Mixture of Carbonic acid, dimethyl ester + Water

Datasets

1. Activity coefficient (2)
2. Mole fraction (28)

Activity coefficient of Carbonic acid, dimethyl ester (1) [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of Carbonic acid, dimethyl ester (1) - Liquid
273.35	37.6
283.15	43.8
293.15	46.3
298.15	48.0
303.15	49.3
313.15	50.0
323.15	50.9
333.15	50.3

Activity coefficient of Carbonic acid, dimethyl ester (1) [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of Carbonic acid, dimethyl ester (1) - Liquid
273.35	37.6
283.15	43.8
293.15	46.3
298.15	48.0
303.15	49.3
313.15	50.0
323.15	50.9
333.15	50.3

Mole fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
101.00	313.15	0.0374

Mole fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
101.00	313.15	0.8586

Mole fraction of Carbonic acid, dimethyl ester (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid mixture 1
283.15	0.8910
293.15	0.8740
303.15	0.8490
313.15	0.8250
323.15	0.8000
333.15	0.7700

Mole fraction of Carbonic acid, dimethyl ester (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid mixture 2
283.15	0.0110
293.15	0.0110
303.15	0.0120
313.15	0.0140
323.15	0.0140
333.15	0.0170

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
293.15	0.9675
313.15	0.9680
303.15	0.9672
308.15	0.9675

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
293.15	0.1497
313.15	0.1874
303.15	0.1702
308.15	0.1787

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 1
298.20	0.0332
308.20	0.0402
318.20	0.0516

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 2
298.20	0.8619
308.20	0.8449
318.20	0.8453

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 1
298.20	0.0332
308.20	0.0402
318.20	0.0516

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mass fraction of Water (2) - Liquid mixture 2
298.20	0.8619
308.20	0.8449
318.20	0.8453

Mole fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
101.30	298.15	0.9834

Mole fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
101.30	298.15	0.1300

Mole fraction of Carbonic acid, dimethyl ester (1) [ref]

Operational condition: Pressure, kPa = 100 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid mixture 2
313.15	0.0142
303.15	0.0140
313.15	0.0140
303.15	0.0120

Mole fraction of Carbonic acid, dimethyl ester (1) [ref]

Operational condition: Pressure, kPa = 100 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid mixture 1
313.15	0.8242
303.15	0.8510
313.15	0.8240

Mole fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
101.00	313.15	0.0374

Mole fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
101.00	313.15	0.8586

Mole fraction of Carbonic acid, dimethyl ester (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid mixture 1
283.15	0.8910
293.15	0.8740
303.15	0.8490
313.15	0.8250
323.15	0.8000
333.15	0.7700

Mole fraction of Carbonic acid, dimethyl ester (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid mixture 2
283.15	0.0110
293.15	0.0110
303.15	0.0120
313.15	0.0140
323.15	0.0140
333.15	0.0170

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
293.15	0.9675
313.15	0.9680
303.15	0.9672
308.15	0.9675

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
293.15	0.1497
313.15	0.1874
303.15	0.1702
308.15	0.1787

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 1
298.20	0.0332
308.20	0.0402
318.20	0.0516

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 2
298.20	0.8619
308.20	0.8449
318.20	0.8453

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 1
298.20	0.0332
308.20	0.0402
318.20	0.0516

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mass fraction of Water (2) - Liquid mixture 2
298.20	0.8619
308.20	0.8449
318.20	0.8453

Mole fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
101.30	298.15	0.9834

Mole fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
101.30	298.15	0.1300

Mole fraction of Carbonic acid, dimethyl ester (1) [ref]

Operational condition: Pressure, kPa = 100 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid mixture 2
313.15	0.0142
303.15	0.0140
313.15	0.0140
303.15	0.0120

Mole fraction of Carbonic acid, dimethyl ester (1) [ref]

Operational condition: Pressure, kPa = 100 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Carbonic acid, dimethyl ester (1) - Liquid mixture 1
313.15	0.8242
303.15	0.8510
313.15	0.8240

Sources

• Liquid liquid equlibria of the system dimethyl carbonate + methanol +water at different temperatures
• Activity coefficients and partial molar excess enthalpies at infinite dilution for four esters in water
• Ternary liquid-liquid equilibria and binary excess and deviation properties at constant temperature for mixtures of dimethyl carbonate, anisole, methanol, phenol and water
• Ternary (liquid + liquid) equilibria for (water + 1-propanol + dimethyl carbonate, or diethyl carbonate) systems at several temperatures
• Determination of Ternary Liquid Liquid Equilibria for Dimethyl Carbonate + 2-Methyl-1-propanol or 2-Methyl-2-propanol + Water Systems at T = 303.15 and 313.15 K
• Measurement and Calculation of Liquid Liquid Equilibria of Ternary and Quaternary Systems Containing Water, Propan-1-ol, and 2,2,4-Trimethylpentane (TMP) with 2,2'-Oxybis(propane) (DIPE) or Dimethyl Carbonate (DMC)
• Liquid Phase Equilibria of the Water + Acetic Acid + Dimethyl Carbonate Ternary System at Several Temperatures
• Liquid Phase Equilibria of Water + Formic Acid + Dimethyl Carbonate Ternary System at Several Temperatures

Note: These property values are available through the Cheméo API. A free account gives you an access key.