Chemical Properties of D-Limonene (CAS 5989-27-5)

D-Limonene

InChI
InChI=1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m0/s1
InChI Key
XMGQYMWWDOXHJM-JTQLQIEISA-N
Formula
C10H16
SMILES
C=C(C)[C@H]1CC=C(C)CC1
Molecular Weight1
136.24
CAS
5989-27-5
Other Names
  • (+)-(4R)-limonene
  • (+)-(R)-Limonene
  • (+)-(R)-p-mentha-1,8-diene
  • (+)-.alpha.-limonene
  • (+)-4-isopropenyl-1-methylcyclohexene
  • (+)-dipentene
  • (+)-limonene
  • (+)-p-mentha-1,8-diene
  • (4R)-(+)-limonene
  • (4R)-Limonene
  • (R)-(+)-limonene
  • (R)-(+)-p-mentha-1,8-diene
  • (R)-1-methyl-4-(1-methylethenyl)cyclohexene
  • (R)-4-isopropenyl-1-methyl-1-cyclohexene
  • (R)-limonene
  • (R)-p-mentha-1,8-diene
  • 4-Isopropenyl-1-methyl-1-cyclohexene-, (R)-
  • Biogenic SE 374
  • Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4R)-
  • Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (R)-
  • D-(+)-limonene
  • Dextro-limonene
  • EC 7
  • Glidesafe
  • Glidsafe
  • Limonene, (D)-
  • Refchole
  • carvene
  • cyclohexene, 1-methyl-4-(1-methylethenyl)-, (R)-,
  • limonene, (+)-
  • p-mentha-1,8-diene, (R)-(+)-
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Contents

  1. Physical Properties
  2. Temperature Dependent Properties
  3. Datasets
  4. Correlations
  5. Similar Compounds
  6. Mixtures
  7. Sources

Physical Properties

Property Value Unit Source
ΔcH°liquid -6167.20 ± 2.10 kJ/mol NIST
εr 2.38 NCMS SOLV-DB
ΔfH°gas 44.31 kJ/mol Relay (1.0) Calculated Property
ΔfusH° 11.73 kJ/mol Joback Calculated Property
ΔvapH° [48.12; 49.90] kJ/mol Show Hide
ΔvapH° 48.12 kJ/mol NCMS SOLV-DB
ΔvapH° 49.50 kJ/mol NIST
ΔvapH° 49.60 kJ/mol NIST
ΔvapH° 49.90 kJ/mol NIST
ΔvapH° 49.60 kJ/mol NIST
ΔvapH° 48.90 ± 0.10 kJ/mol NIST
IE 8.65 eV Relay (1.0) Calculated Property
log10WS -4.26 Estimated Solubility
logPoct/wat 4.830 NCMS SOLV-DB
McVol 132.300 ml/mol McGowan Calculated Property
NFPA Fire 2 NCMS SOLV-DB
NFPA Health 1 NCMS SOLV-DB
NFPA Safety 0 NCMS SOLV-DB
Tboil [448.00; 452.00] K Show Hide
Tboil 449.15 K NCMS SOLV-DB
Tboil 449.00 K NIST
Tboil 451.00 K NIST
Tboil 449.40 ± 2.00 K NIST
Tboil 448.00 ± 4.00 K NIST
Tboil 451.00 ± 0.50 K NIST
Tboil 451.00 ± 0.50 K NIST
Tboil 451.00 ± 1.00 K NIST
Tboil 449.40 ± 3.00 K NIST
Tboil 451.00 ± 3.00 K NIST
Tboil 449.00 ± 3.00 K NIST
Tboil 451.00 ± 2.00 K NIST
Tboil 449.90 ± 3.00 K NIST
Tboil 449.70 ± 3.00 K NIST
Tboil 449.50 ± 3.00 K NIST
Tboil 452.00 ± 3.00 K NIST
Tboil 449.00 ± 6.00 K NIST
Tboil 448.00 ± 4.00 K NIST
Tboil 449.00 ± 4.00 K NIST
Tc 653.00 K IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 6 Compiled value
Tfus [198.65; 198.85] K Show Hide
Tfus 198.85 K NCMS SOLV-DB
Tfus 198.65 ± 0.15 K NIST
Vc 0.470 m3/kmol IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 6 Compiled value

Cheméo can also estimate Critical Pressure, Standard Gibbs free energy of formation, Acentric Factor for this compound, but they fall outside the models' validated range, so they are not shown here. Open the prediction tool to compute them on demand.

