Chemical Properties of tert-Butyl acrylate (CAS 1663-39-4)

InChI

InChI=1S/C7H12O2/c1-5-6(8)9-7(2,3)4/h5H,1H2,2-4H3

InChI Key

ISXSCDLOGDJUNJ-UHFFFAOYSA-N

Formula

C7H12O2

SMILES

C=CC(=O)OC(C)(C)C

Molecular Weight¹

128.17

CAS

1663-39-4

Other Names

• 1,1-dimethylethyl 2-propenoate
• 2-Propenoic acid, 1,1-dimethylethyl ester
• Acrylic acid, tert-butyl ester
• t-Butyl acrylate
• tert-butyl 2-propenoate

• ω : Acentric Factor.
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• η : Dynamic viscosity (Pa×s).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• ρ_l : Liquid Density (kg/m³).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• V_c : Critical Volume (m³/kmol).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[225.27; 287.01]	J/mol×K	[429.30; 621.15]
Cp,gas	225.27	J/mol×K	429.30	Joback Calculated Property
Cp,gas	236.97	J/mol×K	461.28	Joback Calculated Property
Cp,gas	248.07	J/mol×K	493.25	Joback Calculated Property
Cp,gas	258.61	J/mol×K	525.23	Joback Calculated Property
Cp,gas	268.60	J/mol×K	557.20	Joback Calculated Property
Cp,gas	278.06	J/mol×K	589.18	Joback Calculated Property
Cp,gas	287.01	J/mol×K	621.15	Joback Calculated Property
η	[0.0002772; 0.0043009]	Pa×s	[241.47; 429.30]
η	0.0043009	Pa×s	241.47	Joback Calculated Property
η	0.0020951	Pa×s	272.78	Joback Calculated Property
η	0.0011835	Pa×s	304.08	Joback Calculated Property
η	0.0007438	Pa×s	335.38	Joback Calculated Property
η	0.0005060	Pa×s	366.69	Joback Calculated Property
η	0.0003658	Pa×s	398.00	Joback Calculated Property
η	0.0002772	Pa×s	429.30	Joback Calculated Property
ρl	[861.82; 884.13]	kg/m3	[293.15; 318.15]
ρl	884.13	kg/m3	293.15	Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
ρl	884.13	kg/m3	293.15	Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures
ρl	879.66	kg/m3	298.15	Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
ρl	879.66	kg/m3	298.15	Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures
ρl	875.20	kg/m3	303.15	Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
ρl	875.20	kg/m3	303.15	Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures
ρl	870.74	kg/m3	308.15	Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
ρl	870.74	kg/m3	308.15	Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures
ρl	866.28	kg/m3	313.15	Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
ρl	866.28	kg/m3	313.15	Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures
ρl	861.82	kg/m3	318.15	Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
ρl	861.82	kg/m3	318.15	Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures

Correlations

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 202.65]	kPa	[338.15; 438.86]	The Yaws Handbook of Vapor Pressure
Equation			ln(Pvp) = A + B/(T + C)
Coefficient A			1.89075e+01
Coefficient B			-5.07474e+03
Coefficient C			-6.56080e+01
Temperature range, min.			338.15
Temperature range, max.			438.86
Pvap	1.33	kPa	338.15	Calculated Property
Pvap	2.78	kPa	349.34	Calculated Property
Pvap	5.48	kPa	360.53	Calculated Property
Pvap	10.27	kPa	371.72	Calculated Property
Pvap	18.43	kPa	382.91	Calculated Property
Pvap	31.78	kPa	394.10	Calculated Property
Pvap	52.87	kPa	405.29	Calculated Property
Pvap	85.14	kPa	416.48	Calculated Property
Pvap	133.13	kPa	427.67	Calculated Property
Pvap	202.65	kPa	438.86	Calculated Property

Similar Compounds

Find more compounds similar to tert-Butyl acrylate.

Mixtures

• tert-Butyl acrylate + Acetonitrile
• tert-Butyl acrylate + Tetrahydrofuran

Sources

• Cheméo Relay (1.0)
• Crippen Method
• Crippen Method
• Densities and volumetric properties of (acetonitrile + alkyl acrylate monomer) binary mixtures at temperatures from 293.15 K to 318.15 K
• Temperature and concentration dependence of volumetric properties of (tetrahydrofuran + methyl acrylate, or + ethyl acrylate, or + n-butyl acrylate, or + tert-butyl acrylate) binary mixtures
• Joback Method
• McGowan Method
• NIST Webbook
• The Yaws Handbook of Vapor Pressure

Note: Cheméo is only indexing the data, follow the source links to retrieve the latest data. The source is also providing more information like the publication year, authors and more. Take the time to validate and double check the source of the data.