Chemical Properties of Ethane, methoxy- (CAS 540-67-0)

Ethane, methoxy-

InChI
InChI=1S/C3H8O/c1-3-4-2/h3H2,1-2H3
InChI Key
XOBKSJJDNFUZPF-UHFFFAOYSA-N
Formula
C3H8O
SMILES
CCOC
Molecular Weight1
60.10
CAS
540-67-0
Other Names
  • C2H5OCH3
  • ETHOXY METHANE
  • Ether, ethyl methyl
  • Ethyl methyl ether
  • Methane, ethoxy-
  • Methoxyethane
  • Methyl ethyl ether
  • UN 1039
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Physical Properties

Property Value Unit Source
ω [0.2360; 0.2440]   Show Hide
ω 0.2361 PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
ω 0.2360 ChemSep v8.3 pure component data Compiled value
ω 0.2440 KDB
PAff 808.60 kJ/mol NIST
BasG 781.20 kJ/mol NIST
ΔcH°gas -2107.40 ± 0.63 kJ/mol NIST
μ [1.20; 1.23] debye Show Hide
μ 1.23 debye ChemSep v8.3 pure component data Compiled value
μ 1.20 debye KDB
ΔfG° [-117.70; -117.70] kJ/mol Show Hide
ΔfG° -117.70 kJ/mol ChemSep v8.3 pure component data Compiled value
ΔfG° -117.70 kJ/mol KDB
ΔfH°gas [-216.60; -216.40] kJ/mol Show Hide
ΔfH°gas -216.40 kJ/mol ChemSep v8.3 pure component data Compiled value
ΔfH°gas -216.60 kJ/mol KDB
ΔfH°gas -216.40 ± 0.67 kJ/mol NIST
ΔfusH° 4.71 kJ/mol Joback Calculated Property
ΔvapH° 22.70 kJ/mol Relay (1.0) Calculated Property
IE [9.50; 9.86] eV Show Hide
IE 9.72 ± 0.07 eV NIST
IE 9.72 ± 0.07 eV NIST
IE 9.86 eV NIST
IE 9.72 eV NIST
IE 9.50 eV NIST
IE 9.60 ± 0.10 eV NIST
IE 9.72 eV NIST
IE 9.81 eV NIST
log10WS 0.21 Relay (1.0) Calculated Property
logPoct/wat 0.653 Crippen Calculated Property
McVol 59.000 ml/mol McGowan Calculated Property
NFPA Fire 4 KDB
NFPA Health 2 KDB
Pc [4361.00; 4688.00] kPa Show Hide
Pc 4380.00 kPa IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Pc 4397.51 kPa PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Pc 4400.00 kPa ChemSep v8.3 pure component data Compiled value
Pc 4400.00 kPa KDB
Pc 4361.00 ± 50.66 kPa NIST
Pc 4400.00 ± 40.53 kPa NIST
Pc Outlier 4688.00 ± 303.98 kPa NIST
Ptriple 7.85e-03 kPa ChemSep v8.3 pure component data Compiled value
ρc [272.17; 307.03] kg/m3 Show Hide
ρc 272.17 ± 1.80 kg/m3 NIST
ρc 307.03 ± 19.83 kg/m3 NIST
Inp [419.00; 421.00]   Show Hide
Inp 421.00 NIST
Inp 421.00 NIST
Inp 419.00 NIST
Inp 421.00 NIST
Tboil [279.75; 312.10] K Show Hide
Tboil 280.50 K ChemSep v8.3 pure component data Compiled value
Tboil 280.60 K KDB
Tboil 283.20 K NIST
Tboil 312.10 ± 0.40 K NIST
Tboil 279.75 ± 0.60 K NIST
Tc [437.80; 441.60] K Show Hide
Tc 437.90 K IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Tc 437.80 K PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tc 437.80 K ChemSep v8.3 pure component data Compiled value
Tc 438.15 K Air Liquide Gas Encyclopedia
Tc 437.80 K KDB
Tc 438.03 ± 1.00 K NIST
Tc 437.80 ± 0.30 K NIST
Tc 437.90 ± 0.30 K NIST
Tc Outlier 441.60 ± 4.00 K NIST
Tc 440.90 ± 3.00 K NIST
Tfus [134.15; 160.15] K Show Hide
Tfus 160.15 K Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Tfus 160.00 K ChemSep v8.3 pure component data Compiled value
Tfus 134.15 K Air Liquide Gas Encyclopedia
Tfus 160.00 K KDB
Ttriple 160.00 K ChemSep v8.3 pure component data Compiled value
UQi 2.48 ChemSep v8.3 pure component data Compiled value
URi 2.72 ChemSep v8.3 pure component data Compiled value
Vc [0.221; 0.222] m3/kmol Show Hide
Vc 0.222 m3/kmol IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Vc 0.221 m3/kmol PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Vc 0.221 m3/kmol ChemSep v8.3 pure component data Compiled value
Vc 0.221 m3/kmol KDB
Vc 0.222 ± 0.003 m3/kmol NIST
Zc [0.2670000; 0.2671360]   Show Hide
Zc 0.2670000 IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Zc 0.2670000 ChemSep v8.3 pure component data Compiled value
Zc 0.2671360 KDB
Zra 0.27 ChemSep v8.3 pure component data Compiled value

