Chemical Properties of tert-Butyl acrylate (CAS 1663-39-4)

tert-Butyl acrylate

InChI
InChI=1S/C7H12O2/c1-5-6(8)9-7(2,3)4/h5H,1H2,2-4H3
InChI Key
ISXSCDLOGDJUNJ-UHFFFAOYSA-N
Formula
C7H12O2
SMILES
C=CC(=O)OC(C)(C)C
Molecular Weight1
128.17
CAS
1663-39-4
Other Names
  • 1,1-dimethylethyl 2-propenoate
  • 2-Propenoic acid, 1,1-dimethylethyl ester
  • Acrylic acid, tert-butyl ester
  • t-butyl acrylate
  • tert-butyl 2-propenoate
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Physical Properties

Property Value Unit Source
ω 0.4039 Relay (1.0) Calculated Property
ΔfH°gas -424.13 kJ/mol Relay (1.0) Calculated Property
ΔfusH° 9.56 kJ/mol Joback Calculated Property
ΔvapH° 43.50 kJ/mol Relay (1.0) Calculated Property
IE 9.99 eV Relay (1.0) Calculated Property
log10WS -1.29 Relay (1.0) Calculated Property
logPoct/wat 1.514 Crippen Calculated Property
McVol 112.630 ml/mol McGowan Calculated Property
Pc 3005.73 kPa Joback Calculated Property
Tboil 384.90 K Relay (1.0) Calculated Property
Tc 575.64 K Relay (1.0) Calculated Property
Tfus 200.69 K Relay (1.0) Calculated Property
Vc 0.419 m3/kmol Relay (1.0) Calculated Property

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Temperature Dependent Properties

Property Value Unit Temperature (K) Source
ρl [861.82; 884.13] kg/m3 [293.15; 318.15] Show Hide
ρl 884.13 kg/m3 293.15 Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
ρl 884.13 kg/m3 293.15 Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures
ρl 879.66 kg/m3 298.15 Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
ρl 879.66 kg/m3 298.15 Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures
ρl 875.20 kg/m3 303.15 Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
ρl 875.20 kg/m3 303.15 Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures
ρl 870.74 kg/m3 308.15 Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
ρl 870.74 kg/m3 308.15 Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures
ρl 866.28 kg/m3 313.15 Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
ρl 866.28 kg/m3 313.15 Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures
ρl 861.82 kg/m3 318.15 Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
ρl 861.82 kg/m3 318.15 Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures

Correlations

Property Value Unit Temperature (K) Source
Cp,gas [159.05; 361.53] J/mol×K [273.00; 1000.00] Joback Predicted correlation Show Hide
EquationY = A + B·T + C·T² + D·T³ + E·T⁴
Y is Cp,gas in J/mol×K, T in K
Coefficient A-5.53000e+00
Coefficient B7.19860e-01
Coefficient C-4.57100e-04
Coefficient D1.04300e-07
Coefficient E0.00000e+00
Temperature range, min.273.00
Temperature range, max.1000.00
Cp,gas 159.05 J/mol×K 273.00 Calculated Property
Cp,gas 196.55 J/mol×K 353.78 Calculated Property
Cp,gas 229.53 J/mol×K 434.56 Calculated Property
Cp,gas 258.32 J/mol×K 515.33 Calculated Property
Cp,gas 283.25 J/mol×K 596.11 Calculated Property
Cp,gas 304.65 J/mol×K 676.89 Calculated Property
Cp,gas 322.85 J/mol×K 757.67 Calculated Property
Cp,gas 338.17 J/mol×K 838.44 Calculated Property
Cp,gas 350.96 J/mol×K 919.22 Calculated Property
Cp,gas 361.53 J/mol×K 1000.00 Calculated Property
Property Value Unit Temperature (K) Source
η [0.0091467; 0.0002514] Pa×s [211.64; 419.62] Joback Predicted correlation Show Hide
EquationY = exp(A + B/T + C·ln(T) + D·T^E)
Y is η in Pa×s, T in K
Coefficient A-1.19456e+01
Coefficient B1.53466e+03
Coefficient C0.00000e+00
Coefficient D0.00000e+00
Coefficient E0.00000e+00
Temperature range, min.211.64
Temperature range, max.419.62
η 0.0091467 Pa×s 211.64 Calculated Property
η 0.0044798 Pa×s 234.75 Calculated Property
η 0.0024935 Pa×s 257.86 Calculated Property
η 0.0015284 Pa×s 280.97 Calculated Property
η 0.0010091 Pa×s 304.07 Calculated Property
η 0.0007066 Pa×s 327.18 Calculated Property
η 0.0005185 Pa×s 350.29 Calculated Property
η 0.0003954 Pa×s 373.40 Calculated Property
η 0.0003112 Pa×s 396.51 Calculated Property
η 0.0002514 Pa×s 419.62 Calculated Property
Property Value Unit Temperature (K) Source
Pvap [1.33; 202.65] kPa [338.15; 438.86] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.89075e+01
Coefficient B-5.07474e+03
Coefficient C-6.56080e+01
Temperature range, min.338.15
Temperature range, max.438.86
Pvap 1.33 kPa 338.15 Calculated Property
Pvap 2.78 kPa 349.34 Calculated Property
Pvap 5.48 kPa 360.53 Calculated Property
Pvap 10.27 kPa 371.72 Calculated Property
Pvap 18.43 kPa 382.91 Calculated Property
Pvap 31.78 kPa 394.10 Calculated Property
Pvap 52.87 kPa 405.29 Calculated Property
Pvap 85.14 kPa 416.48 Calculated Property
Pvap 133.13 kPa 427.67 Calculated Property
Pvap 202.65 kPa 438.86 Calculated Property

Similar Compounds

Isopropyl acrylate. Acetic acid, 1,1-dimethylethyl ester. TERT-BUTYL METHACRYLATE. Acetic acid, bromo-, 1,1-dimethylethyl ester. Acetic acid, dibromo, 1,1-dimethylethyl ester. 1-Propene, 3-(1,1-dimethylethoxy)-. Acetic acid, chloro-, 1,1-dimethylethyl ester. Acetic acid, tribromo, 1,1-dimethylethyl ester. Acetic acid, dichloro-, 1,1-dimethylethyl ester. Acetic acid, trifluoro-, 1,1-dimethylethyl ester. 2-Butenedioic acid (Z)-, bis(1-methylethyl) ester. 3-Pentenoic acid, 1,1-dimethylethyl ester, (E)-. 2(5H)-Furanone, 5,5-dimethyl-. Propanoic acid, 1,1-dimethylethyl ester. Di-t-butyl malonate.

Find more compounds similar to tert-Butyl acrylate.

Mixtures

Sources

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