Chemical Properties of 1,3-Dioxolane (CAS 646-06-0)

1,3-Dioxolane

InChI
InChI=1S/C3H6O2/c1-2-5-3-4-1/h1-3H2
InChI Key
WNXJIVFYUVYPPR-UHFFFAOYSA-N
Formula
C3H6O2
SMILES
C1COCO1
Molecular Weight1
74.08
CAS
646-06-0
Other Names
  • 1,3-Dioxole, dihydro-
  • 1,3-dioxacyclopentane
  • 1,3-dioxolan
  • Dioxolan
  • Dioxolane
  • Ethylene glycol formal
  • Formal glycol
  • Glycolformal
  • dihydro-1,3-dioxole
  • ethylene glycol methylene ether
  • formaldehyde ethylene acetal
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Physical Properties

Property Value Unit Source
ω 0.2707 Relay (1.0) Calculated Property
Δcliquid [-1705.00; -1700.00] kJ/mol Show Hide
Δcliquid -1700.80 ± 1.40 kJ/mol NIST
Δcliquid -1700.00 kJ/mol NIST
Δcliquid -1705.00 kJ/mol NIST
Cp,liquid 121.66 J/mol×K Thermodynamics of Mixtures Involving Some Linear or Cyclic Ketones and Cyclic Ethers. 4. Systems Containing 1,3-Dioxolane
η 0.0005310 Pa×s Excess Molar Volumes and Viscosity Deviations of Binary Liquid Mixtures of 1,3-Dioxolane and 1,4-Dioxane with Butyl Acetate, Butyric Acid, Butylamine, and 2-Butanone at 298.15 K
Δf -153.60 kJ/mol Joback Calculated Property
Δfgas -301.70 ± 2.20 kJ/mol NIST
Δfliquid -337.20 ± 1.40 kJ/mol NIST
Δfus 12.35 kJ/mol Joback Calculated Property
Δvap [35.50; 36.00] kJ/mol Show Hide
Δvap 35.50 kJ/mol NIST
Δvap 36.00 ± 0.40 kJ/mol NIST
IE [9.90; 10.10] eV Show Hide
IE 9.90 eV NIST
IE 10.02 eV NIST
IE 10.10 eV NIST
logPoct/wat -0.009 Crippen Calculated Property
McVol 54.010 ml/mol McGowan Calculated Property
Pc 5818.28 kPa Joback Calculated Property
Inp [582.00; 638.00]   Show Hide
Inp 638.00 NIST
Inp 594.00 NIST
Inp 597.00 NIST
Inp 582.00 NIST
Inp 593.00 NIST
Inp 590.00 NIST
Inp 608.00 NIST
Inp 592.00 NIST
Inp 592.00 NIST
Inp 635.00 NIST
Inp 597.00 NIST
Inp 635.00 NIST
I 935.00 NIST
gas 310.50 ± 4.10 J/mol×K NIST
liquid 280.20 J/mol×K NIST
Tboil [339.12; 348.75] K Show Hide
Tboil 339.12 K Study of isobaric vapour liquid equilibrium of some cyclic ethers with 1-chloropropane: Experimental results and SAFT-VR modelling
Tboil 348.57 K Vapor-Liquid Equilibrium Data for Methanol + 1,3-Dioxolane + Water and Constituent Binary Systems at 101.3 kPa.
Tboil 348.00 K Study of Solution Properties of Some Alkali Bromides in Aqueous Binary Mixtures of 1,3-Dioxolane in View of Different Models
Tboil 347.70 K NIST
Tboil 348.75 K NIST
Tc 532.03 K Relay (1.0) Calculated Property
Tfus [175.85; 175.90] K Show Hide
Tfus 175.85 K NIST
Tfus 175.90 ± 0.60 K NIST
Ttriple 175.93 ± 0.02 K NIST
Vc 0.197 m3/kmol Relay (1.0) Calculated Property