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
η [0.0003820; 0.0010780] Pa×s [283.15; 373.15] Show Hide
η 0.0010780 Pa×s 283.15 Density, Viscosity, and Refractive Index in the Range (283.15 to 353.15) K and Vapor Pressure of r-Pinene, d-Limonene, (()-Linalool, and Citral Over the Pressure Range 1.0 kPa Atmospheric Pressure
η 0.0009020 Pa×s 293.15 Density, viscosity, vapour liquid equilibrium, excess molar enthalpy, and their correlations of the binary system [1-pentanol + R-(+)-limonene] over the complete concentration range, at different temperatures
η 0.0009320 Pa×s 293.15 Density, Viscosity, and Refractive Index in the Range (283.15 to 353.15) K and Vapor Pressure of r-Pinene, d-Limonene, (()-Linalool, and Citral Over the Pressure Range 1.0 kPa Atmospheric Pressure
η 0.0008900 Pa×s 298.15 Density, viscosity, vapour liquid equilibrium, excess molar enthalpy, and their correlations of the binary system [1-pentanol + R-(+)-limonene] over the complete concentration range, at different temperatures
η 0.0009230 Pa×s 298.15 NCMS SOLV-DB
η 0.0008970 Pa×s 298.15 Density, Viscosity, and Refractive Index in the Range (283.15 to 353.15) K and Vapor Pressure of r-Pinene, d-Limonene, (()-Linalool, and Citral Over the Pressure Range 1.0 kPa Atmospheric Pressure
η 0.0007930 Pa×s 303.15 Density, viscosity, vapour liquid equilibrium, excess molar enthalpy, and their correlations of the binary system [1-pentanol + R-(+)-limonene] over the complete concentration range, at different temperatures
η 0.0008160 Pa×s 303.15 Density, Viscosity, and Refractive Index in the Range (283.15 to 353.15) K and Vapor Pressure of r-Pinene, d-Limonene, (()-Linalool, and Citral Over the Pressure Range 1.0 kPa Atmospheric Pressure
η 0.0007020 Pa×s 313.15 Density, viscosity, vapour liquid equilibrium, excess molar enthalpy, and their correlations of the binary system [1-pentanol + R-(+)-limonene] over the complete concentration range, at different temperatures
η 0.0007220 Pa×s 313.15 Density, Viscosity, and Refractive Index in the Range (283.15 to 353.15) K and Vapor Pressure of r-Pinene, d-Limonene, (()-Linalool, and Citral Over the Pressure Range 1.0 kPa Atmospheric Pressure
η 0.0006450 Pa×s 323.15 Density, Viscosity, and Refractive Index in the Range (283.15 to 353.15) K and Vapor Pressure of r-Pinene, d-Limonene, (()-Linalool, and Citral Over the Pressure Range 1.0 kPa Atmospheric Pressure
η 0.0006280 Pa×s 323.15 Density, viscosity, vapour liquid equilibrium, excess molar enthalpy, and their correlations of the binary system [1-pentanol + R-(+)-limonene] over the complete concentration range, at different temperatures
η 0.0005660 Pa×s 333.15 Density, viscosity, vapour liquid equilibrium, excess molar enthalpy, and their correlations of the binary system [1-pentanol + R-(+)-limonene] over the complete concentration range, at different temperatures
η 0.0005800 Pa×s 333.15 Density, Viscosity, and Refractive Index in the Range (283.15 to 353.15) K and Vapor Pressure of r-Pinene, d-Limonene, (()-Linalool, and Citral Over the Pressure Range 1.0 kPa Atmospheric Pressure
η 0.0005000 Pa×s 343.15 Density, viscosity, vapour liquid equilibrium, excess molar enthalpy, and their correlations of the binary system [1-pentanol + R-(+)-limonene] over the complete concentration range, at different temperatures
