Mixture of Decamethylcyclopentasiloxane + Heptane

Datasets

1. Excess molar enthalpy (molar enthalpy (3)
2. Excess molar volume, m3/mol

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Fixed			Measured
Mole fraction of Heptane (2) - Liquid	Temperature, K - Liquid	Pressure, kPa - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.5000	298.15	101.00	1.0000

Partial molar enthalpy, kJ/mol of Heptane (2) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Heptane (2) - Liquid	Partial molar enthalpy, kJ/mol of Heptane (2) - Liquid
0.0148	0.8570
0.0268	0.8506
0.0384	0.8370
0.0499	0.8263
0.0719	0.8168
0.0825	0.8070
0.0929	0.7931
0.1031	0.7792
0.1130	0.7832
0.1228	0.7781
0.1323	0.7701
0.1507	0.7571
0.1683	0.7431
0.1853	0.7268
0.2015	0.7154
0.2172	0.6989
0.2322	0.6872
0.4562	0.4633
0.4640	0.4497
0.4716	0.4441
0.4790	0.4385
0.4862	0.4329
0.4932	0.4273
0.5001	0.4186
0.5067	0.4140
0.5132	0.4053
0.5195	0.3996
0.7398	0.1665
0.7423	0.1646
0.7448	0.1667
0.7472	0.1648
0.7496	0.1629
0.7520	0.1600
0.7543	0.1571
0.7565	0.1572
0.7587	0.1523

Partial molar enthalpy, kJ/mol of Decamethylcyclopentasiloxane (1) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Heptane (2) - Liquid	Partial molar enthalpy, kJ/mol of Decamethylcyclopentasiloxane (1) - Liquid
0.2148	0.0211
0.2163	0.0202
0.2178	0.0204
0.2193	0.0215
0.2208	0.0227
0.2223	0.0238
0.2239	0.0240
0.2254	0.0242
0.2271	0.0253
0.2287	0.0245
0.2303	0.0247
0.4952	0.1918
0.4975	0.1940
0.4999	0.1972
0.5022	0.1983
0.5046	0.2015
0.5070	0.2026
0.5095	0.2068
0.5119	0.2100
0.5144	0.2111
0.5169	0.2103
0.7346	0.6204
0.7374	0.6275
0.7402	0.6307
0.7430	0.6368
0.7459	0.6500
0.7488	0.6571
0.7517	0.6673
0.7546	0.6734
0.7576	0.6676
0.7605	0.6707
0.8898	1.2116
0.8939	1.2277
0.8980	1.2569
0.9022	1.276
0.9064	1.3122
0.9107	1.3353
0.9150	1.3615
0.9193	1.3836
0.9237	1.4097
0.9281	1.4389
0.9326	1.462
0.9371	1.4811
0.9417	1.5012
0.9509	1.5755
0.9556	1.6016
0.9603	1.6347
0.9651	1.6738
0.9700	1.7129
0.9748	1.719
0.9798	1.7811
0.9847	1.8032
0.9898	1.8393

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Heptane (2) - Liquid	Excess molar volume, m3/mol - Liquid
0.1411	1.3300e-07
0.2809	1.8900e-07
0.3875	2.2000e-07
0.4981	2.3000e-07
0.5974	2.6300e-07
0.6967	2.5700e-07
0.7773	2.3500e-07
0.8618	1.7800e-07
0.9101	1.4000e-07
0.9566	6.9000e-08

Sources

• Thermodynamic Study of Heptane + Silicone Mixtures. Excess Volumes and Enthalpies at 298.15 K