Chemical Properties of lithium iodide (CAS 10377-51-2)

InChI

InChI=1S/HI.Li/h1H;/q;+1/p-1

InChI Key

HSZCZNFXUDYRKD-UHFFFAOYSA-M

Formula

ILi

SMILES

[I-].[Li+]

Molecular Weight¹

133.84

CAS

10377-51-2

• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• C_p,solid : Solid phase heat capacity (J/mol×K).
• EA : Electron affinity (eV).
• IE : Ionization energy (eV).
• P_vap : Vapor pressure (kPa).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
EA	[0.75; 1.12]	eV
EA	0.75 ± 0.04	eV	NIST
EA	1.12	eV	NIST
IE	[7.50; 8.60]	eV
IE	7.50	eV	NIST
IE	8.60 ± 0.30	eV	NIST
IE	8.55 ± 0.15	eV	NIST
IE	8.44 ± 0.03	eV	NIST

Cheméo can also estimate Normal Boiling Point Temperature, Normal melting (fusion) point, Critical Temperature, Critical Pressure, Critical Volume, Enthalpy of formation at standard conditions, Enthalpy of vaporization at standard conditions, Standard Gibbs free energy of formation, Acentric Factor, Log10 of Water solubility in mol/l for this compound, but they fall outside the models' validated range, so they are not shown here. Open the prediction tool to compute them on demand.

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[39.14; 41.68]	J/mol×K	[2500.00; 6000.00]	NIST
Equation			Y = A + B·t + C·t² + D·t³ + E/t², t = T/1000 Y is Cp,gas in J/mol×K, T in K
Coefficient A			3.70580e+01
Coefficient B			1.01160e+00
Coefficient C			-8.21900e-02
Coefficient D			7.00900e-03
Coefficient E			-2.52429e-01
Reference			Chase, 1998
Comment			F=-102.9415, G=275.3771, H=-91.00200; Data last reviewed in June, 1966
Temperature range, min.			2500.00
Temperature range, max.			6000.00
Cp,gas	39.14	J/mol×K	2500.00	Calculated Property
Cp,gas	39.43	J/mol×K	2888.89	Calculated Property
Cp,gas	39.71	J/mol×K	3277.78	Calculated Property
Cp,gas	39.99	J/mol×K	3666.67	Calculated Property
Cp,gas	40.26	J/mol×K	4055.56	Calculated Property
Cp,gas	40.53	J/mol×K	4444.44	Calculated Property
Cp,gas	40.81	J/mol×K	4833.33	Calculated Property
Cp,gas	41.09	J/mol×K	5222.22	Calculated Property
Cp,gas	41.38	J/mol×K	5611.11	Calculated Property
Cp,gas	41.68	J/mol×K	6000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[63.18; 63.18]	J/mol×K	[742.00; 2500.00]	NIST
Equation			Y = A + B·t + C·t² + D·t³ + E/t², t = T/1000 Y is Cp,liquid in J/mol×K, T in K
Coefficient A			6.31780e+01
Coefficient B			-5.68576e-10
Coefficient C			4.08052e-10
Coefficient D			-8.94250e-11
Coefficient E			-1.00439e-11
Reference			Chase, 1998
Comment			F=-277.1854, G=175.0669, H=-258.3494; Data last reviewed in June, 1966
Temperature range, min.			742.00
Temperature range, max.			2500.00
Cp,liquid	63.18	J/mol×K	742.00	Calculated Property
Cp,liquid	63.18	J/mol×K	937.33	Calculated Property
Cp,liquid	63.18	J/mol×K	1132.67	Calculated Property
Cp,liquid	63.18	J/mol×K	1328.00	Calculated Property
Cp,liquid	63.18	J/mol×K	1523.33	Calculated Property
Cp,liquid	63.18	J/mol×K	1718.67	Calculated Property
Cp,liquid	63.18	J/mol×K	1914.00	Calculated Property
Cp,liquid	63.18	J/mol×K	2109.33	Calculated Property
Cp,liquid	63.18	J/mol×K	2304.67	Calculated Property
Cp,liquid	63.18	J/mol×K	2500.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Cp,solid	[50.07; 63.88]	J/mol×K	[298.00; 742.00]	NIST
Equation			Y = A + B·t + C·t² + D·t³ + E/t², t = T/1000 Y is Cp,solid in J/mol×K, T in K
Coefficient A			1.01507e+02
Coefficient B			-1.92294e+02
Coefficient C			2.85820e+02
Coefficient D			-1.21613e+02
Coefficient E			-1.44711e+00
Reference			Chase, 1998
Comment			F=-298.9757, G=246.0527, H=-270.0772; Data last reviewed in June, 1966
Temperature range, min.			298.00
Temperature range, max.			742.00
Cp,solid	50.07	J/mol×K	298.00	Calculated Property
Cp,solid	52.11	J/mol×K	347.33	Calculated Property
Cp,solid	53.41	J/mol×K	396.67	Calculated Property
Cp,solid	54.53	J/mol×K	446.00	Calculated Property
Cp,solid	55.71	J/mol×K	495.33	Calculated Property
Cp,solid	57.03	J/mol×K	544.67	Calculated Property
Cp,solid	58.54	J/mol×K	594.00	Calculated Property
Cp,solid	60.21	J/mol×K	643.33	Calculated Property
Cp,solid	62.01	J/mol×K	692.67	Calculated Property
Cp,solid	63.88	J/mol×K	742.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Pvap	[0.13; 101.33]	kPa	[996.15; 1447.00]	The Yaws Handbook of Vapor Pressure
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.75421e+01
Coefficient B			-1.71770e+04
Coefficient C			-1.17900e+02
Temperature range, min.			996.15
Temperature range, max.			1447.00
Pvap	0.13	kPa	996.15	Calculated Property
Pvap	0.38	kPa	1046.24	Calculated Property
Pvap	0.99	kPa	1096.34	Calculated Property
Pvap	2.32	kPa	1146.43	Calculated Property
Pvap	5.04	kPa	1196.53	Calculated Property
Pvap	10.22	kPa	1246.62	Calculated Property
Pvap	19.51	kPa	1296.72	Calculated Property
Pvap	35.33	kPa	1346.81	Calculated Property
Pvap	61.08	kPa	1396.91	Calculated Property
Pvap	101.33	kPa	1447.00	Calculated Property

