Chemical Properties of Methane, trifluoro- (CAS 75-46-7)

InChI

InChI=1S/CHF3/c2-1(3)4/h1H

InChI Key

XPDWGBQVDMORPB-UHFFFAOYSA-N

Formula

CHF3

SMILES

FC(F)F

Molecular Weight¹

70.01

CAS

75-46-7

Other Names

• Arcton
• Arcton 1
• CHF3
• FC 23
• FC 23 (fluorocarbon)
• Fluoroform [R23]
• Fluoryl
• Freon 23
• Freon F-23
• Genetron 23
• Genetron HFC23
• HFC 23
• Halocarbon 23
• Propellant 23
• R 23
• R 23 (halocarbon)
• R-23
• REFRIGERANT-23
• Refrigerant 23
• UN 1984
• carbon trifluoride
• fluoroform
• methyl trifluoride
• trifluoromethane

• ω : Acentric Factor.
• PAff : Proton affinity (kJ/mol).
• BasG : Gas basicity (kJ/mol).
• Δ_cH°_gas : Standard gas enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• μ : Dipole Moment (debye).
• η : Dynamic viscosity (Pa×s).
• ε_r : Dielectric Constant (Relative permittivity).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_fusH : Enthalpy of fusion at a given temperature (kJ/mol).
• Δ_subH : Enthalpy of sublimation at a given temperature (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• n₀ : Refractive Index.
• ρ_c : Critical density (kg/m³).
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• Δ_fusS : Entropy of fusion at a given temperature (J/mol×K).
• S°_liquid : Liquid phase molar entropy at standard conditions (J/mol×K).
• γ : Surface Tension (N/m).
• Δ_vapS : Entropy of vaporization at a given temperature (J/mol×K).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• T_triple : Triple Point Temperature (K).
• V_c : Critical Volume (m³/kmol).
• Z_c : Critical Compressibility.
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	[0.2528; 0.2600]
ω	0.2528		PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
ω	0.2600		KDB
PAff	619.50	kJ/mol	NIST
BasG	589.70	kJ/mol	NIST
ΔcH°gas	[-516.30; -71.55]	kJ/mol
ΔcH°gas	-71.55 ± 0.71	kJ/mol	NIST
ΔcH°gas	-516.30	kJ/mol	NIST
μ	1.60	debye	KDB
εr	1.01		NCMS SOLV-DB
ΔfG°	-662.80	kJ/mol	KDB
ΔfH°gas	[-697.50; -690.80]	kJ/mol
ΔfH°gas	-695.85 ± 0.56	kJ/mol	Active Thermochemical Tables 1.112, gas-phase enthalpies of formation Compiled value
ΔfH°gas	-697.50	kJ/mol	KDB
ΔfH°gas	-690.80	kJ/mol	NIST
ΔfH°gas	-695.40 ± 2.70	kJ/mol	NIST
ΔfusH°	4.06	kJ/mol	Joback Calculated Property
ΔvapH°	16.78	kJ/mol	NCMS SOLV-DB