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
ΔvapH [24.69; 37.10] kJ/mol [231.00; 359.50] Show Hide
ΔvapH 26.30 kJ/mol 231.00 NIST
ΔvapH 37.00 kJ/mol 257.50 NIST
ΔvapH 24.69 kJ/mol 280.80 KDB
ΔvapH 30.10 kJ/mol 357.00 NIST
ΔvapH 37.10 kJ/mol 359.50 NIST
ρl 700.00 kg/m3 293.00 KDB
γ 0.02 N/m 298.20 KDB

Correlations

Property Value Unit Temperature (K) Source
Cp,gas [65.17; 228.83] J/mol×K [150.00; 1500.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is Cp,gas in J/mol×K, T in K
Coefficient A6.05710e+01
Coefficient B-5.57180e+02
Coefficient C5.17124e+00
Coefficient D4.80840e-04
Coefficient E-1.75810e-07
Temperature range, min.150.00
Temperature range, max.1500.00
Cp,gas 65.17 J/mol×K 150.00 Calculated Property
Cp,gas 91.83 J/mol×K 300.00 Calculated Property
Cp,gas 121.75 J/mol×K 450.00 Calculated Property
Cp,gas 147.74 J/mol×K 600.00 Calculated Property
Cp,gas 169.43 J/mol×K 750.00 Calculated Property
Cp,gas 187.36 J/mol×K 900.00 Calculated Property
Cp,gas 201.98 J/mol×K 1050.00 Calculated Property
Cp,gas 213.62 J/mol×K 1200.00 Calculated Property
Cp,gas 222.51 J/mol×K 1350.00 Calculated Property
Cp,gas 228.83 J/mol×K 1500.00 Calculated Property
Property Value Unit Temperature (K) Source
Cp,liquid [117.49; 145.10] J/mol×K [160.00; 291.87] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is Cp,liquid in J/mol×K, T in K
Coefficient A1.09050e+02
Coefficient B-3.16450e+01
Coefficient C8.70545e-01
Coefficient D8.46840e-03
Coefficient E4.12020e-06
Temperature range, min.160.00
Temperature range, max.291.87
Cp,liquid 117.49 J/mol×K 160.00 Calculated Property
Cp,liquid 118.97 J/mol×K 174.65 Calculated Property
Cp,liquid 120.69 J/mol×K 189.30 Calculated Property
Cp,liquid 122.70 J/mol×K 203.96 Calculated Property
Cp,liquid 125.07 J/mol×K 218.61 Calculated Property
Cp,liquid 127.86 J/mol×K 233.26 Calculated Property
Cp,liquid 131.15 J/mol×K 247.91 Calculated Property
Cp,liquid 135.04 J/mol×K 262.57 Calculated Property
Cp,liquid 139.64 J/mol×K 277.22 Calculated Property
Cp,liquid 145.10 J/mol×K 291.87 Calculated Property
Property Value Unit Temperature (K) Source
η [0.0009134; 0.0001003] Pa×s [160.00; 373.15] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = exp(A + B/T + C·ln(T) + D·T^E)
Y is η in Pa×s, T in K
Coefficient A-1.11380e+01
Coefficient B6.28050e+02
Coefficient C4.23450e-02
Coefficient D-2.02810e-08
Coefficient E2.00000e+00
Temperature range, min.160.00
Temperature range, max.373.15
η 0.0009134 Pa×s 160.00 Calculated Property
η 0.0005538 Pa×s 183.68 Calculated Property
η 0.0003766 Pa×s 207.37 Calculated Property
η 0.0002773 Pa×s 231.05 Calculated Property
η 0.0002162 Pa×s 254.73 Calculated Property
η 0.0001759 Pa×s 278.42 Calculated Property
η 0.0001479 Pa×s 302.10 Calculated Property
η 0.0001275 Pa×s 325.78 Calculated Property
η 0.0001122 Pa×s 349.47 Calculated Property
η 0.0001003 Pa×s 373.15 Calculated Property
Property Value Unit Temperature (K) Source
