Mixtures Containing Ethyl Formate and 2-Alkanols: Friction Theory and Free Volume Theory
ρl	903.60	kg/m3	303.15	Densities and Viscosities of Binary Mixtures Containing Ethyl Formate and 2-Alkanols: Friction Theory and Free Volume Theory
ρl	897.10	kg/m3	308.15	Densities and Viscosities of Binary Mixtures Containing Ethyl Formate and 2-Alkanols: Friction Theory and Free Volume Theory
ρl	890.50	kg/m3	313.15	Densities and Viscosities of Binary Mixtures Containing Ethyl Formate and 2-Alkanols: Friction Theory and Free Volume Theory
ρl	883.00	kg/m3	318.15	Densities and Viscosities of Binary Mixtures Containing Ethyl Formate and 2-Alkanols: Friction Theory and Free Volume Theory
ρl	876.00	kg/m3	323.15	Densities and Viscosities of Binary Mixtures Containing Ethyl Formate and 2-Alkanols: Friction Theory and Free Volume Theory

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[53.93; 213.97]	J/mol×K	[100.00; 1500.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is Cp,gas in J/mol×K, T in K
Coefficient A			5.23780e+01
Coefficient B			-4.59080e+02
Coefficient C			4.96724e+00
Coefficient D			6.55060e-04
Coefficient E			-2.48320e-07
Temperature range, min.			100.00
Temperature range, max.			1500.00
Cp,gas	53.93	J/mol×K	100.00	Calculated Property
Cp,gas	80.09	J/mol×K	255.56	Calculated Property
Cp,gas	111.40	J/mol×K	411.11	Calculated Property
Cp,gas	137.88	J/mol×K	566.67	Calculated Property
Cp,gas	159.63	J/mol×K	722.22	Calculated Property
Cp,gas	177.33	J/mol×K	877.78	Calculated Property
Cp,gas	191.41	J/mol×K	1033.33	Calculated Property
Cp,gas	202.12	J/mol×K	1188.89	Calculated Property
Cp,gas	209.59	J/mol×K	1344.44	Calculated Property
Cp,gas	213.97	J/mol×K	1500.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[138.12; 162.95]	J/mol×K	[254.20; 374.20]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is Cp,liquid in J/mol×K, T in K
Coefficient A			1.15910e+02
Coefficient B			2.28300e+02
Coefficient C			-2.82946e+00
Coefficient D			2.73660e-02
Coefficient E			-2.97810e-05
Temperature range, min.			254.20
Temperature range, max.			374.20
Cp,liquid	138.12	J/mol×K	254.20	Calculated Property
Cp,liquid	140.78	J/mol×K	267.53	Calculated Property
Cp,liquid	143.58	J/mol×K	280.87	Calculated Property
Cp,liquid	146.48	J/mol×K	294.20	Calculated Property
Cp,liquid	149.43	J/mol×K	307.53	Calculated Property
Cp,liquid	152.39	J/mol×K	320.87	Calculated Property
Cp,liquid	155.29	J/mol×K	334.20	Calculated Property
Cp,liquid	158.06	J/mol×K	347.53	Calculated Property
Cp,liquid	160.63	J/mol×K	360.87	Calculated Property
Cp,liquid	162.95	J/mol×K	374.20	Calculated Property