IE	[13.80; 15.50]	eV
IE	13.86	eV	NIST
IE	13.90	eV	NIST
IE	14.19 ± 0.02	eV	NIST
IE	13.86	eV	NIST
IE	13.80	eV	NIST
IE	13.84	eV	NIST
IE	Outlier 15.50	eV	NIST
IE	14.80	eV	NIST
IE	14.80 ± 0.05	eV	NIST
IE	14.80	eV	NIST
logPoct/wat	0.640		NCMS SOLV-DB
McVol	30.260	ml/mol	McGowan Calculated Property
Pc	[4752.14; 5035.85]	kPa
Pc	4800.00	kPa	IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 10 Compiled value
Pc	4752.14	kPa	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Pc	4858.00	kPa	KDB
Pc	4828.00 ± 25.00	kPa	NIST
Pc	4816.20 ± 2.00	kPa	NIST
Pc	Outlier 5035.85 ± 10.13	kPa	NIST
Pc	4836.12 ± 6.89	kPa	NIST
ρc	[516.00; 527.90]	kg/m3
ρc	527.20 ± 2.80	kg/m3	NIST
ρc	527.90 ± 4.90	kg/m3	NIST
ρc	525.80 ± 2.80	kg/m3	NIST
ρc	527.20 ± 0.70	kg/m3	NIST
ρc	Outlier 516.00	kg/m3	NIST
ρc	525.08 ± 3.22	kg/m3	NIST
Inp	[202.00; 202.00]
Inp	202.00		NIST
Inp	202.00		NIST
Inp	202.00		NIST
S°liquid	151.04	J/mol×K	NIST
Tboil	[188.70; 191.15]	K
Tboil	191.00	K	KDB
Tboil	191.15	K	NCMS SOLV-DB
Tboil	188.70	K	NIST
Tboil	191.00 ± 0.05	K	NIST
Tboil	189.00 ± 0.30	K	NIST
Tboil	189.00 ± 0.50	K	NIST
Tc	[298.95; 299.45]	K
Tc	299.00	K	IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 10 Compiled value
Tc	299.05	K	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tc	299.30	K	KDB
Tc	299.06 ± 0.30	K	NIST
Tc	299.30 ± 0.20	K	NIST
Tc	299.01 ± 0.02	K	NIST
Tc	298.95 ± 0.10	K	NIST
Tc	Outlier 299.45 ± 0.10	K	NIST
Tc	299.07	K	NIST
Tc	299.07 ± 0.16	K	NIST
Tfus	[110.20; 117.97]	K
Tfus	115.60	K	Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Tfus	117.97	K	KDB
Tfus	117.95	K	NCMS SOLV-DB
Tfus	110.20 ± 0.20	K	NIST
Tfus	117.97 ± 0.05	K	NIST
Tfus	113.00 ± 0.50	K	NIST
Tfus	117.97 ± 0.05	K	NIST
Ttriple	[117.97; 118.02]	K
Ttriple	118.02	K	Solid Liquid Equilibria for the CO2 + R23 and N2O + R23 Systems
Ttriple	117.98	K	Staveley, Lobo and Calado (1981), triple points Compiled value
Ttriple	117.97 ± 0.02	K	NIST
Ttriple	117.97 ± 0.02	K	NIST
Vc	[0.133; 0.135]	m3/kmol
Vc	0.135	m3/kmol	IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 10 Compiled value
Vc	0.133	m3/kmol	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Vc	0.133	m3/kmol	KDB
Zc	[0.2596370; 0.2600000]
Zc	0.2600000		IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 10 Compiled value
Zc	0.2596370		KDB