ΔvapH [29.82; 9.82] kJ/mol [160.00; 423.18] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A·(1 − Tr)^(B + C·Tr + D·Tr² + E·Tr³), Tr = T/Tc
Y is ΔvapH in kJ/mol, T in K
Coefficient A1.36790e+02
Coefficient B9.49480e+00
Coefficient C-2.56550e+01
Coefficient D2.84240e+01
Coefficient E-1.16030e+01
Critical temperature, Tc (K)4.37800e+02
Temperature range, min.160.00
Temperature range, max.423.18
ΔvapH 29.82 kJ/mol 160.00 Calculated Property
ΔvapH 28.37 kJ/mol 189.24 Calculated Property
ΔvapH 27.35 kJ/mol 218.48 Calculated Property
ΔvapH 26.29 kJ/mol 247.73 Calculated Property
ΔvapH 24.86 kJ/mol 276.97 Calculated Property
ΔvapH 22.93 kJ/mol 306.21 Calculated Property
ΔvapH 20.51 kJ/mol 335.45 Calculated Property
ΔvapH 17.76 kJ/mol 364.70 Calculated Property
ΔvapH 14.66 kJ/mol 393.94 Calculated Property
ΔvapH 9.82 kJ/mol 423.18 Calculated Property
Property Value Unit Temperature (K) Source
Pvap [1.33; 3537.71] kPa [217.94; 437.80] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.23480e+01
Coefficient B-1.40486e+03
Coefficient C-1.01451e+02
Temperature range, min.217.94
Temperature range, max.437.80
Pvap 1.33 kPa 217.94 Calculated Property
Pvap 10.79 kPa 242.37 Calculated Property
Pvap 47.07 kPa 266.80 Calculated Property
Pvap 140.51 kPa 291.23 Calculated Property
Pvap 326.86 kPa 315.66 Calculated Property
Pvap 639.65 kPa 340.08 Calculated Property
Pvap 1105.02 kPa 364.51 Calculated Property
Pvap 1739.59 kPa 388.94 Calculated Property
Pvap 2550.68 kPa 413.37 Calculated Property
Pvap 3537.71 kPa 437.80 Calculated Property
Pvap [0.01; 4401.90] kPa [160.00; 437.80] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = exp(A + B/T + C·ln(T) + D·T^E)
Y is Pvap in kPa, T in K
Coefficient A5.69322e+01
Coefficient B-4.65920e+03
Coefficient C-6.41370e+00
Coefficient D5.77270e-06
Coefficient E2.00000e+00
CommentRange stopped at Tc; ChemSep gives it to 437.85 K.
Temperature range, min.160.00
Temperature range, max.437.80
Pvap 0.01 kPa 160.00 Calculated Property
Pvap 0.39 kPa 190.87 Calculated Property
Pvap 4.76 kPa 221.73 Calculated Property
Pvap 29.26 kPa 252.60 Calculated Property
Pvap 114.53 kPa 283.47 Calculated Property
Pvap 329.79 kPa 314.33 Calculated Property
Pvap 765.54 kPa 345.20 Calculated Property
Pvap 1521.76 kPa 376.07 Calculated Property
Pvap 2699.87 kPa 406.93 Calculated Property
Pvap 4401.90 kPa 437.80 Calculated Property
Pvap [3.35e-04; 4647.74] kPa [160.00; 437.80] KDB Vapor Pressure Data Show Hide
Equationln(Y) = A + B/T + C·ln(T) + D·T² + E/T²
Y is Pvap in kPa, T in K
Coefficient A2.43488e+02
Coefficient B-1.12818e+04
Coefficient C-3.58975e+01
Coefficient D4.71928e-05
Coefficient E0.00000e+00
Temperature range, min.160.00
Temperature range, max.437.80
Pvap 3.35e-04 kPa 160.00 Calculated Property
Pvap 0.09 kPa 190.87 Calculated Property
Pvap 2.80 kPa 221.73 Calculated Property
Pvap 26.01 kPa 252.60 Calculated Property
Pvap 117.24 kPa 283.47 Calculated Property
Pvap 341.34 kPa 314.33 Calculated Property
Pvap 765.38 kPa 345.20 Calculated Property
