Chemical Properties of 1,1,1,3,3-pentafluorobutane (CAS 406-58-6)

InChI

InChI=1S/C4H5F5/c1-3(5,6)2-4(7,8)9/h2H2,1H3

InChI Key

WZLFPVPRZGTCKP-UHFFFAOYSA-N

Formula

C4H5F5

SMILES

CC(F)(F)CC(F)(F)F

Molecular Weight¹

148.07

CAS

406-58-6

Other Names

• HFC-365mfc
• R-365mfc

• C_p,gas : Ideal gas heat capacity (J/mol×K).
• ε_r : Dielectric Constant (Relative permittivity).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_vap : Vapor pressure (kPa).
• ρ_l : Liquid Density (kg/m³).
• c_sound,fluid : Speed of sound in fluid (m/s).
• T_boil : Normal Boiling Point Temperature (K).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Contents

1. Physical Properties
2. Temperature Dependent Properties
3. Datasets
4. Correlations
5. Similar Compounds
6. Mixtures
7. Sources

Physical Properties

Property	Value	Unit	Source
ΔfusH°	6.69	kJ/mol	Joback Calculated Property
ΔvapH°	26.46	kJ/mol	Relay (1.0) Calculated Property
logPoct/wat	2.594		Crippen Calculated Property
McVol	76.070	ml/mol	McGowan Calculated Property
Tboil	301.36	K	Relay (1.0) Calculated Property

Cheméo can also estimate Normal melting (fusion) point, Critical Temperature, Critical Pressure, Critical Volume, Enthalpy of formation at standard conditions, Standard Gibbs free energy of formation, Acentric Factor, Ionization energy, Log10 of Water solubility in mol/l for this compound, but they fall outside the models' validated range, so they are not shown here. Open the prediction tool to compute them on demand.

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[131.53; 177.98]	J/mol×K	[280.81; 417.90]
Cp,gas	131.53	J/mol×K	280.81	Joback Calculated Property
Cp,gas	140.34	J/mol×K	303.66	Joback Calculated Property
Cp,gas	148.71	J/mol×K	326.51	Joback Calculated Property
Cp,gas	156.64	J/mol×K	349.36	Joback Calculated Property
Cp,gas	164.15	J/mol×K	372.21	Joback Calculated Property
Cp,gas	171.26	J/mol×K	395.05	Joback Calculated Property
Cp,gas	177.98	J/mol×K	417.90	Joback Calculated Property
Pvap	[194.90; 2637.10]	kPa	[332.79; 447.89]
Pvap	194.90	kPa	332.79	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	197.10	kPa	333.18	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	261.50	kPa	342.65	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	303.90	kPa	347.94	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	348.70	kPa	352.87	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	401.10	kPa	357.77	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	459.20	kPa	363.03	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	519.80	kPa	367.94	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	586.10	kPa	372.87	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	662.30	kPa	378.04	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	741.40	kPa	382.95	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	828.90	kPa	387.88	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	927.20	kPa	393.02	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	1036.40	kPa	398.06	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	1146.00	kPa	402.92	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	1271.50	kPa	408.07	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	1403.80	kPa	413.09	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	1542.40	kPa	418.00	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	1698.60	kPa	423.13	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	1862.70	kPa	428.15	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	2034.50	kPa	433.05	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	2225.40	kPa	438.03	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	2425.50	kPa	442.99	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
Pvap	2637.10	kPa	447.89	Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K