Cheméo can also estimate Log10 of Water solubility in mol/l for this compound, but it falls outside the models' validated range, so it is not shown here. Open the prediction tool to compute it on demand.

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	86.44	J/mol×K	190.97	NIST
η	0.0001670	Pa×s	298.15	NCMS SOLV-DB
ΔfusH	[4.06; 4.06]	kJ/mol	[117.97; 118.00]
ΔfusH	4.06	kJ/mol	117.97	NIST
ΔfusH	4.06	kJ/mol	117.97	NIST
ΔfusH	4.06	kJ/mol	118.00	NIST
ΔfusH	4.06	kJ/mol	118.00	NIST
ΔsubH	25.60	kJ/mol	103.50	NIST
ΔvapH	[16.71; 18.10]	kJ/mol	[164.00; 248.00]
ΔvapH	18.10	kJ/mol	164.00	NIST
ΔvapH	18.00	kJ/mol	169.00	NIST
ΔvapH	18.00	kJ/mol	169.00	NIST
ΔvapH	16.71	kJ/mol	190.97	NIST
ΔvapH	16.71	kJ/mol	190.97	NIST
ΔvapH	16.80	kJ/mol	248.00	NIST
Pvap	[34.35; 4709.30]	kPa	[173.86; 298.15]
Pvap	34.35	kPa	173.86	Vapor-liquid and vapor-liquid-liquid equilibrium measurements and correlation of the binary mixtures 2,3,3,3-tetrafluoroprop-1-ene (R1234yf) p (tetrafluoromethane (R14), trifluoromethane (R23), octafluoropropane (R218), nitrogen (R728) and argon (R740)) and ethane (R170) p trifluoromethane (R23)
Pvap	41.46	kPa	177.11	Vapor-liquid and vapor-liquid-liquid equilibrium measurements and correlation of the binary mixtures 2,3,3,3-tetrafluoroprop-1-ene (R1234yf) p (tetrafluoromethane (R14), trifluoromethane (R23), octafluoropropane (R218), nitrogen (R728) and argon (R740)) and ethane (R170) p trifluoromethane (R23)
Pvap	62.33	kPa	183.19	Vapor-liquid and vapor-liquid-liquid equilibrium measurements and correlation of the binary mixtures 2,3,3,3-tetrafluoroprop-1-ene (R1234yf) p (tetrafluoromethane (R14), trifluoromethane (R23), octafluoropropane (R218), nitrogen (R728) and argon (R740)) and ethane (R170) p trifluoromethane (R23)
Pvap	62.29	kPa	183.20	Vapor-liquid and vapor-liquid-liquid equilibrium measurements and correlation of the binary mixtures 2,3,3,3-tetrafluoroprop-1-ene (R1234yf) p (tetrafluoromethane (R14), trifluoromethane (R23), octafluoropropane (R218), nitrogen (R728) and argon (R740)) and ethane (R170) p trifluoromethane (R23)
Pvap	85.40	kPa	188.31	Vapor-Liquid Equilibrium Data for the Ethane + Trifluoromethane System at Temperatures from (188.31 to 243.76) K
Pvap	113.55	kPa	193.19	Vapor-liquid and vapor-liquid-liquid equilibrium measurements and correlation of the binary mixtures 2,3,3,3-tetrafluoroprop-1-ene (R1234yf) p (tetrafluoromethane (R14), trifluoromethane (R23), octafluoropropane (R218), nitrogen (R728) and argon (R740)) and ethane (R170) p trifluoromethane (R23)
Pvap	115.20	kPa	193.28	Vapor-Liquid Equilibrium Data for the Ethane + Trifluoromethane System at Temperatures from (188.31 to 243.76) K
Pvap	153.30	kPa	198.66	Vapor-Liquid Equilibrium Data for the Ethane + Trifluoromethane System at Temperatures from (188.31 to 243.76) K
Pvap	307.80	kPa	212.84	Vapor-Liquid Equilibrium Data for the Ethane + Trifluoromethane System at Temperatures from (188.31 to 243.76) K
Pvap	591.50	kPa	228.50	Vapor-Liquid Equilibrium Data for the Ethane + Trifluoromethane System at Temperatures from (188.31 to 243.76) K