η 0.0005240 Pa×s 343.15 Density, Viscosity, and Refractive Index in the Range (283.15 to 353.15) K and Vapor Pressure of r-Pinene, d-Limonene, (()-Linalool, and Citral Over the Pressure Range 1.0 kPa Atmospheric Pressure
η 0.0004520 Pa×s 353.15 Density, viscosity, vapour liquid equilibrium, excess molar enthalpy, and their correlations of the binary system [1-pentanol + R-(+)-limonene] over the complete concentration range, at different temperatures
η 0.0004760 Pa×s 353.15 Density, Viscosity, and Refractive Index in the Range (283.15 to 353.15) K and Vapor Pressure of r-Pinene, d-Limonene, (()-Linalool, and Citral Over the Pressure Range 1.0 kPa Atmospheric Pressure
η 0.0004130 Pa×s 363.15 Density, viscosity, vapour liquid equilibrium, excess molar enthalpy, and their correlations of the binary system [1-pentanol + R-(+)-limonene] over the complete concentration range, at different temperatures
η 0.0003820 Pa×s 373.15 Density, viscosity, vapour liquid equilibrium, excess molar enthalpy, and their correlations of the binary system [1-pentanol + R-(+)-limonene] over the complete concentration range, at different temperatures
ΔfusH 11.38 kJ/mol 199.20 NIST
ΔvapH [37.90; 49.20] kJ/mol [305.50; 417.00] Show Hide
ΔvapH 47.70 kJ/mol 305.50 NIST
ΔvapH 49.20 kJ/mol 342.00 NIST
ΔvapH 44.50 kJ/mol 367.50 NIST
ΔvapH 46.10 ± 0.20 kJ/mol 417.00 NIST
ΔvapH 43.50 ± 0.20 kJ/mol 417.00 NIST
ΔvapH 40.90 ± 0.30 kJ/mol 417.00 NIST
ΔvapH 37.90 ± 0.60 kJ/mol 417.00 NIST
Pvap [1.01e-03; 2.67] kPa [238.20; 341.15] Show Hide
Pvap 1.01e-03 kPa 238.20 Thermodynamic study of selected monoterpenes III
Pvap 1.01e-03 kPa 238.20 Thermodynamic study of selected monoterpenes III
Pvap 1.01e-03 kPa 238.20 Thermodynamic study of selected monoterpenes III
Pvap 1.76e-03 kPa 243.20 Thermodynamic study of selected monoterpenes III
Pvap 1.76e-03 kPa 243.20 Thermodynamic study of selected monoterpenes III
Pvap 1.76e-03 kPa 243.20 Thermodynamic study of selected monoterpenes III
Pvap 2.96e-03 kPa 248.15 Thermodynamic study of selected monoterpenes III
Pvap 2.96e-03 kPa 248.15 Thermodynamic study of selected monoterpenes III
Pvap 2.96e-03 kPa 248.15 Thermodynamic study of selected monoterpenes III
Pvap 4.89e-03 kPa 253.15 Thermodynamic study of selected monoterpenes III
Pvap 4.89e-03 kPa 253.15 Thermodynamic study of selected monoterpenes III
Pvap 4.89e-03 kPa 253.15 Thermodynamic study of selected monoterpenes III
Pvap 7.90e-03 kPa 258.15 Thermodynamic study of selected monoterpenes III
Pvap 7.90e-03 kPa 258.15 Thermodynamic study of selected monoterpenes III
Pvap 7.90e-03 kPa 258.15 Thermodynamic study of selected monoterpenes III
Pvap 0.01 kPa 263.15 Thermodynamic study of selected monoterpenes III
Pvap 0.01 kPa 263.15 Thermodynamic study of selected monoterpenes III
Pvap 0.01 kPa 263.15 Thermodynamic study of selected monoterpenes III
Pvap 0.02 kPa 268.15 Thermodynamic study of selected monoterpenes III
Pvap 0.02 kPa 268.15 Thermodynamic study of selected monoterpenes III
Pvap 0.02 kPa 268.15 Thermodynamic study of selected monoterpenes III
Pvap 0.03 kPa 273.15 Thermodynamic study of selected monoterpenes III
Pvap 0.03 kPa 273.15 Thermodynamic study of selected monoterpenes III
Pvap 0.03 kPa 273.15 Thermodynamic study of selected monoterpenes III