Datasets

1. Relative permittivity at zero frequency (1)
2. Mass density, kg/m3 (1)
3. Speed of sound, m/s (1)

Relative permittivity at zero frequency

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Relative permittivity at zero frequency - Liquid
263.14	1000.00	14.8991
263.14	2000.00	14.9339
263.14	3000.00	14.9675
263.14	5000.00	15.0355
263.14	9000.00	15.1666
263.14	11000.00	15.2295
263.14	12000.00	15.2606
263.15	4000.00	15.001
263.15	6000.00	15.0681
263.15	7000.00	15.0997
263.15	8000.00	15.1352
263.15	10000.00	15.1979
263.15	13000.00	15.2925
263.15	14000.00	15.3179
263.15	15000.00	15.3453
263.16	16000.00	15.376
273.18	1000.00	13.8707
273.18	2000.00	13.907
273.18	3000.00	13.9444
273.18	4000.00	13.9789
273.18	5000.00	14.0155
273.18	7000.00	14.0864
273.18	8000.00	14.1193
273.19	6000.00	14.0488
273.19	9000.00	14.151
273.19	10000.00	14.1868
273.19	11000.00	14.2212
273.19	12000.00	14.252
273.19	13000.00	14.2819
273.19	14000.00	14.3131
273.19	15000.00	14.3437
273.20	16000.00	14.3733
283.10	1000.00	12.8983
283.10	2000.00	12.9424
283.10	4000.00	13.0232
283.10	5000.00	13.0635
283.10	9000.00	13.2072
283.10	10000.00	13.2519
283.11	3000.00	12.9815
283.11	6000.00	13.1003
283.11	7000.00	13.1372
283.11	8000.00	13.1743
283.11	11000.00	13.2847
283.11	12000.00	13.3213
283.11	13000.00	13.3541
283.11	15000.00	13.4183
283.11	16000.00	13.4493
283.12	14000.00	13.3889
293.22	5000.00	12.1498
293.22	6000.00	12.1866
293.23	1000.00	11.9936
293.23	2000.00	12.0329
293.23	3000.00	12.0713
293.23	4000.00	12.1135
293.23	7000.00	12.226
293.23	8000.00	12.2608
293.23	9000.00	12.2974
293.23	10000.00	12.3321
293.23	11000.00	12.3672
293.23	12000.00	12.4025
293.23	13000.00	12.4364
293.23	14000.00	12.469
293.23	15000.00	12.5018
293.23	16000.00	12.5349
303.00	1000.00	11.2337
303.00	2000.00	11.275
303.00	3000.00	11.3146
303.00	4000.00	11.3535
303.00	5000.00	11.3908
303.00	6000.00	11.429
303.01	7000.00	11.4659
303.01	8000.00	11.5028
303.01	9000.00	11.5382
303.01	10000.00	11.5749
303.01	11000.00	11.6078
303.01	12000.00	11.6429
303.01	13000.00	11.6764
303.01	14000.00	11.7115
303.01	15000.00	11.745
303.01	16000.00	11.7786
Reference