Pvap	600.35	kPa	228.83	Vapor-liquid and vapor-liquid-liquid equilibrium measurements and correlation of the binary mixtures 2,3,3,3-tetrafluoroprop-1-ene (R1234yf) p (tetrafluoromethane (R14), trifluoromethane (R23), octafluoropropane (R218), nitrogen (R728) and argon (R740)) and ethane (R170) p trifluoromethane (R23)
Pvap	707.03	kPa	233.16	Vapor-liquid and vapor-liquid-liquid equilibrium measurements and correlation of the binary mixtures 2,3,3,3-tetrafluoroprop-1-ene (R1234yf) p (tetrafluoromethane (R14), trifluoromethane (R23), octafluoropropane (R218), nitrogen (R728) and argon (R740)) and ethane (R170) p trifluoromethane (R23)
Pvap	1028.00	kPa	243.76	Vapor-Liquid Equilibrium Data for the Ethane + Trifluoromethane System at Temperatures from (188.31 to 243.76) K
Pvap	2176.00	kPa	267.81	Isothermal (vapour + liquid) equilibrium data for binary systems of (n-hexane + CO2 or CHF3)
Pvap	2497.00	kPa	272.86	Isothermal (vapour + liquid) equilibrium data for binary systems of (n-hexane + CO2 or CHF3)
Pvap	2502.79	kPa	273.25	Vapor-liquid and vapor-liquid-liquid equilibrium measurements and correlation of the binary mixtures 2,3,3,3-tetrafluoroprop-1-ene (R1234yf) p (tetrafluoromethane (R14), trifluoromethane (R23), octafluoropropane (R218), nitrogen (R728) and argon (R740)) and ethane (R170) p trifluoromethane (R23)
Pvap	2881.00	kPa	277.90	Isothermal (vapour + liquid) equilibrium data for binary systems of (n-hexane + CO2 or CHF3)
Pvap	3269.00	kPa	282.96	Isothermal (vapour + liquid) equilibrium data for binary systems of (n-hexane + CO2 or CHF3)
Pvap	3242.00	kPa	283.15	(Vapour + liquid) equilibria of the {trifluoromethane (HFC-23) + propane} and {trifluoromethane (HFC-23) + n-butane} systems
Pvap	3246.00	kPa	283.15	(Vapour + liquid) equilibria of the {trifluoromethane (HFC-23) + propane} and {trifluoromethane (HFC-23) + n-butane} systems
Pvap	3707.00	kPa	287.99	Isothermal (vapour + liquid) equilibrium data for binary systems of (n-hexane + CO2 or CHF3)
Pvap	4084.00	kPa	292.02	Isothermal (vapour + liquid) equilibrium data for binary systems of (n-hexane + CO2 or CHF3)
Pvap	4180.00	kPa	293.04	Isothermal (vapour + liquid) equilibrium data for binary systems of (n-hexane + CO2 or CHF3)
Pvap	4162.00	kPa	293.15	(Vapour + liquid) equilibria of the {trifluoromethane (HFC-23) + propane} and {trifluoromethane (HFC-23) + n-butane} systems
Pvap	4158.00	kPa	293.15	(Vapour + liquid) equilibria of the {trifluoromethane (HFC-23) + propane} and {trifluoromethane (HFC-23) + n-butane} systems
Pvap	4171.70	kPa	293.18	Experimental determination of the critical loci for R-23 + (npropane or n-hexane) and R-116 + n-propane binary mixtures
Pvap	4605.00	kPa	297.07	Isothermal (vapour + liquid) equilibrium data for binary systems of (n-hexane + CO2 or CHF3)
Pvap	4709.30	kPa	298.15	Experimental determination of the critical loci for R-23 + (npropane or n-hexane) and R-116 + n-propane binary mixtures
n0	1.21500		298.15	NCMS SOLV-DB
ρl	1246.00	kg/m3	239.00	KDB
ΔfusS	[34.40; 34.40]	J/mol×K	[117.97; 117.97]
ΔfusS	34.40	J/mol×K	117.97	NIST
ΔfusS	34.40	J/mol×K	117.97	NIST
γ	[3.00e-05; 0.01]	N/m	[200.20; 298.15]
γ	0.01	N/m	200.20	KDB
γ	3.00e-05	N/m	298.15	NCMS SOLV-DB
ΔvapS	[87.50; 87.50]	J/mol×K	[190.97; 190.97]
ΔvapS	87.50	J/mol×K	190.97	NIST
ΔvapS	87.50	J/mol×K	190.97	NIST

