Chemical Properties of Nickel (CAS 7440-02-0)

InChI

InChI=1S/Ni

InChI Key

PXHVJJICTQNCMI-UHFFFAOYSA-N

Formula

Ni

SMILES

[Ni]

Molecular Weight¹

58.69

CAS

7440-02-0

Other Names

• nickel element

• PAff : Proton affinity (kJ/mol).
• BasG : Gas basicity (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• C_p,solid : Solid phase heat capacity (J/mol×K).
• EA : Electron affinity (eV).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• P_vap : Vapor pressure (kPa).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
PAff	737.00	kJ/mol	NIST
BasG	714.10	kJ/mol	NIST
EA	[1.16; 1.16]	eV
EA	1.16 ± 0.05	eV	NIST
EA	1.16 ± 0.00	eV	NIST
EA	1.16 ± 0.01	eV	NIST
IE	[7.60; 7.64]	eV
IE	7.64	eV	NIST
IE	7.64	eV	NIST
IE	7.64	eV	NIST
IE	7.64	eV	NIST
IE	7.64 ± 0.00	eV	NIST
IE	7.61	eV	NIST
IE	Outlier 7.60 ± 0.20	eV	NIST
IE	7.63	eV	NIST

Cheméo can also estimate Normal Boiling Point Temperature, Normal melting (fusion) point, Critical Temperature, Critical Pressure, Critical Volume, Enthalpy of formation at standard conditions, Enthalpy of vaporization at standard conditions, Standard Gibbs free energy of formation, Acentric Factor, Log10 of Water solubility in mol/l for this compound, but they fall outside the models' validated range, so they are not shown here. Open the prediction tool to compute them on demand.