Property	Value	Unit	Temperature (K)	Source
η	[0.0007434; 0.0002487]	Pa×s	[245.00; 345.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = exp(A + B/T + C·ln(T) + D·T^E) Y is η in Pa×s, T in K
Coefficient A			-8.94830e+00
Coefficient B			8.48560e+02
Coefficient C			-3.15670e-01
Coefficient D			2.85820e-07
Coefficient E			2.00000e+00
Temperature range, min.			245.00
Temperature range, max.			345.00
η	0.0007434	Pa×s	245.00	Calculated Property
η	0.0006318	Pa×s	256.11	Calculated Property
η	0.0005441	Pa×s	267.22	Calculated Property
η	0.0004740	Pa×s	278.33	Calculated Property
η	0.0004172	Pa×s	289.44	Calculated Property
η	0.0003706	Pa×s	300.56	Calculated Property
η	0.0003320	Pa×s	311.67	Calculated Property
η	0.0002996	Pa×s	322.78	Calculated Property
η	0.0002721	Pa×s	333.89	Calculated Property
η	0.0002487	Pa×s	345.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
ΔvapH	[36.97; 0.76]	kJ/mol	[193.55; 508.45]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A·(1 − Tr)^(B + C·Tr + D·Tr² + E·Tr³), Tr = T/Tc Y is ΔvapH in kJ/mol, T in K
Coefficient A			5.98130e+01
Coefficient B			2.19310e+00
Coefficient C			-4.65870e+00
Coefficient D			4.70890e+00
Coefficient E			-1.76960e+00
Critical temperature, Tc (K)			5.08500e+02
Temperature range, min.			193.55
Temperature range, max.			508.45
ΔvapH	36.97	kJ/mol	193.55	Calculated Property
ΔvapH	35.17	kJ/mol	228.54	Calculated Property
ΔvapH	33.42	kJ/mol	263.53	Calculated Property
ΔvapH	31.56	kJ/mol	298.52	Calculated Property
ΔvapH	29.46	kJ/mol	333.51	Calculated Property
ΔvapH	27.01	kJ/mol	368.49	Calculated Property
ΔvapH	24.06	kJ/mol	403.48	Calculated Property
ΔvapH	20.40	kJ/mol	438.47	Calculated Property
ΔvapH	15.31	kJ/mol	473.46	Calculated Property
ΔvapH	0.76	kJ/mol	508.45	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 4887.31]	kPa	[240.08; 508.40]	The Yaws Handbook of Vapor Pressure
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.46571e+01
Coefficient B			-2.89533e+03
Coefficient C			-3.85850e+01
Temperature range, min.			240.08
Temperature range, max.			508.40
Pvap	1.33	kPa	240.08	Calculated Property
Pvap	8.50	kPa	269.89	Calculated Property
Pvap	35.48	kPa	299.71	Calculated Property
Pvap	110.53	kPa	329.52	Calculated Property
Pvap	278.75	kPa	359.33	Calculated Property
Pvap	600.63	kPa	389.15	Calculated Property
Pvap	1147.48	kPa	418.96	Calculated Property
Pvap	1995.33	kPa	448.77	Calculated Property
Pvap	3219.01	kPa	478.59	Calculated Property
Pvap	4887.31	kPa	508.40	Calculated Property
Pvap	[0.02; 4664.62]	kPa	[193.55; 508.45]	ChemSep v8.3 pure component data Compiled value
Equation			Y = exp(A + B/T + C·ln(T) + D·T^E) Y is Pvap in kPa, T in K
Coefficient A			6.21374e+01
Coefficient B			-5.67864e+03
Coefficient C			-7.03140e+00
Coefficient D			5.00570e-06
Coefficient E			2.00000e+00
Temperature range, min.			193.55
Temperature range, max.			508.45
Pvap	0.02	kPa	193.55	Calculated Property
Pvap	0.53	kPa	228.54	Calculated Property
Pvap	5.71	kPa	263.53	Calculated Property
Pvap	32.78	kPa	298.52	Calculated Property
Pvap	123.60	kPa	333.51	Calculated Property
Pvap	349.06	kPa	368.49	Calculated Property
Pvap	803.50	kPa	403.48	Calculated Property
Pvap	1595.23	kPa	438.47	Calculated Property
Pvap	2840.53	kPa	473.46	Calculated Property
Pvap	4664.62	kPa	508.45	Calculated Property
Pvap	[0.02; 4690.28]	kPa	[193.55; 508.40]	KDB Vapor Pressure Data
Equation			ln(Y) = A + B/T + C·ln(T) + D·T² + E/T² Y is Pvap in kPa, T in K
Coefficient A			6.34086e+01
Coefficient B			-5.70647e+03
Coefficient C			-7.24275e+00
Coefficient D			5.41841e-06
Coefficient E			0.00000e+00
Temperature range, min.			193.55
Temperature range, max.			508.40
Pvap	0.02	kPa	193.55	Calculated Property
Pvap	0.54	kPa	228.53	Calculated Property
Pvap	5.80	kPa	263.52	Calculated Property
Pvap	33.10	kPa	298.50	Calculated Property
Pvap	124.22	kPa	333.48	Calculated Property
Pvap	349.77	kPa	368.47	Calculated Property
Pvap	803.96	kPa	403.45	Calculated Property
Pvap	1596.30	kPa	438.43	Calculated Property
Pvap	2847.13	kPa	473.42	Calculated Property
Pvap	4690.28	kPa	508.40	Calculated Property