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[50.99; 95.01]	J/mol×K	[298.00; 1200.00]	NIST
Equation			Y = A + B·t + C·t² + D·t³ + E/t², t = T/1000 Y is Cp,gas in J/mol×K, T in K
Coefficient A			6.46369e+00
Coefficient B			1.85433e+02
Coefficient C			-1.40887e+02
Coefficient D			3.98492e+01
Coefficient E			6.45140e-02
Reference			Chase, 1998
Comment			F=-705.8450, G=218.4579, H=-697.0544; Data last reviewed in June, 1969
Temperature range, min.			298.00
Temperature range, max.			1200.00
Cp,gas	50.99	J/mol×K	298.00	Calculated Property
Cp,gas	60.89	J/mol×K	398.22	Calculated Property
Cp,gas	69.08	J/mol×K	498.44	Calculated Property
Cp,gas	75.71	J/mol×K	598.67	Calculated Property
Cp,gas	80.98	J/mol×K	698.89	Calculated Property
Cp,gas	85.11	J/mol×K	799.11	Calculated Property
Cp,gas	88.35	J/mol×K	899.33	Calculated Property
Cp,gas	90.91	J/mol×K	999.56	Calculated Property
Cp,gas	93.06	J/mol×K	1099.78	Calculated Property
Cp,gas	95.01	J/mol×K	1200.00	Calculated Property
Cp,gas	[94.87; 107.42]	J/mol×K	[1200.00; 6000.00]	NIST
Equation			Y = A + B·t + C·t² + D·t³ + E/t², t = T/1000 Y is Cp,gas in J/mol×K, T in K
Coefficient A			1.00535e+02
Coefficient B			3.93663e+00
Coefficient C			-7.57020e-01
Coefficient D			5.04540e-02
Coefficient E			-1.35168e+01
Reference			Chase, 1998
Comment			F=-759.4546, G=336.4170, H=-697.0544; Data last reviewed in June, 1969
Temperature range, min.			1200.00
Temperature range, max.			6000.00
Cp,gas	94.87	J/mol×K	1200.00	Calculated Property
Cp,gas	100.85	J/mol×K	1733.33	Calculated Property
Cp,gas	103.53	J/mol×K	2266.67	Calculated Property
Cp,gas	105.01	J/mol×K	2800.00	Calculated Property
Cp,gas	105.90	J/mol×K	3333.33	Calculated Property
Cp,gas	106.45	J/mol×K	3866.67	Calculated Property
Cp,gas	106.80	J/mol×K	4400.00	Calculated Property
Cp,gas	107.03	J/mol×K	4933.33	Calculated Property
Cp,gas	107.22	J/mol×K	5466.67	Calculated Property
Cp,gas	107.42	J/mol×K	6000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Pvap	[0.05; 4839.80]	kPa	[117.97; 299.00]	KDB Vapor Pressure Data
Equation			ln(Y) = A + B/T + C·ln(T) + D·T² + E/T² Y is Pvap in kPa, T in K
Coefficient A			7.39171e+01
Coefficient B			-3.58622e+03
Coefficient C			-9.81412e+00
Coefficient D			2.80359e-05
Coefficient E			0.00000e+00
Temperature range, min.			117.97
Temperature range, max.			299.00
Pvap	0.05	kPa	117.97	Calculated Property
Pvap	1.12	kPa	138.08	Calculated Property
Pvap	9.51	kPa	158.20	Calculated Property
Pvap	45.82	kPa	178.31	Calculated Property
Pvap	152.46	kPa	198.43	Calculated Property
Pvap	394.61	kPa	218.54	Calculated Property
Pvap	858.05	kPa	238.66	Calculated Property
Pvap	1650.89	kPa	258.77	Calculated Property
Pvap	2913.63	kPa	278.89	Calculated Property
Pvap	4839.80	kPa	299.00	Calculated Property
Pvap	[2.72; 102.54]	kPa	[145.36; 191.19]	NIST
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.44038e+01
Coefficient B			-1.65346e+03
Coefficient C			-2.20130e+01
Reference			Valentine, Brodale, et al., 1962
Comment			Coefficents calculated by NIST from author's data.
Temperature range, min.			145.36
Temperature range, max.			191.19
Pvap	2.72	kPa	145.36	Calculated Property
Pvap	4.62	kPa	150.45	Calculated Property
Pvap	7.55	kPa	155.54	Calculated Property
Pvap	11.89	kPa	160.64	Calculated Property
Pvap	18.15	kPa	165.73	Calculated Property
Pvap	26.91	kPa	170.82	Calculated Property
Pvap	38.86	kPa	175.91	Calculated Property
Pvap	54.83	kPa	181.01	Calculated Property
Pvap	75.71	kPa	186.10	Calculated Property
Pvap	102.54	kPa	191.19	Calculated Property
Pvap	[2.72; 102.54]	kPa	[145.36; 191.19]	NIST
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.44038e+01
Coefficient B			-1.65346e+03
Coefficient C			-2.20130e+01
Reference			Valentine, Brodale, et al., 1962, 2
Comment			Coefficents calculated by NIST from author's data.
Temperature range, min.			145.36
Temperature range, max.			191.19
Pvap	2.72	kPa	145.36	Calculated Property
Pvap	4.62	kPa	150.45	Calculated Property
Pvap	7.55	kPa	155.54	Calculated Property
Pvap	11.89	kPa	160.64	Calculated Property
Pvap	18.15	kPa	165.73	Calculated Property
Pvap	26.91	kPa	170.82	Calculated Property
Pvap	38.86	kPa	175.91	Calculated Property
Pvap	54.83	kPa	181.01	Calculated Property
Pvap	75.71	kPa	186.10	Calculated Property
Pvap	102.54	kPa	191.19	Calculated Property