Pvap 0.03 kPa 273.65 Thermodynamic study of selected monoterpenes III
Pvap 0.03 kPa 273.65 Thermodynamic study of selected monoterpenes III
Pvap 0.03 kPa 273.65 Thermodynamic study of selected monoterpenes III
Pvap 0.04 kPa 278.15 Thermodynamic study of selected monoterpenes III
Pvap 0.04 kPa 278.15 Thermodynamic study of selected monoterpenes III
Pvap 0.04 kPa 278.15 Thermodynamic study of selected monoterpenes III
Pvap 0.07 kPa 283.15 Thermodynamic study of selected monoterpenes III
Pvap 0.07 kPa 283.15 Thermodynamic study of selected monoterpenes III
Pvap 0.07 kPa 283.15 Thermodynamic study of selected monoterpenes III
Pvap 0.09 kPa 288.15 Thermodynamic study of selected monoterpenes III
Pvap 0.09 kPa 288.15 Thermodynamic study of selected monoterpenes III
Pvap 0.09 kPa 288.15 Thermodynamic study of selected monoterpenes III
Pvap 0.13 kPa 293.15 Thermodynamic study of selected monoterpenes III
Pvap 0.13 kPa 293.15 Thermodynamic study of selected monoterpenes III
Pvap 0.13 kPa 293.15 Thermodynamic study of selected monoterpenes III
Pvap 0.19 kPa 298.15 Thermodynamic study of selected monoterpenes III
Pvap 0.19 kPa 298.15 Thermodynamic study of selected monoterpenes III
Pvap 0.19 kPa 298.15 Thermodynamic study of selected monoterpenes III
Pvap 0.26 kPa 303.15 Thermodynamic study of selected monoterpenes III
Pvap 0.26 kPa 303.15 Thermodynamic study of selected monoterpenes III
Pvap 0.26 kPa 303.15 Thermodynamic study of selected monoterpenes III
Pvap 0.36 kPa 308.15 Thermodynamic study of selected monoterpenes III
Pvap 0.36 kPa 308.15 Thermodynamic study of selected monoterpenes III
Pvap 0.36 kPa 308.15 Thermodynamic study of selected monoterpenes III
Pvap 2.67 kPa 341.15 NCMS SOLV-DB
n0 [1.47000; 1.47300]   [293.20; 298.15] Show Hide
n0 1.47300 293.20 Vapor Liquid Equilibrium Data for Binary Systems of 1-Methyl-4-(1-methylethenyl)-cyclohexene + {Ethanol, Propan-1-ol, Propan-2-ol, Butan-1-ol, Pentan-1-ol, or Hexan-1-ol} at 40 kPa
n0 1.47081 298.15 Deterpenation of Citrus Essential Oil by Liquid-Liquid Extraction with 1-Alkyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)amide Ionic Liquids
n0 1.47000 298.15 NCMS SOLV-DB
ρl [837.31; 841.35] kg/m3 [298.15; 298.20] Show Hide
ρl 838.68 kg/m3 298.15 Improved concentration of citrus essential oil by solvent extraction with acetate ionic liquids
ρl 837.31 kg/m3 298.15 Ternary and quaternary (liquid + liquid) equilibria for (water + ethanol + a-pinene, +b-pinene, or +limonene) and (water + ethanol + a-pinene + limonene) at the temperature 298.15 K
ρl 837.31 kg/m3 298.15 Temperature dependence on mutual solubility of binary (methanol + limonene) mixture and (liquid + liquid) equilibria of ternary (methanol + ethanol + limonene) mixture
ρl 837.31 kg/m3 298.15 Mutual Solubilities of Terpene in Methanol and Water and Their Multicomponent Liquid-Liquid Equilibria
ρl 841.35 kg/m3 298.20 Fractionation of orange essential oil using liquid-liquid extraction: Equilibrium data for model and real systems at 298.2 K.
ρl 840.73 kg/m3 298.20 Deterpenation of Citrus Essential Oils Using Glycerol-Based Deep Eutectic Solvents
ρl 841.35 kg/m3 298.20 Physical Behavior of the Phases from the Liquid-Liquid Equilibrium of Citrus Essential Oils Systems at 298.2 K
γ 0.03 N/m 298.15 NCMS SOLV-DB