Property	Value	Unit	Temperature (K)	Source
ρl	[1032.81; 326.45]	kg/m3	[193.55; 508.45]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A / B^(1 + (1 − T/C)^D) Y is ρl in kg/m3, T in K
Coefficient A			6.33875e+01
Coefficient B			2.28820e-01
Coefficient C			5.08500e+02
Coefficient D			2.37920e-01
Temperature range, min.			193.55
Temperature range, max.			508.45
ρl	1032.81	kg/m3	193.55	Calculated Property
ρl	995.93	kg/m3	228.54	Calculated Property
ρl	956.88	kg/m3	263.53	Calculated Property
ρl	915.11	kg/m3	298.52	Calculated Property
ρl	869.86	kg/m3	333.51	Calculated Property
ρl	819.90	kg/m3	368.49	Calculated Property
ρl	763.13	kg/m3	403.48	Calculated Property
ρl	695.26	kg/m3	438.47	Calculated Property
ρl	604.57	kg/m3	473.46	Calculated Property
ρl	326.45	kg/m3	508.45	Calculated Property

Property	Value	Unit	Temperature (K)	Source
γ	[0.04; 0.02]	N/m	[193.15; 327.15]	Jasper (1972), surface tension of pure liquid compounds Compiled value
Equation			Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is γ in N/m, T in K
Coefficient A			6.23892e-02
Coefficient B			-1.31500e-04
Coefficient C			0.00000e+00
Coefficient D			0.00000e+00
Coefficient E			0.00000e+00
Temperature range, min.			193.15
Temperature range, max.			327.15
γ	0.04	N/m	193.15	Calculated Property
γ	0.04	N/m	208.04	Calculated Property
γ	0.03	N/m	222.93	Calculated Property
γ	0.03	N/m	237.82	Calculated Property
γ	0.03	N/m	252.71	Calculated Property
γ	0.03	N/m	267.59	Calculated Property
γ	0.03	N/m	282.48	Calculated Property
γ	0.02	N/m	297.37	Calculated Property
γ	0.02	N/m	312.26	Calculated Property
γ	0.02	N/m	327.15	Calculated Property
γ	[0.04; 2.15e-06]	N/m	[193.55; 507.46]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is γ in N/m, T in K
Coefficient A			-2.09400e-02
Coefficient B			3.23940e+01
Coefficient C			-2.92990e+00
Coefficient D			3.55550e-04
Coefficient E			-4.58370e-06
Comment			Range stopped where the equation turns negative; ChemSep gives it to 508.4 K.
Temperature range, min.			193.55
Temperature range, max.			507.46
γ	0.04	N/m	193.55	Calculated Property
γ	0.03	N/m	228.43	Calculated Property
γ	0.03	N/m	263.31	Calculated Property
γ	0.02	N/m	298.19	Calculated Property
γ	0.02	N/m	333.06	Calculated Property
γ	0.01	N/m	367.94	Calculated Property
γ	0.01	N/m	402.82	Calculated Property
γ	0.01	N/m	437.70	Calculated Property
γ	0.00	N/m	472.58	Calculated Property
γ	2.15e-06	N/m	507.46	Calculated Property

Property	Value	Unit	Temperature (K)	Source
λgas	[0.01; 0.12]	W/m×K	[193.55; 1000.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A·T^B / (1 + C/T + D/T²) Y is λgas in W/m×K, T in K
Coefficient A			3.81390e+02
Coefficient B			9.15900e-01
Coefficient C			1.80000e+09
Coefficient D			-1.14620e+10
Temperature range, min.			193.55
Temperature range, max.			1000.00
λgas	0.01	W/m×K	193.55	Calculated Property
λgas	0.01	W/m×K	283.16	Calculated Property
λgas	0.02	W/m×K	372.76	Calculated Property
λgas	0.03	W/m×K	462.37	Calculated Property
λgas	0.04	W/m×K	551.97	Calculated Property
λgas	0.05	W/m×K	641.58	Calculated Property
λgas	0.07	W/m×K	731.18	Calculated Property
λgas	0.08	W/m×K	820.79	Calculated Property
λgas	0.10	W/m×K	910.39	Calculated Property
λgas	0.12	W/m×K	1000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
λliquid	[0.19; 0.12]	W/m×K	[193.55; 433.15]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is λliquid in W/m×K, T in K
Coefficient A			-3.09270e-02
Coefficient B			1.99990e+01
Coefficient C			-1.49110e+00
Coefficient D			-5.20480e-05
Coefficient E			-2.41110e-06
Temperature range, min.			193.55
Temperature range, max.			433.15
λliquid	0.19	W/m×K	193.55	Calculated Property
λliquid	0.19	W/m×K	220.17	Calculated Property
λliquid	0.18	W/m×K	246.79	Calculated Property
λliquid	0.17	W/m×K	273.42	Calculated Property
λliquid	0.16	W/m×K	300.04	Calculated Property
λliquid	0.15	W/m×K	326.66	Calculated Property
λliquid	0.14	W/m×K	353.28	Calculated Property
λliquid	0.13	W/m×K	379.91	Calculated Property
λliquid	0.12	W/m×K	406.53	Calculated Property
λliquid	0.12	W/m×K	433.15	Calculated Property

Similar Compounds

Find more compounds similar to Ethyl formate.