Temperature Dependent Properties

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[22.39; 25.51]	J/mol×K	[3156.58; 6000.00]	NIST
Equation			Y = A + B·t + C·t² + D·t³ + E/t², t = T/1000 Y is Cp,gas in J/mol×K, T in K
Coefficient A			2.71313e+01
Coefficient B			-2.58756e+00
Coefficient C			2.95110e-01
Coefficient D			1.52000e-02
Coefficient E			4.18300e-02
Reference			Chase, 1998
Comment			F=421.4585, G=214.1643, H=430.1152; Data last reviewed in December, 1976
Temperature range, min.			3156.58
Temperature range, max.			6000.00
Cp,gas	22.39	J/mol×K	3156.58	Calculated Property
Cp,gas	22.34	J/mol×K	3472.52	Calculated Property
Cp,gas	22.39	J/mol×K	3788.45	Calculated Property
Cp,gas	22.54	J/mol×K	4104.39	Calculated Property
Cp,gas	22.77	J/mol×K	4420.32	Calculated Property
Cp,gas	23.11	J/mol×K	4736.26	Calculated Property
Cp,gas	23.55	J/mol×K	5052.19	Calculated Property
Cp,gas	24.10	J/mol×K	5368.13	Calculated Property
Cp,gas	24.75	J/mol×K	5684.06	Calculated Property
Cp,gas	25.51	J/mol×K	6000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[38.91; 38.91]	J/mol×K	[1728.00; 3156.58]	NIST
Equation			Y = A + B·t + C·t² + D·t³ + E/t², t = T/1000 Y is Cp,liquid in J/mol×K, T in K
Coefficient A			3.89110e+01
Coefficient B			0.00000e+00
Coefficient C			0.00000e+00
Coefficient D			0.00000e+00
Coefficient E			0.00000e+00
Reference			Chase, 1998
Comment			F=-2.722630, G=74.47143, H=17.47904; Data last reviewed in December, 1976
Temperature range, min.			1728.00
Temperature range, max.			3156.58
Cp,liquid	38.91	J/mol×K	1728.00	Calculated Property
Cp,liquid	38.91	J/mol×K	1886.73	Calculated Property
Cp,liquid	38.91	J/mol×K	2045.46	Calculated Property
Cp,liquid	38.91	J/mol×K	2204.19	Calculated Property
Cp,liquid	38.91	J/mol×K	2362.93	Calculated Property
Cp,liquid	38.91	J/mol×K	2521.66	Calculated Property
Cp,liquid	38.91	J/mol×K	2680.39	Calculated Property
Cp,liquid	38.91	J/mol×K	2839.12	Calculated Property
Cp,liquid	38.91	J/mol×K	2997.85	Calculated Property
Cp,liquid	38.91	J/mol×K	3156.58	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Cp,solid	[25.97; 34.85]	J/mol×K	[298.00; 600.00]	NIST
Equation			Y = A + B·t + C·t² + D·t³ + E/t², t = T/1000 Y is Cp,solid in J/mol×K, T in K
Coefficient A			1.36916e+01
Coefficient B			8.24951e+01
Coefficient C			-1.74955e+02
Coefficient D			1.61601e+02
Coefficient E			-9.24170e-02
Reference			Chase, 1998
Comment			F=-6.833644, G=27.66900, H=0.000000; Data last reviewed in December, 1976
Temperature range, min.			298.00
Temperature range, max.			600.00
Cp,solid	25.97	J/mol×K	298.00	Calculated Property
Cp,solid	26.86	J/mol×K	331.56	Calculated Property
Cp,solid	27.66	J/mol×K	365.11	Calculated Property
Cp,solid	28.43	J/mol×K	398.67	Calculated Property
Cp,solid	29.22	J/mol×K	432.22	Calculated Property
Cp,solid	30.06	J/mol×K	465.78	Calculated Property
Cp,solid	31.01	J/mol×K	499.33	Calculated Property
Cp,solid	32.10	J/mol×K	532.89	Calculated Property
Cp,solid	33.37	J/mol×K	566.44	Calculated Property
Cp,solid	34.85	J/mol×K	600.00	Calculated Property
Cp,solid	[34.85; 30.79]	J/mol×K	[600.00; 700.00]	NIST
Equation			Y = A + B·t + C·t² + D·t³ + E/t², t = T/1000 Y is Cp,solid in J/mol×K, T in K
Coefficient A			1.24805e+03
Coefficient B			-1.25751e+03
Coefficient C			0.00000e+00
Coefficient D			0.00000e+00
Coefficient E			-1.65127e+02
Reference			Chase, 1998
Comment			F=-788.8263, G=1212.891, H=0.000000; Data last reviewed in December, 1976
Temperature range, min.			600.00
Temperature range, max.			700.00
Cp,solid	34.85	J/mol×K	600.00	Calculated Property
Cp,solid	37.41	J/mol×K	611.11	Calculated Property
Cp,solid	39.09	J/mol×K	622.22	Calculated Property
Cp,solid	39.95	J/mol×K	633.33	Calculated Property
Cp,solid	40.05	J/mol×K	644.44	Calculated Property
Cp,solid	39.44	J/mol×K	655.56	Calculated Property
Cp,solid	38.17	J/mol×K	666.67	Calculated Property
Cp,solid	36.28	J/mol×K	677.78	Calculated Property
Cp,solid	33.81	J/mol×K	688.89	Calculated Property
Cp,solid	30.79	J/mol×K	700.00	Calculated Property
Cp,solid	[30.78; 38.56]	J/mol×K	[700.00; 1728.00]	NIST
Equation			Y = A + B·t + C·t² + D·t³ + E/t², t = T/1000 Y is Cp,solid in J/mol×K, T in K
Coefficient A			1.64984e+01
Coefficient B			1.87491e+01
Coefficient C			-6.63984e+00
Coefficient D			1.71728e+00
Coefficient E			1.87205e+00
Reference			Chase, 1998
Comment			F=-0.467675, G=51.67575, H=0.000000; Data last reviewed in December, 1976
Temperature range, min.			700.00
Temperature range, max.			1728.00
Cp,solid	30.78	J/mol×K	700.00	Calculated Property
Cp,solid	31.11	J/mol×K	814.22	Calculated Property
Cp,solid	31.73	J/mol×K	928.44	Calculated Property
Cp,solid	32.50	J/mol×K	1042.67	Calculated Property
Cp,solid	33.36	J/mol×K	1156.89	Calculated Property
Cp,solid	34.29	J/mol×K	1271.11	Calculated Property
Cp,solid	35.27	J/mol×K	1385.33	Calculated Property
Cp,solid	36.31	J/mol×K	1499.56	Calculated Property
Cp,solid	37.40	J/mol×K	1613.78	Calculated Property
Cp,solid	38.56	J/mol×K	1728.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.00e-03; 99.99]	kPa	[1783.15; 3184.15]	The Yaws Handbook of Vapor Pressure
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.81231e+01
Coefficient B			-4.11757e+04
Coefficient C			-1.38160e+02
Temperature range, min.			1783.15
Temperature range, max.			3184.15
Pvap	1.00e-03	kPa	1783.15	Calculated Property
Pvap	8.70e-03	kPa	1938.82	Calculated Property
Pvap	0.05	kPa	2094.48	Calculated Property
Pvap	0.25	kPa	2250.15	Calculated Property
Pvap	0.97	kPa	2405.82	Calculated Property
Pvap	3.10	kPa	2561.48	Calculated Property
Pvap	8.65	kPa	2717.15	Calculated Property
Pvap	21.46	kPa	2872.82	Calculated Property
Pvap	48.28	kPa	3028.48	Calculated Property
Pvap	99.99	kPa	3184.15	Calculated Property
Pvap	[0.13; 103.16]	kPa	[2083.00; 3005.00]	NIST
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.83788e+01
Coefficient B			-3.87029e+04
Coefficient C			-1.88717e+02
Reference			Stull, 1947
Comment			Coefficents calculated by NIST from author's data.
Temperature range, min.			2083.00
Temperature range, max.			3005.00
Pvap	0.13	kPa	2083.00	Calculated Property
Pvap	0.37	kPa	2185.44	Calculated Property
Pvap	0.94	kPa	2287.89	Calculated Property
Pvap	2.22	kPa	2390.33	Calculated Property
Pvap	4.86	kPa	2492.78	Calculated Property
Pvap	9.94	kPa	2595.22	Calculated Property
Pvap	19.16	kPa	2697.67	Calculated Property
Pvap	35.10	kPa	2800.11	Calculated Property
Pvap	61.41	kPa	2902.56	Calculated Property
Pvap	103.16	kPa	3005.00	Calculated Property