Datasets

Mass density, kg/m3

Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Mass density, kg/m3 - Liquid
283.15 20000.00 862.0
283.15 25000.00 864.9
283.15 30000.00 867.7
283.15 35000.00 870.4
283.15 40000.00 873.3
298.15 20000.00 851.5
298.15 25000.00 854.5
298.15 30000.00 857.6
298.15 35000.00 860.9
298.15 40000.00 863.4
313.15 20000.00 841.0
313.15 25000.00 844.2
313.15 30000.00 847.2
313.15 35000.00 850.3
313.15 40000.00 853.3
328.15 20000.00 830.5
328.15 25000.00 833.8
328.15 30000.00 837.2
328.15 35000.00 840.4
328.15 40000.00 843.8
343.15 20000.00 820.1
343.15 25000.00 823.7
343.15 30000.00 827.3
343.15 35000.00 831.1
343.15 40000.00 834.6
358.15 20000.00 810.2
358.15 25000.00 813.9
358.15 30000.00 817.6
358.15 35000.00 821.3
358.15 40000.00 824.8
Reference
Fixed Measured
Pressure, kPa - Liquid Temperature, K - Liquid Mass density, kg/m3 - Liquid
100.00 298.20 838.59
Reference
Fixed Measured
Pressure, kPa - Liquid Temperature, K - Liquid Mass density, kg/m3 - Liquid
101.80 298.15 838.59
Reference
Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Mass density, kg/m3 - Liquid
298.15 100.00 839.1
Reference
Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Mass density, kg/m3 - Liquid
283.15 20000.00 862.0
283.15 25000.00 864.9
283.15 30000.00 867.7
283.15 35000.00 870.4
283.15 40000.00 873.3
298.15 20000.00 851.5
298.15 25000.00 854.5
298.15 30000.00 857.6
298.15 35000.00 860.9
298.15 40000.00 863.4
313.15 20000.00 841.0
313.15 25000.00 844.2
313.15 30000.00 847.2
313.15 35000.00 850.3
313.15 40000.00 853.3
328.15 20000.00 830.5
328.15 25000.00 833.8
328.15 30000.00 837.2
328.15 35000.00 840.4
328.15 40000.00 843.8
343.15 20000.00 820.1
343.15 25000.00 823.7
343.15 30000.00 827.3
343.15 35000.00 831.1
343.15 40000.00 834.6
358.15 20000.00 810.2
358.15 25000.00 813.9
358.15 30000.00 817.6
358.15 35000.00 821.3
358.15 40000.00 824.8
Reference