Mass density, kg/m3

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mass density, kg/m3 - Liquid
298.16	10021.00	1279.33
292.96	5455.10	1279.78
291.35	4070.90	1279.92
303.85	15147.00	1278.84
309.50	20037.00	1278.36
315.28	25013.00	1277.86
290.22	3193.00	1280.01
288.90	2019.20	1280.13
287.75	1242.00	1280.22
321.09	29987.00	1277.37
326.99	34967.00	1276.87
333.06	40085.00	1276.36
309.51	9974.60	1257.8
315.80	15053.00	1257.28
298.57	1157.40	1258.72
299.69	2006.30	1258.62
301.02	3084.30	1258.51
302.24	4081.30	1258.41
303.47	5080.20	1258.31
322.04	20055.00	1256.76
328.32	25047.00	1256.24
334.62	30028.00	1255.72
341.51	35426.00	1255.16
347.07	39768.00	1254.7
322.05	10082.00	1233.67
309.96	1066.80	1234.65
311.31	2069.70	1234.54
312.57	3017.80	1234.43
313.89	4006.10	1234.33
315.23	5013.40	1234.22
328.80	15073.00	1233.12
335.52	20025.00	1232.59
342.36	25012.00	1232.04
353.15	32850.00	1231.18
335.52	10079.00	1206.32
322.30	1278.80	1207.34
323.48	1919.70	1207.25
325.25	3125.10	1207.12
326.62	4057.40	1207.01
327.90	4926.10	1206.91
353.15	21912.00	1204.96
343.05	15153.00	1205.73
335.52	1037.90	1175.56
337.15	2014.40	1175.44
338.81	3050.50	1175.32
340.39	4011.00	1175.2
342.03	5008.90	1175.08
353.15	11756.00	1174.25
292.96	20092.00	1309.09
287.79	15107.00	1309.56
297.78	24667.00	1308.67
303.22	29830.00	1308.18
282.69	10162.00	1310.01
308.65	34947.00	1307.7
314.06	40001.00	1307.23
276.61	3921.90	1309.71
275.63	2942.20	1309.8
274.73	2060.00	1309.88
273.72	1076.80	1309.97
277.65	4903.90	1309.61
277.66	19995.00	1335.08
282.34	24894.00	1334.64
273.08	15145.00	1335.5
260.21	1298.10	1336.72
261.98	3278.80	1336.55
261.05	2152.90	1336.64
268.32	10033.00	1335.95
263.74	5132.20	1336.38
262.73	4030.20	1336.48
287.06	29792.00	1334.21
292.09	35022.00	1333.75
296.90	39956.00	1333.31
263.72	19989.00	1359.61
268.05	24964.00	1359.2
272.35	29861.00	1358.79
276.83	34914.00	1358.36
281.43	40068.00	1357.92
259.50	15102.00	1360.02
255.26	10152.00	1360.44
250.93	5088.80	1360.86
250.20	4243.70	1360.94
249.22	3081.20	1361.03
248.25	1931.80	1361.13
247.43	956.60	1361.21
250.92	19991.00	1381.43
255.00	25056.00	1381.02
258.99	29998.00	1380.62
262.97	34873.00	1380.23
267.12	39916.00	1379.82
247.08	15188.00	1381.81
243.12	10185.00	1382.22
239.08	5074.00	1382.22
238.27	4040.10	1382.71
237.49	3052.40	1382.79
239.08	5081.70	1382.63
Reference