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Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,gas [87.73; 133.05] J/mol×K [341.89; 543.20] Show Hide
Cp,gas 87.73 J/mol×K 341.89 Joback Calculated Property
Cp,gas 96.41 J/mol×K 375.44 Joback Calculated Property
Cp,gas 104.62 J/mol×K 408.99 Joback Calculated Property
Cp,gas 112.37 J/mol×K 442.54 Joback Calculated Property
Cp,gas 119.68 J/mol×K 476.09 Joback Calculated Property
Cp,gas 126.57 J/mol×K 509.65 Joback Calculated Property
Cp,gas 133.05 J/mol×K 543.20 Joback Calculated Property
Cp,liquid [118.00; 129.50] J/mol×K [288.15; 328.15] Show Hide
Cp,liquid 118.80 J/mol×K 288.15 Thermophysical properties of dimethyl sulfoxide + cyclic and linear ethers at 308.15K Application of an extended cell model
Cp,liquid 120.30 J/mol×K 293.15 Thermophysical properties of dimethyl sulfoxide + cyclic and linear ethers at 308.15K Application of an extended cell model
Cp,liquid 118.00 J/mol×K 298.00 NIST
Cp,liquid 121.70 J/mol×K 298.15 Thermophysical properties of dimethyl sulfoxide + cyclic and linear ethers at 308.15K Application of an extended cell model
Cp,liquid 120.84 J/mol×K 298.15 NIST
Cp,liquid 123.30 J/mol×K 303.15 Thermophysical properties of dimethyl sulfoxide + cyclic and linear ethers at 308.15K Application of an extended cell model
Cp,liquid 124.40 J/mol×K 308.15 Thermophysical properties of dimethyl sulfoxide + cyclic and linear ethers at 308.15K Application of an extended cell model
Cp,liquid 125.30 J/mol×K 313.15 Thermophysical properties of dimethyl sulfoxide + cyclic and linear ethers at 308.15K Application of an extended cell model
Cp,liquid 126.80 J/mol×K 318.15 Thermophysical properties of dimethyl sulfoxide + cyclic and linear ethers at 308.15K Application of an extended cell model
Cp,liquid 128.10 J/mol×K 323.15 Thermophysical properties of dimethyl sulfoxide + cyclic and linear ethers at 308.15K Application of an extended cell model
Cp,liquid 129.50 J/mol×K 328.15 Thermophysical properties of dimethyl sulfoxide + cyclic and linear ethers at 308.15K Application of an extended cell model
η [0.0004580; 0.0005878] Pa×s [298.15; 318.15] Show Hide
η 0.0005878 Pa×s 298.15 Studies on Thermodynamic and Transport Properties of Binary Mixtures of Acetonitrile with Some Cyclic Ethers at Different Temperatures by Volumetric, Viscometric, and Interferometric Techniques
η 0.0005128 Pa×s 308.15 Studies on Thermodynamic and Transport Properties of Binary Mixtures of Acetonitrile with Some Cyclic Ethers at Different Temperatures by Volumetric, Viscometric, and Interferometric Techniques
η 0.0004580 Pa×s 318.15 Studies on Thermodynamic and Transport Properties of Binary Mixtures of Acetonitrile with Some Cyclic Ethers at Different Temperatures by Volumetric, Viscometric, and Interferometric Techniques
ΔfusH [2.68; 6.57] kJ/mol [142.40; 175.90] Show Hide
ΔfusH 2.68 kJ/mol 142.40 NIST
ΔfusH 6.57 kJ/mol 175.90 NIST
ΔfusH 6.57 kJ/mol 175.90 NIST
ΔvapH [33.70; 35.80] kJ/mol [301.50; 339.00] Show Hide
ΔvapH 35.80 kJ/mol 301.50 NIST
ΔvapH 34.10 kJ/mol 317.50 NIST
ΔvapH 34.60 kJ/mol 326.00 NIST
ΔvapH 33.70 kJ/mol 326.00 NIST
ΔvapH 33.70 kJ/mol 339.00 NIST
ν [0.0000005; 0.0000007] m2/s [283.15; 313.15] Show Hide
ν 0.0000007 m2/s 283.15 Experimental and predicted viscosities of binary mixtures of cyclic ethers with 1-chloropentane or 1-chlorohexane at 283.15, 298.15, and 313.15K
ν 0.0000006 m2/s 298.15 Experimental and predicted viscosities of binary mixtures of cyclic ethers with 1-chloropentane or 1-chlorohexane at 283.15, 298.15, and 313.15K
ν 0.0000005 m2/s 313.15 Experimental and predicted viscosities of binary mixtures of cyclic ethers with 1-chloropentane or 1-chlorohexane at 283.15, 298.15, and 313.15K
Pvap [5.42; 49.01] kPa [280.46; 328.15] Show Hide
Pvap 5.42 kPa 280.46 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap 6.20 kPa 282.96 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap 7.14 kPa 285.51 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap 7.91 kPa 287.44 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap 10.78 kPa 293.48 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap 13.59 kPa 298.12 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap 13.54 kPa 298.15 Isothermal vapour-liquid equilibrium for cyclic ethers with 1-chloropentane
Pvap 13.54 kPa 298.15 Isothermal (vapour + liquid) equilibrium of (cyclic ethers + chlorohexane) mixtures: Experimental results and SAFT modelling
Pvap 15.69 kPa 301.25 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap 17.05 kPa 303.00 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap 19.15 kPa 305.57 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap 23.08 kPa 309.76 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap 26.83 kPa 313.15 Isothermal vapour-liquid equilibrium for cyclic ethers with 1-chloropentane