Mixtures

• Nickel + tin
• antimony + Nickel
• antimony + Nickel + tin
• Nickel + Bismuth
• silver + Nickel + Bismuth
• Palladium + Nickel

Sources

• Cheméo Relay (1.0, beta) Beta: served but experimental, data-limited and below our cross-validation release bar; the Joback value is recommended where available.
• Thermochemical studies of three bis(O-alkyl-N-benzoylthiocarbamato)nickel(II) complexes
• Standard molar enthalpies of formation of two crystalline bis[N-(diethylaminothiocarbonyl)benzamidinato]nickel(II) complexes
• Standard molar enthalpies of formation of nickel(II) I2-diketonates and monothio-I2-diketonates
• Thermodynamic stability of RNi2 Laves phases
• Enthalpy of mixing of liquid Ni-Ti-Zr alloys at 1873 K
• Thermodynamic activity measurements in nickel-base industrial alloys and steels by Knudsen cell Mass spectrometry
• Correlation between excess volume and thermodynamic functions of liquid Pd-X (X = Fe, Cu and Ni) binary systems
• Thermodynamic properties of liquid silver indium alloys determined from e.m.f. measurements
• Interfaces in lead-free solder alloys: Enthalpy of formation of binary Ag Sn, Cu Sn and Ni Sn intermetallic compounds
• Enthalpy of mixing of liquid systems for lead free soldering: The Ni-Sb-Sn system
• Thermochemistry of Liquid Ni-Sb-Sn Alloys
• Synthesis, crystal structure and thermochemistry of nickel hydrogen pyridine-2,6-dicarboxylate
• Vaporization studies over (NiO + Ni2Te3O8) in the Ni-Te-O system by transpiration thermogravimetry and Knudsen effusion mass spectrometry
• Mixing enthalpies of liquid Bi-Ni and Ag-Bi-Ni alloys
• On the partial enthalpy of mixing of Nb in liquid Al
• NIST Webbook
• The Yaws Handbook of Vapor Pressure

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