Speed of sound, m/s

Fixed		Measured
Temperature, K - Fluid (supercritical or subcritical phases)	Pressure, kPa - Fluid (supercritical or subcritical phases)	Speed of sound, m/s - Fluid (supercritical or subcritical phases)
250.00	40129.80	1086.73
250.00	45133.20	1104.43
250.00	50136.70	1121.55
250.00	7108.89	951.224
250.00	8108.14	955.954
250.00	6108.31	946.435
250.00	4106.88	936.695
250.00	5107.39	941.591
250.00	9108.81	960.643
250.00	10109.50	965.279
250.00	12611.20	976.667
250.00	3106.29	931.741
250.00	15112.80	987.778
250.00	17614.50	998.623
250.00	35126.70	1068.44
250.00	1105.24	921.654
250.00	2105.81	926.727
250.00	30123.20	1049.47
250.00	20116.20	1009.23
250.00	25119.70	1029.77
260.00	20118.30	973.79
260.00	25121.80	995.21
260.00	70153.30	1155.9
260.00	17616.60	962.702
260.00	15114.80	951.341
260.00	10111.60	927.709
260.00	60146.30	1124.06
260.00	100174.00	1242.39
260.00	30125.80	1015.72
260.00	8109.95	917.883
260.00	7109.17	912.886
260.00	12613.30	939.678
260.00	35129.20	1035.4
260.00	45136.00	1072.64
260.00	9110.74	922.822
260.00	40132.60	1054.35
260.00	3105.32	892.275
260.00	50139.50	1090.32
260.00	90167.30	1214.88
260.00	80160.30	1186.11
260.00	4105.93	897.525
260.00	1104.31	881.567
260.00	2104.81	886.957
260.00	6107.90	907.823
260.00	5106.33	902.702
280.00	3105.41	815.422
280.00	9110.25	849.619
280.00	1104.39	803.308
280.00	2104.89	809.414
280.00	5106.56	827.157
280.00	12612.60	868.295
280.00	4106.02	821.335
280.00	6107.80	832.893
280.00	10110.90	855.044
280.00	30124.50	951.169
280.00	15114.20	881.135
280.00	17615.90	893.599
280.00	25121.00	929.005
280.00	20117.60	905.714
280.00	7108.52	838.546
280.00	8109.28	844.119
280.00	35128.00	972.336
280.00	40131.30	992.623
280.00	50138.30	1030.93
280.00	90166.20	1161.95
280.00	45134.90	1012.14
280.00	60145.20	1066.64
280.00	100172.00	1190.62
280.00	80159.20	1131.86
280.00	70152.20	1100.18
300.00	4106.00	747.608
300.00	1104.50	727.097
300.00	3105.50	740.902
300.00	5107.00	754.188
300.00	6107.62	760.648
300.00	2105.02	734.062
300.00	15113.80	814.225
300.00	10110.20	785.368
300.00	17615.70	827.906
300.00	20117.40	841.146
300.00	25121.00	866.442
300.00	12612.00	800.064
300.00	7107.15	766.961
300.00	8107.81	773.205
300.00	9108.42	779.34
300.00	30125.10	890.344
300.00	35128.60	913.064
300.00	40132.00	934.735
300.00	45135.50	955.482
300.00	50139.00	975.384
300.00	80159.80	1081.4
300.00	90166.80	1112.74
300.00	70152.90	1048.27
300.00	60145.90	1013.06
300.00	100174.00	1142.54
319.99	5107.70	683.411
319.99	6108.64	690.741
319.99	8110.03	704.932
319.99	7109.32	697.912
319.99	4106.30	675.918
319.99	3105.53	668.239
319.99	2104.92	660.367
320.00	60147.60	963.245
320.00	45137.20	902.594
320.00	70154.70	1000.07
320.00	40133.60	880.586
320.00	50140.60	923.632
320.00	90168.80	1067.14
320.00	80161.70	1034.59
320.00	100176.00	1098.0
320.00	30126.10	833.194
320.00	35129.70	857.515
320.00	25122.60	807.438
320.00	9111.17	711.767
320.00	10111.90	718.523
320.00	15115.40	750.505
320.00	17617.20	765.527
320.00	12613.70	734.862
320.00	20119.00	779.984
320.01	1103.13	652.277
340.00	70150.00	955.265
340.00	80157.10	991.116
340.00	100171.00	1056.68
340.00	90164.30	1024.81
340.00	45131.10	853.186
340.00	50134.60	875.341
340.00	60141.60	916.858
340.00	35124.20	805.417
340.00	40127.70	829.931
340.00	5108.05	614.361
340.00	9109.42	646.622
340.00	10109.90	654.203
340.00	4107.49	605.733
340.00	12611.40	672.434
340.00	25119.20	751.783
340.00	3106.96	596.831
340.00	6109.06	622.752
340.00	7109.73	630.92
340.00	8108.87	638.859
340.00	15112.90	689.742
340.00	17614.40	706.243
340.00	30122.50	779.466
340.00	2106.43	587.648
340.00	20116.00	722.034
340.00	1105.82	578.155
360.00	60143.90	873.891
360.00	100172.00	1018.48
360.00	50136.90	830.523
360.00	70150.90	913.8
360.00	80157.90	950.908
360.00	90164.90	985.685
360.00	45133.90	807.276
360.00	20116.60	667.308
360.00	40130.40	782.776
360.00	17614.90	650.069
360.00	25120.10	699.501
360.00	30123.50	729.186
360.00	5104.79	546.727
360.00	4103.97	536.638
360.00	6106.19	556.452
360.00	35126.90	756.831
360.00	7106.94	565.844
360.00	9108.39	583.754
360.00	10109.10	592.319
360.00	15112.70	631.924
360.00	8107.67	574.937
360.00	3103.33	526.145
360.00	12610.90	612.735
360.00	2102.72	515.201
360.00	1102.09	503.74
379.99	45133.80	764.514
379.99	5103.45	479.824
379.99	8106.27	512.709
379.99	40130.20	738.79
379.99	70151.40	875.312
379.99	80158.50	913.604
379.99	90165.60	949.388
379.99	2101.66	441.66
379.99	3102.07	455.118
379.99	4102.71	467.802
379.99	6104.71	491.269
379.99	60144.30	833.968
379.99	100173.00	983.052
379.99	7105.49	502.214
379.99	17613.70	596.763
379.99	50137.30	788.832
379.99	12610.10	555.505
379.99	25119.00	650.335
379.99	1100.78	427.276
379.99	9107.51	522.809
379.99	10108.30	532.542
379.99	15111.90	576.814
379.99	30122.60	682.079
379.99	35126.20	711.417
379.99	20115.50	615.559
400.00	5108.09	413.052
400.00	3106.43	382.376
400.00	2105.65	364.944
400.00	4107.25	398.307
400.00	1605.20	355.522
400.00	17616.20	546.393
400.00	20118.00	566.858
400.00	25121.50	604.312
400.00	80159.30	879.055
400.00	15114.50	524.475
400.00	90166.40	915.765
400.00	12612.70	500.78
400.00	50138.00	750.161
400.00	60145.20	796.979
400.00	70152.30	839.661
400.00	100174.00	950.225
400.00	30124.90	638.139
400.00	40131.80	697.922
400.00	9110.16	463.702
400.00	10110.90	474.847
400.00	35128.30	669.157
400.00	6107.81	426.803
400.00	7108.64	439.765
400.00	45135.30	724.825
400.00	8109.38	452.032
419.99	7105.63	378.198
419.99	10107.80	419.256
419.99	6104.97	362.506
419.99	8106.35	392.762
419.99	5104.27	345.407
419.99	9107.10	406.402
419.99	4103.55	326.491
419.99	3102.80	305.082
419.99	2103.32	280.019
Reference