Pvap 26.73 kPa 313.16 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap 31.18 kPa 316.81 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap 49.01 kPa 328.15 Isothermal (vapour + liquid) equilibrium of (cyclic ethers + chlorohexane) mixtures: Experimental results and SAFT modelling
Pvap 49.01 kPa 328.15 Isothermal vapour-liquid equilibrium for cyclic ethers with 1-chloropentane
n0 [1.39740; 1.39800]   [298.15; 298.15] Show Hide
n0 1.39800 298.15 Studies on liquid liquid interactions of some ternary mixtures by density, viscosity, ultrasonic speed and refractive index measurements
n0 1.39740 298.15 Physics and Chemistry of Lithium Halides in 1,3-Dioxolane and Its Binary Mixtures with Acetonitrile probed by Conductometric, Volumetric, Viscometric, Refractometric and Acoustic Study
n0 1.39779 298.15 Vapor-Liquid Equilibria for Binary and Ternary Mixtures of 1,3-Dioxolane, 2-Propanol, and 2,2,4-Trimethylpentane at 101.3 kPa
ρl [1046.30; 1059.00] kg/m3 [298.15; 308.15] Show Hide
ρl 1059.00 kg/m3 298.15 Vapour liquid equilibrium of cyclic ethers with 1-chlorohexane: Experimental results and UNIFAC predictions
ρl 1058.73 kg/m3 298.15 Ionic solvation of tetrabutylammonium hexafluorophosphate in pure nitromethane, 1, 3-dioxolane and nitrobenzene: A comparative physicochemical study
ρl 1058.62 kg/m3 298.15 (Vapour + liquid) equilibrium of binary mixtures (1,3-dioxolane or 1,4-dioxane + 2-methyl-1-propanol or 2-methyl-2-propanol) at isobaric conditions
ρl 1058.62 kg/m3 298.15 Surface study of mixtures containing cyclic ethers and isomeric chlorobutanes
ρl 1058.70 kg/m3 298.15 Probing subsistence of ion-pair and triple-ion of an ionic salt in liquid environments by means of conductometric contrivance
ρl 1047.20 kg/m3 298.15 Thermodynamic properties of liquid mixtures containing 1,3-dioxolane and anilines: Excess molar volumes, excess molar enthalpies, excess Gibb's free energy and isentropic compressibilities changes of mixing
ρl 1058.76 kg/m3 298.15 Isothermal Vapor-Liquid Equilibria and Excess Gibbs Energies for Binary Mixtures of Cyclic Ethers with 1,2-Dichloroethane
ρl 1058.62 kg/m3 298.15 Experimental and predicted viscosities of the ternary mixture (hexane + 1,3-dioxolane + 2-butanol) at 298.15 and 313.15 K
ρl 1058.90 kg/m3 298.15 Densities, Speeds of Sound, Excess Molar Enthalpies, and Heat Capacities of o-Chlorotoluene and Cyclic Ether Mixtures
ρl 1051.80 kg/m3 303.15 Viscous synergy and antagonism and isentropic compressibility of ternary mixtures containing 1,3-dioxolane, water and monoalkanols at 303.15K
ρl 1052.60 kg/m3 303.15 Densities, Speeds of Sound, Excess Molar Enthalpies, and Heat Capacities of o-Chlorotoluene and Cyclic Ether Mixtures
ρl 1046.30 kg/m3 308.15 Densities, Speeds of Sound, Excess Molar Enthalpies, and Heat Capacities of o-Chlorotoluene and Cyclic Ether Mixtures
ΔfusS [18.80; 37.33] J/mol×K [142.40; 175.90] Show Hide
ΔfusS 18.80 J/mol×K 142.40 NIST
ΔfusS 37.33 J/mol×K 175.90 NIST
csound,fluid [1270.90; 1406.30] m/s [283.15; 313.15] Show Hide
csound,fluid 1406.30 m/s 283.15 Speeds of Sound and Isentropic Compressibilities for Binary Mixtures of a Cyclic Diether with a Cyclic Compound at Three Temperatures
csound,fluid 1339.90 m/s 298.15 Speeds of Sound and Isentropic Compressibilities for Binary Mixtures of a Cyclic Diether with a Cyclic Compound at Three Temperatures
csound,fluid 1340.20 m/s 298.15 Densities and speeds of sound for binary mixtures of (1,3-dioxolane or 1,4-dioxane) with (2-methyl-1-propanol or 2-methyl-2-propanol) at the temperatures 298.15 K and 313.15 K
csound,fluid 1271.60 m/s 313.15 Speeds of Sound and Isentropic Compressibilities for Binary Mixtures of a Cyclic Diether with a Cyclic Compound at Three Temperatures
csound,fluid 1270.90 m/s 313.15 Densities and speeds of sound for binary mixtures of (1,3-dioxolane or 1,4-dioxane) with (2-methyl-1-propanol or 2-methyl-2-propanol) at the temperatures 298.15 K and 313.15 K
γ [0.03; 0.03] N/m [288.15; 308.15] Show Hide
γ 0.03 N/m 288.15 Densities, Viscosities, Refractive Indices, and Surface Tensions for the Mixtures of 1,3-Dioxolane + 2-Propanol or + 2,2,4-Trimethylpentane at (288.15, 298.15, and 308.15) K and 1,3-Dioxolane + 2-Propanol + 2,2,4-Trimethylpentane at 298.15 K
γ 0.03 N/m 298.15 Densities, Viscosities, Refractive Indices, and Surface Tensions for the Mixtures of 1,3-Dioxolane + 2-Propanol or + 2,2,4-Trimethylpentane at (288.15, 298.15, and 308.15) K and 1,3-Dioxolane + 2-Propanol + 2,2,4-Trimethylpentane at 298.15 K
γ 0.03 N/m 308.15 Densities, Viscosities, Refractive Indices, and Surface Tensions for the Mixtures of 1,3-Dioxolane + 2-Propanol or + 2,2,4-Trimethylpentane at (288.15, 298.15, and 308.15) K and 1,3-Dioxolane + 2-Propanol + 2,2,4-Trimethylpentane at 298.15 K