Correlations

Property Value Unit Temperature (K) Source
Cp,gas [165.92; 457.19] J/mol×K [273.00; 1000.00] Joback Predicted correlation Show Hide
EquationY = A + B·T + C·T² + D·T³ + E·T⁴
Y is Cp,gas in J/mol×K, T in K
Coefficient A-5.24100e+01
Coefficient B9.40340e-01
Coefficient C-5.46640e-04
Coefficient D1.15900e-07
Coefficient E0.00000e+00
Temperature range, min.273.00
Temperature range, max.1000.00
Cp,gas 165.92 J/mol×K 273.00 Calculated Property
Cp,gas 216.98 J/mol×K 353.78 Calculated Property
Cp,gas 262.50 J/mol×K 434.56 Calculated Property
Cp,gas 302.87 J/mol×K 515.33 Calculated Property
Cp,gas 338.44 J/mol×K 596.11 Calculated Property
Cp,gas 369.58 J/mol×K 676.89 Calculated Property
Cp,gas 396.66 J/mol×K 757.67 Calculated Property
Cp,gas 420.04 J/mol×K 838.44 Calculated Property
Cp,gas 440.10 J/mol×K 919.22 Calculated Property
Cp,gas 457.19 J/mol×K 1000.00 Calculated Property
Property Value Unit Temperature (K) Source
Pvap [1.33; 202.63] kPa [324.43; 480.94] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.42584e+01
Coefficient B-3.89401e+03
Coefficient C-4.57090e+01
Temperature range, min.324.43
Temperature range, max.480.94
Pvap 1.33 kPa 324.43 Calculated Property
Pvap 3.03 kPa 341.82 Calculated Property
Pvap 6.28 kPa 359.21 Calculated Property
Pvap 12.06 kPa 376.60 Calculated Property
Pvap 21.71 kPa 393.99 Calculated Property
Pvap 36.95 kPa 411.38 Calculated Property
Pvap 59.91 kPa 428.77 Calculated Property
Pvap 93.16 kPa 446.16 Calculated Property
Pvap 139.63 kPa 463.55 Calculated Property
Pvap 202.63 kPa 480.94 Calculated Property
Property Value Unit Temperature (K) Source
γ [0.04; 0.01] N/m [176.65; 451.15] Jasper (1972), surface tension of pure liquid compounds Compiled value Show Hide
EquationY = A + B·T + C·T² + D·T³ + E·T⁴
Y is γ in N/m, T in K
Coefficient A5.48756e-02
Coefficient B-9.29000e-05
Coefficient C0.00000e+00
Coefficient D0.00000e+00
Coefficient E0.00000e+00
Temperature range, min.176.65
Temperature range, max.451.15
γ 0.04 N/m 176.65 Calculated Property
γ 0.04 N/m 207.15 Calculated Property
γ 0.03 N/m 237.65 Calculated Property
γ 0.03 N/m 268.15 Calculated Property
γ 0.03 N/m 298.65 Calculated Property
γ 0.02 N/m 329.15 Calculated Property
γ 0.02 N/m 359.65 Calculated Property
γ 0.02 N/m 390.15 Calculated Property
γ 0.02 N/m 420.65 Calculated Property
γ 0.01 N/m 451.15 Calculated Property

Similar Compounds

Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (S)-. Limonene. Limonene. (+)-(7S)-Helmintogermacrene. Helmintogermacrene. (+)-Germacrene A. (R,1E,5E,9E)-1,5,9-Trimethyl-12-(prop-1-en-2-yl)cyclotetradeca-1,5,9-triene. «beta»-Bisabolene. germacrene A. (+)-Axinyssene. Dimyrcene isomer # 3. p-Camphorene. dimyrcene-II. Cyclohexene, 1-methyl-5-(1-methylethenyl)-, (R)-. Cyclohexene, 1-methyl-5-(1-methylethenyl)-.

Find more compounds similar to D-Limonene.

Mixtures

Find more mixtures with D-Limonene.

Sources

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