Correlations

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 202.67]	kPa	[236.26; 308.55]	The Yaws Handbook of Vapor Pressure
Equation			ln(Pvp) = A + B/(T + C)
Coefficient A			1.97674e+01
Coefficient B			-4.05201e+03
Coefficient C			-2.82470e+01
Temperature range, min.			236.26
Temperature range, max.			308.55
Pvap	1.33	kPa	236.26	Calculated Property
Pvap	2.75	kPa	244.29	Calculated Property
Pvap	5.39	kPa	252.32	Calculated Property
Pvap	10.08	kPa	260.36	Calculated Property
Pvap	18.07	kPa	268.39	Calculated Property
Pvap	31.19	kPa	276.42	Calculated Property
Pvap	52.04	kPa	284.45	Calculated Property
Pvap	84.16	kPa	292.49	Calculated Property
Pvap	132.31	kPa	300.52	Calculated Property
Pvap	202.67	kPa	308.55	Calculated Property

Similar Compounds

Find more compounds similar to 1,1,1,3,3-pentafluorobutane.

Mixtures

• Butane, decafluoro- + 1,1,1,3,3-pentafluorobutane
• Carbon dioxide + 1,1,1,3,3-pentafluorobutane

Sources

• Cheméo Relay (1.0)
• Cheméo Relay (1.0, beta) Beta: served but experimental, data-limited and below our cross-validation release bar; the Joback value is recommended where available.
• Crippen Method
• Crippen Method
• Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
• Vapor-Liquid Equilibrium Data for the Carbon Dioxide (CO2) + 1,1,1,3,3-Pentafluorobutane (R365mfc) System at Temperatures from 283.15 to 337.15 K
• Measurements of the Speed of Sound in the Refrigerants HFC227ea and HFC365mfc in the Liquid Region
• Surface Tension and p ? T Data for 1,1,1,3,3-Pentafluorobutane (HFC-365mfc) and 1,1,1,2,2,3,3-Heptafluoro-3-methoxy-propane (HFE-347mcc)
• Relative Permittivities of 1,1,1,2,3,3,3-Heptafluoropropane (HFC-227ea), 1,1,1,2,3,3-Hexafluoropropane (HFC-236ea), and 1,1,1,3,3-Pentafluorobutane (HFC-365mfc) in the Liquid Phase
• Joback Method
• McGowan Method
• The Yaws Handbook of Vapor Pressure

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