Correlations

Property Value Unit Temperature (K) Source
Pvap [1.33; 214.40] kPa [256.45; 372.15] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Pvp) = A + B/(T + C)
Coefficient A1.46333e+01
Coefficient B-3.02711e+03
Coefficient C-4.54420e+01
Temperature range, min.256.45
Temperature range, max.372.15
Pvap 1.33 kPa 256.45 Calculated Property
Pvap 3.04 kPa 269.31 Calculated Property
Pvap 6.33 kPa 282.16 Calculated Property
Pvap 12.23 kPa 295.02 Calculated Property
Pvap 22.16 kPa 307.87 Calculated Property
Pvap 37.98 kPa 320.73 Calculated Property
Pvap 62.03 kPa 333.58 Calculated Property
Pvap 97.16 kPa 346.44 Calculated Property
Pvap 146.69 kPa 359.29 Calculated Property
Pvap 214.40 kPa 372.15 Calculated Property

Similar Compounds

1,3,5-Trioxepane. Ethane, 1,1'-[methylenebis(oxy)]bis-. Ethane, 1,2-dimethoxy-. l,3,6-Trioxocane. 1,3,6,9,11,14-Hexaoxacyclohexadecane. 1,3,6,9,12,14,17,20,22,25,28,31-Dodecaoxacyclotritricontane. 1,3,6,9,12,15,17,20,23,26,29,32-Dodecaoxacyclo-tetratricontane. 1,3,6,9,12,15,17,20,23,26-Decaoxacyclooctacosane. 1,3,6,9,12,14,17,20-Octaoxacyclodocosane. Ether, bis(ethoxymethyl). 1,3-Dioxolane, 2-methyl-. 2-METHOXY-1,3-DIOXOLANE. Methane, bis(2-chloroethoxy)-. Ethane, 1,1,2-trimethoxy-. Ethanol, 2-methoxy-.

Find more compounds similar to 1,3-Dioxolane.

Mixtures

Find more mixtures with 1,3-Dioxolane.

Sources

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