Pvap 1479.02 kPa 376.07 Calculated Property
Pvap 2653.25 kPa 406.93 Calculated Property
Pvap 4647.74 kPa 437.80 Calculated Property
Pvap [0.13; 101.21] kPa [182.00; 280.70] NIST Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.38915e+01
Coefficient B-2.19348e+03
Coefficient C-4.41890e+01
ReferenceStull, 1947
CommentCoefficents calculated by NIST from author's data.
Temperature range, min.182.00
Temperature range, max.280.70
Pvap 0.13 kPa 182.00 Calculated Property
Pvap 0.43 kPa 192.97 Calculated Property
Pvap 1.17 kPa 203.93 Calculated Property
Pvap 2.84 kPa 214.90 Calculated Property
Pvap 6.16 kPa 225.87 Calculated Property
Pvap 12.25 kPa 236.83 Calculated Property
Pvap 22.62 kPa 247.80 Calculated Property
Pvap 39.22 kPa 258.77 Calculated Property
Pvap 64.47 kPa 269.73 Calculated Property
Pvap 101.21 kPa 280.70 Calculated Property
Pvap [93.15; 4030.74] kPa [280.70; 433.00] NIST Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.25606e+01
Coefficient B-1.38186e+03
Coefficient C-1.08534e+02
ReferenceStull, 1947
CommentCoefficents calculated by NIST from author's data.
Temperature range, min.280.70
Temperature range, max.433.00
Pvap 93.15 kPa 280.70 Calculated Property
Pvap 191.06 kPa 297.62 Calculated Property
Pvap 348.23 kPa 314.54 Calculated Property
Pvap 579.42 kPa 331.47 Calculated Property
Pvap 897.26 kPa 348.39 Calculated Property
Pvap 1311.63 kPa 365.31 Calculated Property
Pvap 1829.42 kPa 382.23 Calculated Property
Pvap 2454.64 kPa 399.16 Calculated Property
Pvap 3188.69 kPa 416.08 Calculated Property
Pvap 4030.74 kPa 433.00 Calculated Property
Property Value Unit Temperature (K) Source
ρl [837.49; 293.88] kg/m3 [160.00; 437.80] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A / B^(1 + (1 − T/C)^D)
Y is ρl in kg/m3, T in K
Coefficient A6.72764e+01
Coefficient B2.63670e-01
Coefficient C4.37860e+02
Coefficient D2.52310e-01
CommentRange stopped at Tc; ChemSep gives it to 437.85 K.
Temperature range, min.160.00
Temperature range, max.437.80
ρl 837.49 kg/m3 160.00 Calculated Property
ρl 808.85 kg/m3 190.87 Calculated Property
ρl 778.53 kg/m3 221.73 Calculated Property
ρl 746.10 kg/m3 252.60 Calculated Property
ρl 710.97 kg/m3 283.47 Calculated Property
ρl 672.20 kg/m3 314.33 Calculated Property
ρl 628.15 kg/m3 345.20 Calculated Property
ρl 575.50 kg/m3 376.07 Calculated Property
ρl 505.17 kg/m3 406.93 Calculated Property
ρl 293.88 kg/m3 437.80 Calculated Property
Property Value Unit Temperature (K) Source
γ [0.03; 0.02] N/m [160.15; 280.55] Jasper (1972), surface tension of pure liquid compounds Compiled value Show Hide
EquationY = A + B·T + C·T² + D·T³ + E·T⁴
Y is γ in N/m, T in K
Coefficient A5.45339e-02
Coefficient B-1.31700e-04
Coefficient C0.00000e+00
Coefficient D0.00000e+00
Coefficient E0.00000e+00
Temperature range, min.160.15
Temperature range, max.280.55
γ 0.03 N/m 160.15 Calculated Property
γ 0.03 N/m 173.53 Calculated Property
γ 0.03 N/m 186.91 Calculated Property
γ 0.03 N/m 200.28 Calculated Property