Mixtures

• Ethyl formate + Ethane, 1,2-dichloro-
• Ethyl formate + Propane, 1,3-dichloro-
• Ethyl formate + Butane, 1,4-dichloro-
• Ethyl formate + Pentane, 1,5-dichloro-
• Ethyl formate + Hexane, 1,6-dichloro-
• Ethyl formate + Pentane
• Ethyl formate + Ethane, 1,2-dibromo-
• Ethyl formate + Propane, 1,3-dibromo-
• Ethyl formate + Butane, 1,4-dibromo-
• Ethyl formate + Pentane, 1,5-dibromo-
• Ethyl formate + 1,6-DIBROMOHEXANE
• Ethyl formate + Ethanol + Water
• Ethyl formate + Formic acid + Water
• Ethyl formate + Heptane
• Ethyl formate + Octane
• Ethyl formate + Nonane
• Ethyl formate + Thiophene, tetrabromo-
• Ethyl formate + 1-Propanol
• Ethyl formate + 2-Propanol
• Ethyl formate + 1-Butanol

Find more mixtures with Ethyl formate.

Sources

• KDB Vapor Pressure Data
• Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) ChEDL chemicals 1.5.2, from Bradley, J.-C.; Williams, A.; Lang, A. Jean-Claude Bradley Open Melting Point Dataset. Figshare, 2014 (CC0).
• IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 ChEDL chemicals 1.5.2, from Kudchadker, A. P.; Ambrose, D.; Tsonopoulos, C. Vapor-Liquid Critical Properties of Elements and Compounds. 7. Oxygen Compounds Other Than Alkanols and Cycloalkanols. J. Chem. Eng. Data 2001, 46, 457-479.
• Jasper (1972), surface tension of pure liquid compounds ChEDL chemicals 1.5.2, from Jasper, J. J. The Surface Tension of Pure Liquid Compounds. J. Phys. Chem. Ref. Data 1972, 1, 841-1010 (as transcribed in Lange's Handbook).
• PSRK revision IV (2005), critical constants and acentric factors of 1000 components ChEDL chemicals 1.5.2, from Horstmann, S.; Jabłoniec, A.; Krafczyk, J.; Fischer, K.; Gmehling, J. PSRK Group Contribution Equation of State: Comprehensive Revision and Extension IV, Including Critical Constants and α-Function Parameters for 1000 Components. Fluid Phase Equilib. 2005, 227, 157-164.
• ChemSep v8.3 pure component data Converted from ChemSep v8.3 pure component data, H. Kooijman and R. Taylor (2021, 2022), Artistic License 2.0; see how the values differ.
• Crippen Method
• Excess properties and isobaric vapor liquid equilibria for four binary systems of alkyl (methyl to butyl) methanoates with decane
• Determination and correlation of solubilities of 1,2-bis(2-oxo-5,5-dimethyl-1,3,2-dioxyphosphacyclohexyl-2-imino) ethane in selected solvents
• Experimentation and thermodynamic representations of binaries containing compounds of low boiling points: Pentane and alkylmethanoates
• Solutions of alkyl methanoates and alkanes: Simultaneous modeling of phase equilibria and mixing properties. Estimation of behavior by UNIFAC with recalculation of parameters
• Solubility, liquid-liquid equilibrium and critical states for the quaternary system formic acid - ethanol - ethyl formate - water at 298.15 K and 308.15 K
• Thermodynamic study of (alkyl esters + a,x-alkyl dihalides) I: HE and V E for 25 binary mixtures {xCu-1H2u-1CO2C2H5 + (1-x)a,x-ClCH2(CH2)v-2CH2Cl}, where u = 1 to 5, a = 1 and v = x = 2 to 6
• Excess molar enthalpies of ethylformate and (1-propanol, 2-propanol, 1-butanol, 2-butanol, and 1-pentanol) at T = (298.15 and 308.15) K and p = (5 and 10) MPa
• Thermodynamic study of (alkyl esters + a,x-alkyl dihalides) II: HE m and V E m for 25 binary mixtures {xCu-1H2u-1CO2C2H5 + (1 - x)a,x-BrCH2(CH2)v-2CH2Br}, where u = 1 to 5, a = 1 and v = x = 2 to 6