Similar Compounds

Find more compounds similar to Methane, trifluoro-.

Mixtures

• Ethane + Methane, trifluoro-
• 1-Hexene + Methane, trifluoro-
• Methane, trifluoro- + Pentane, 3-methyl-
• Nitrous oxide + Methane, trifluoro-
• Methane, trifluoro- + Benzene, octyl-
• Propane + Methane, trifluoro-
• n-Hexane + Methane, trifluoro-
• Butane + Methane, trifluoro-
• Methane, trifluoro- + Methyl Alcohol
• Ethanol + Methane, trifluoro-
• 1-Propanol + Methane, trifluoro-
• Methane, trifluoro- + 1-Butanol
• Methane, trifluoro- + Fenofibrate
• Benzene + Methane, trifluoro-
• Toluene + Methane, trifluoro-
• Methane, trifluoro- + Benzene, 1,3-dimethyl-
• Methane, trifluoro- + Mesitylene
• Methane, trifluoro- + Nonane
• Methane, trifluoro- + Decane
• Undecane + Methane, trifluoro-

Find more mixtures with Methane, trifluoro-.

Sources

• KDB Vapor Pressure Data
• Active Thermochemical Tables 1.112, gas-phase enthalpies of formation ChEDL chemicals 1.5.2, from Active Thermochemical Tables (ATcT), version 1.112, Argonne National Laboratory; Ruscic, B. et al. Active Thermochemical Tables: Thermochemistry for the 21st Century. J. Phys.: Conf. Ser. 2005, 16, 561.
• Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) ChEDL chemicals 1.5.2, from Bradley, J.-C.; Williams, A.; Lang, A. Jean-Claude Bradley Open Melting Point Dataset. Figshare, 2014 (CC0).
• IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 10 ChEDL chemicals 1.5.2, from Marsh, K. N.; Abramson, A.; Ambrose, D.; Morton, D. W.; Nikitin, E.; Tsonopoulos, C.; Young, C. L. Vapor-Liquid Critical Properties of Elements and Compounds. 10. Organic Compounds Containing Halogens. J. Chem. Eng. Data 2007, 52, 1509-1538.
• PSRK revision IV (2005), critical constants and acentric factors of 1000 components ChEDL chemicals 1.5.2, from Horstmann, S.; Jabłoniec, A.; Krafczyk, J.; Fischer, K.; Gmehling, J. PSRK Group Contribution Equation of State: Comprehensive Revision and Extension IV, Including Critical Constants and α-Function Parameters for 1000 Components. Fluid Phase Equilib. 2005, 227, 157-164.
• Staveley, Lobo and Calado (1981), triple points ChEDL chemicals 1.5.2, from Staveley, L. A. K.; Lobo, L. Q.; Calado, J. C. G. Triple-Points of Low Melting Substances and Their Use in Cryogenic Work. Cryogenics 1981, 21, 131-144.
• Crippen Method
• Virial Coefficients from Burnett Measurements for the R23 + N2O System
• Solid Liquid Equilibria for the CO2 + R23 and N2O + R23 Systems
• PVTx measurements for N2O+CH3F, N2O+CH2F2, and N2O+ CHF3 binary systems
• Fluid phase equilibria in the binary system trifluoromethane + 1-phenyloctane
• Solubility of HFCs in lower alcohols
• Solubility of hydrofluorocarbons in aromatic solvents and alcohols: Experimental data and modeling with CPA EoS
• Isothermal vapor-liquid equilibrium data for the trifluoromethane (R23) + 2,3,3,3-tetrafluoroprop-1-ene (R1234yf) system at temperatures from 254 to 348 K
• Vapor-liquid and vapor-liquid-liquid equilibrium measurements and correlation of the binary mixtures 2,3,3,3-tetrafluoroprop-1-ene (R1234yf) p (tetrafluoromethane (R14), trifluoromethane (R23), octafluoropropane (R218), nitrogen (R728) and argon (R740)) and ethane (R170) p trifluoromethane (R23)
• An Isothermal vapour-liquid equilibrium data for the binary systems of CHF3 with (n-nonane, n-decane, or n-undecane) and C2F6 with (n-nonane or n-decane)
• Phase equilibria of the binary systems of fenofibrate and dense gases (carbon dioxide, propane, trifluoromethane)
• (Vapour + liquid) equilibria of the {trifluoromethane (HFC-23) + propane} and {trifluoromethane (HFC-23) + n-butane} systems
• Sorption of trifluoromethane in zeolites and ionic liquid
• Solubilities of hydrofluorocarbons in ionic liquids: Experimental and modelling study
• Solubility of hydrofluorocarbons in phosphonium-based ionic liquids: Experimental and modelling study
• Isothermal (vapour + liquid) equilibrium data for binary systems of (n-hexane + CO2 or CHF3)
• Isothermal vapour-liquid equilibrium data for the binary systems of (CHF3 or C2F6) and n-heptane
• Experimental determination of the critical loci for R-23 + (npropane or n-hexane) and R-116 + n-propane binary mixtures
• Isothermal vapour-liquid equilibrium data for binary systems of (CHF3 or C2F6) with (1-hexene or 3-methylpentane)
• Isothermal Vapor-Liquid Equilibrium Data for Binary Systems of CHF3 or C2F6 with Methylcyclohexane or Toluene
• Vapor-Liquid Equilibrium Data for the Ethane + Trifluoromethane System at Temperatures from (188.31 to 243.76) K
• Vapor-Liquid Equilibria for the Trifluoromethane + 1,1,1,2-Tetrafluoroethane System
• Solubility of Hydrofluorocarbons in Halobenzene Solvents
• Experimental Determination and Modeling of Bubble and Dew Points in the System CO2 + CHF3
• Joback Method
• KDB
• McGowan Method
• NIST Webbook
• NCMS SOLV-DB

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