Chemical Properties of Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II) (CAS 14040-05-2)

Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II)

InChI
InChI=1S/2C11H20O2.Cu/c2*1-10(2,3)8(12)7-9(13)11(4,5)6;/h2*7,12H,1-6H3;/q;;+2/p-2/b2*8-7-;
InChI Key
VCIKJQZFNVXWPF-ATMONBRVSA-L
Formula
C22H38CuO4
SMILES
CC(C)(C)C(=O)C=C([O-])C(C)(C)C.CC(C)(C)C(=O)C=C([O-])C(C)(C)C.[Cu]
Molecular Weight1
430.08
CAS
14040-05-2
Other Names
  • Copper dipivaloylmethane
  • Copper, bis(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O')-
  • Copper,bis(3,5-heptanedionato-2,2,6,6-tetramethyl)
  • copper, bis(2,2,6,6-tetramethyl-3,5-heptanedionato-O3,O5)-
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Physical Properties

Property Value Unit Source
Δsub [122.80; 129.10] kJ/mol Show Hide
Δsub 129.10 ± 0.80 kJ/mol NIST
Δsub 122.80 ± 6.50 kJ/mol NIST
IE 7.40 eV NIST

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Temperature Dependent Properties

Property Value Unit Temperature (K) Source
ΔsubH [74.80; 127.60] kJ/mol [351.00; 448.00] Show Hide
ΔsubH 127.20 ± 1.70 kJ/mol 351.00 NIST
ΔsubH 127.60 ± 0.40 kJ/mol 361.00 NIST
ΔsubH 124.50 ± 0.80 kJ/mol 372.00 NIST
ΔsubH 100.00 kJ/mol 403.50 NIST
ΔsubH 124.60 kJ/mol 407.00 NIST
ΔsubH 74.80 kJ/mol 415.00 NIST
ΔsubH 123.60 kJ/mol 445.50 NIST
ΔsubH 120.00 kJ/mol 448.00 NIST
ΔvapH 77.80 ± 0.80 kJ/mol 493.50 NIST
Psub [4.00e-05; 2.37e-03] kPa [375.00; 435.00] Show Hide
Psub 4.00e-05 kPa 375.00 Vapor pressure, kinetics and enthalpy of sublimation of bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II)
Psub 7.20e-05 kPa 385.00 Vapor pressure, kinetics and enthalpy of sublimation of bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II)
Psub 1.51e-04 kPa 395.00 Vapor pressure, kinetics and enthalpy of sublimation of bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II)
Psub 3.43e-04 kPa 404.00 Vapor pressure, kinetics and enthalpy of sublimation of bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II)
Psub 7.20e-04 kPa 415.00 Vapor pressure, kinetics and enthalpy of sublimation of bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II)
Psub 1.46e-03 kPa 425.00 Vapor pressure, kinetics and enthalpy of sublimation of bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II)
Psub 2.37e-03 kPa 435.00 Vapor pressure, kinetics and enthalpy of sublimation of bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II)

Similar Compounds

Nickel, bis(3,5-heptanedionato-o,o'-2,2,6,6-tetramethyl)-. Ytterbium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O')-, (OC-6-11)-. Praseodymium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O')-, (OC-6-11)-. Europium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato)-. Tris(2,2,6,6-tetramethylheptane-3,5-dionato)yttrium(III). Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)cobalt. Rhodium, 2,2,6,6-tetramethylheptan-3,5-dionato-O,O')-bis«eta»2-ethene. Copper, bis(2,2,6-trimethyl-3,5-heptanedionato-O,O')-. Copper, bis(2,6-dimethyl-3,5-heptanedionato-O,O')-, (sp-4-1)-. 5-Hydroxy-2,2,6,6-tetramethyl-4-cyclohexene-1,3-dione. 4-Hepten-3-one, 5-hydroxy-2,6-dimethyl-. 1,5-Heptadien-4-one, 3,3,6-trimethyl-. 2,2,6-Trimethyl-6-vinyl dihydropyran-3-one. 2-Cyclohexen-1-one, 4,4,6-trimethyl-. 2,4,4-Trimethyl-3-carboxaldehyde-5-hydroxy-2,5-cyclohexadiene-1-one.

Find more compounds similar to Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II).

Mixtures

Sources

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