γ 0.03 N/m 213.66 Calculated Property
γ 0.02 N/m 227.04 Calculated Property
γ 0.02 N/m 240.42 Calculated Property
γ 0.02 N/m 253.79 Calculated Property
γ 0.02 N/m 267.17 Calculated Property
γ 0.02 N/m 280.55 Calculated Property
γ [0.03; 9.20e-04] N/m [160.00; 423.18] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is γ in N/m, T in K
Coefficient A-1.01650e-02
Coefficient B6.68370e+01
Coefficient C-3.70840e+00
Coefficient D3.14290e-03
Coefficient E-1.27410e-05
Temperature range, min.160.00
Temperature range, max.423.18
γ 0.03 N/m 160.00 Calculated Property
γ 0.03 N/m 189.24 Calculated Property
γ 0.03 N/m 218.48 Calculated Property
γ 0.02 N/m 247.73 Calculated Property
γ 0.02 N/m 276.97 Calculated Property
γ 0.01 N/m 306.21 Calculated Property
γ 0.01 N/m 335.45 Calculated Property
γ 0.01 N/m 364.70 Calculated Property
γ 0.00 N/m 393.94 Calculated Property
γ 9.20e-04 N/m 423.18 Calculated Property
Property Value Unit Temperature (K) Source
λgas [0.01; 0.09] W/m×K [160.00; 1000.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A·T^B / (1 + C/T + D/T²)
Y is λgas in W/m×K, T in K
Coefficient A2.10580e-04
Coefficient B9.44720e-01
Coefficient C5.15360e+02
Coefficient D8.10830e+03
Temperature range, min.160.00
Temperature range, max.1000.00
λgas 0.01 W/m×K 160.00 Calculated Property
λgas 0.01 W/m×K 253.33 Calculated Property
λgas 0.02 W/m×K 346.67 Calculated Property
λgas 0.03 W/m×K 440.00 Calculated Property
λgas 0.04 W/m×K 533.33 Calculated Property
λgas 0.05 W/m×K 626.67 Calculated Property
λgas 0.06 W/m×K 720.00 Calculated Property
λgas 0.07 W/m×K 813.33 Calculated Property
λgas 0.08 W/m×K 906.67 Calculated Property
λgas 0.09 W/m×K 1000.00 Calculated Property
Property Value Unit Temperature (K) Source
λliquid [0.22; 0.10] W/m×K [123.15; 393.15] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is λliquid in W/m×K, T in K
Coefficient A2.90030e-02
Coefficient B3.41240e+01
Coefficient C-1.93560e+00
Coefficient D1.02950e-03
Coefficient E-7.99390e-06
Temperature range, min.123.15
Temperature range, max.393.15
λliquid 0.22 W/m×K 123.15 Calculated Property
λliquid 0.20 W/m×K 153.15 Calculated Property
λliquid 0.19 W/m×K 183.15 Calculated Property
λliquid 0.18 W/m×K 213.15 Calculated Property
λliquid 0.16 W/m×K 243.15 Calculated Property
λliquid 0.15 W/m×K 273.15 Calculated Property
λliquid 0.13 W/m×K 303.15 Calculated Property
λliquid 0.12 W/m×K 333.15 Calculated Property
λliquid 0.11 W/m×K 363.15 Calculated Property
λliquid 0.10 W/m×K 393.15 Calculated Property

Similar Compounds

Ethyl, 1-methoxy-. Ethyl ether. Ethane, (chloromethoxy)-. Acetonitrile, ethoxy-. Formic-d acid,ethylester. Ethyl formate. Ethane, 1,2-dimethoxy-. Ethane, 1-bromo-2-methoxy-. 2-Chloroethyl methyl ether. Acetaldehyde, methoxy-. propargylethyl ether. 2,5-Dioxaheptane. Ethanol, 2-methoxy-. Ethane, 1,1'-[methylenebis(oxy)]bis-. 2-Ethoxyethyl bromide.

Find more compounds similar to Ethane, methoxy-.

Sources

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