• Thermodynamic study of (alkyl esters + a,x-alkyl dihalides) V. Hex and Vex for 25 binary mixtures {xCu-1H2u-1CO2CH3 + (1-x)a,x-ClCH2(CH2)v-2CH2Cl}, where u = 1 to 5, a = 1 and v = x = 2 to 6
• Measurement and correlation of the solubility of 2,3,4,5-tetrabromothiophene in different solvents
• Solid Liquid Phase Equilibrium of N,N'-Piperazinebis(neopentylglycol)phosphoramidate in Selected Solvents from T = (293.15 to 333.15) K
• Measurement and Correlation of Solubility of Resorcinol Bis(cyclic 2,2-dimethyl-1,3-propanediol phosphate) in Selected Solvents from T = 293.15 to 333.15 K
• Solution Thermodynamics of Benzotriazole in Different Pure Solvents
• Solubility Determination, Modeling, and Thermodynamic Dissolution Properties of Benzenesulfonamide in 16 Neat Solvents from 273.15 to 324.45 K
• Solubility Measurement and Thermodynamic Modeling for o-Toluenesulfonamide in 16 Solvents from T = 273.15 to 323.85 K
• Isobaric Vapor-Liquid Equilibria and Excess Quantities for Binary Mixtures of an Ethyl Ester + tert-Butanol and a New Approach to VLE Data Processing
• Viscosity, Density, and Refractive Index of Some (Ester + Hydrocarbon) Binary Mixtures at 303.15 K and 313.15 K
• Measurement of Activity Coefficients at Infinite Dilution of Benzene, Toluene, Ethanol, Esters, Ketones, and Ethers at Various Temperatures in Water Using the Dilutor Technique
• Density and Viscosity Correlation for Several Common Fragrance and Flavor Esters
• Isobaric Vapor-Liquid Equilibrium Data and Excess Properties of Binary Systems Comprised of Alkyl Methanoates + Hexane
• Solubility of 1H-1,2,4-Triazole in Ethanol, 1-Propanol, 2-Propanol, 1,2-Propanediol, Ethyl Formate, Methyl Acetate, Ethyl Acetate, and Butyl Acetate at (283 to 363) K
• Solubility of 3-Nitrophthalic Acid in Different Solvents between 278 K and 353 K
• Solubilities of Betulinic Acid in Thirteen Organic Solvents at Different Temperatures
• Densities and Viscosities of Binary Mixtures Containing Ethyl Formate and 2-Alkanols: Friction Theory and Free Volume Theory
• Solubilities of Betulin in Fourteen Organic Solvents at Different Temperatures
• Excess Volumes of Binary Solutions of Methyl Formate, Ethyl Formate, Propyl Formate, and Benzyl Acetate with Bromo-, Chloro-, and Nitrobenzenes at (303.15, 308.15, and 313.15) K
• Solubility of Chlorpheniramine Maleate in Ethanol, 1-Propanol, 1-Butanol, Benzene, Ethyl Acetate, Ethyl Formate, and Butyl Acetate between 283 K and 333 K
• Solubility of 2-(4-Ethylbenzoyl)benzoic Acid in Eleven Organic Solvents between 279.55 K and 343.15 K
• Isobaric Vapor Liquid Equilibrium of Binary Mixtures of Vinyl Acetate and Ethyl Formate with Cumene at 97.3 kPa
• Densities and Viscosities of 1-Butyl-3-methylimidazolium Tetrafluoroborate + Molecular Solvent Binary Mixtures
• Solubility of Tiamulin Hydrogen Fumarate in Acetone, Acetonitrile, Ethyl Acetate, Ethyl Formate, and Butyl Acetate from (288.2 to 318.2) K
• Physical Properties of Binary Mixtures of Ethyl Formate with Benzene, Isopropyl Benzene, Isobutyl Benzene, and Butylbenzene at (303.15, 308.15, and 313.15) K
• Henry s Law Constants of Organic Compounds in Water and n-Octane at T = 293.2 K
• Joback Method
• KDB
• Aqueous Solubility Prediction Method
• Estimated Solubility Method
• McGowan Method
• NIST Webbook
• The Yaws Handbook of Vapor Pressure

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