Mixtures

• lithium iodide + Water
• Acetonitrile + lithium iodide + Dimethyl Sulfoxide
• 1,3-Dioxolane + lithium iodide
• 1,3-Dioxolane + Acetonitrile + lithium iodide
• lithium iodide + Glycine + Water
• Diethyl carbonate + Acetonitrile + lithium iodide
• Ethanol + lithium iodide
• Ethanol, 2-methoxy- + lithium iodide + Methyl Alcohol
• lithium iodide + Methyl Alcohol
• lithium iodide + Methyl Alcohol + Water
• L-Valine + lithium iodide + Water

Sources

• Cheméo Relay (1.0, beta) Beta: served but experimental, data-limited and below our cross-validation release bar; the Joback value is recommended where available.
• Ionic interplay of lithium salts in binary mixtures of acetonitrile and diethyl carbonate probed by physicochemical approach
• Density of ethanolic alkali halide salt solutions by experiment andmolecular simulation
• Experimental and theoretical studies of thermodynamics of lithium halide solutions - ethanol mixtures
• Densities and apparent molar volumes of aqueous LiI solutions at temperatures from (296 to 600) K and at pressures up to 30 MPa
• Conductometric study of some alkali metal halides in (dimethyl sulfoxide + acetonitrile) at T = 298.15 K
• Measuring and modeling aqueous electrolyte/amino-acid solutions with ePC-SAFT
• Viscosities of aqueous LiI solutions at 293 525K and 0.1 40MPa
• Physics and Chemistry of Lithium Halides in 1,3-Dioxolane and Its Binary Mixtures with Acetonitrile probed by Conductometric, Volumetric, Viscometric, Refractometric and Acoustic Study
• Electrical Conductivity of Lithium Chloride, Lithium Bromide, and Lithium Iodide Electrolytes in Methanol, Water, and Their Binary Mixtures
• Temperature Dependence of the Density of Aqueous Alkali Halide Salt Solutions by Experiment and Molecular Simulation
• Density of Methanolic Alkali Halide Salt Solutions by Experiment and Molecular Simulation
• Ion-Solvent Interactions of Some Halides of Common Cations with Organic Solvent Mixtures by Conductometric, Volumetric, Viscometric, and Refractometric Techniques
• NIST Webbook
• The Yaws Handbook of Vapor Pressure

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