Chemical Properties of Propylamine (CAS 107-10-8)

InChI

InChI=1S/C3H9N/c1-2-3-4/h2-4H2,1H3

InChI Key

WGYKZJWCGVVSQN-UHFFFAOYSA-N

Formula

C3H9N

SMILES

CCCN

Molecular Weight¹

59.11

CAS

107-10-8

Other Names

• 1-AMINOPROPANE
• 1-Propanamine
• 1-Propylamine
• MONOPROPYLAMINE
• Mono-n-propylamine
• NSC 7490
• PROPANAMINE
• Rcra waste number U194
• UN 1277
• n-C3H7NH2
• n-Propylamine
• propan-1-amine

• ω : Acentric Factor.
• PAff : Proton affinity (kJ/mol).
• BasG : Gas basicity (kJ/mol).
• Δ_cH°_liquid : Standard liquid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• μ : Dipole Moment (debye).
• η : Dynamic viscosity (Pa×s).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fH°_liquid : Liquid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_fusH : Enthalpy of fusion at a given temperature (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• NFPA Fire : NFPA Fire Rating.
• NFPA Health : NFPA Health Rating.
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I : Polar retention indices.
• Δ_fusS : Entropy of fusion at a given temperature (J/mol×K).
• S°_liquid : Liquid phase molar entropy at standard conditions (J/mol×K).
• c_sound,fluid : Speed of sound in fluid (m/s).
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• T_triple : Triple Point Temperature (K).
• V_c : Critical Volume (m³/kmol).
• V_m : Molar Volume (m³/mol).
• Z_c : Critical Compressibility.
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	0.3030		KDB
PAff	[907.10; 917.80]	kJ/mol
PAff	917.80	kJ/mol	NIST
PAff	907.50	kJ/mol	NIST
PAff	907.10	kJ/mol	NIST
BasG	883.90	kJ/mol	NIST
ΔcH°liquid	[-2365.00; -2344.00]	kJ/mol
ΔcH°liquid	-2365.00 ± 3.00	kJ/mol	NIST
ΔcH°liquid	-2344.00	kJ/mol	NIST
μ	1.30	debye	KDB
ΔfG°	39.82	kJ/mol	KDB
ΔfH°gas	[-106.70; -69.90]	kJ/mol
ΔfH°gas	-72.43	kJ/mol	KDB
ΔfH°gas	-69.90 ± 0.80	kJ/mol	NIST
ΔfH°gas	-70.17 ± 0.54	kJ/mol	NIST
ΔfH°gas	-106.70	kJ/mol	NIST
ΔfH°liquid	[-138.00; -101.50]	kJ/mol
ΔfH°liquid	-101.50 ± 0.40	kJ/mol	NIST
ΔfH°liquid	-138.00	kJ/mol	NIST
ΔfusH°	8.72	kJ/mol	Joback Calculated Property
ΔvapH°	[29.20; 31.43]	kJ/mol
ΔvapH°	31.43	kJ/mol	NIST
ΔvapH°	31.30	kJ/mol	NIST
ΔvapH°	31.30 ± 0.20	kJ/mol	NIST
ΔvapH°	31.30	kJ/mol	NIST
ΔvapH°	29.20	kJ/mol	NIST
IE	[8.50; 9.44]	eV
IE	8.50 ± 0.10	eV	NIST
IE	8.78 ± 0.02	eV	NIST
IE	9.40 ± 0.30	eV	NIST
IE	9.44	eV	NIST
log10WS	0.05		Relay (1.0) Calculated Property
logPoct/wat	0.355		Crippen Calculated Property
McVol	63.110	ml/mol	McGowan Calculated Property
NFPA Fire	3		KDB
NFPA Health	3		KDB
Pc	[4720.00; 4737.96]	kPa
Pc	4720.00	kPa	KDB
Pc	4737.96 ± 101.32	kPa	NIST
Pc	4737.96 ± 40.53	kPa	NIST
Inp	[472.00; 542.00]
Inp	521.00		NIST
Inp	521.00		NIST
Inp	Outlier 472.00		NIST
Inp	542.00		NIST
Inp	518.00		NIST
Inp	515.00		NIST
Inp	515.00		NIST
Inp	527.00		NIST
Inp	528.00		NIST
Inp	524.00		NIST
Inp	526.00		NIST
Inp	510.00		NIST
Inp	542.00		NIST
Inp	518.00		NIST
Inp	518.00		NIST
Inp	527.00		NIST
I	[783.00; 817.00]
I	787.00		NIST
I	785.00		NIST
I	817.00		NIST
I	815.00		NIST
I	783.00		NIST
I	800.00		NIST
I	816.00		NIST
I	816.00		NIST
S°liquid	[227.44; 228.20]	J/mol×K
S°liquid	227.44	J/mol×K	NIST
S°liquid	228.20	J/mol×K	NIST
Tboil	320.37	K	KDB
Tc	[496.95; 499.20]	K
Tc	497.00	K	KDB
Tc	499.20	K	Gas-Liquid Critical Temperatures of Some Alkenes, Amines, and Cyclic Hydrocarbons
Tc	497.00	K	NIST
Tc	496.95 ± 1.50	K	NIST
Tc	496.95 ± 0.50	K	NIST
Tfus	[190.00; 190.15]	K
Tfus	190.00	K	KDB
Tfus	190.15	K	NIST
Tfus	190.00 ± 0.60	K	NIST
Tfus	190.15 ± 0.50	K	NIST
Ttriple	[188.36; 188.38]	K
Ttriple	188.36	K	KDB
Ttriple	188.38 ± 0.01	K	NIST
Ttriple	188.36 ± 0.07	K	NIST
Vc	0.233	m3/kmol	KDB
Vm	8.32e-05	m3/mol	Thermodynamic study of (heptane + amine) mixtures. II. Excess and partial molar volumes at 298.15 K
Zc	0.2661370		KDB

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[106.30; 145.07]	J/mol×K	[340.57; 522.57]
Cp,gas	106.30	J/mol×K	340.57	Joback Calculated Property
Cp,gas	113.40	J/mol×K	370.90	Joback Calculated Property
Cp,gas	120.24	J/mol×K	401.24	Joback Calculated Property
Cp,gas	126.82	J/mol×K	431.57	Joback Calculated Property
Cp,gas	133.15	J/mol×K	461.90	Joback Calculated Property
Cp,gas	139.23	J/mol×K	492.23	Joback Calculated Property
Cp,gas	145.07	J/mol×K	522.57	Joback Calculated Property
Cp,liquid	[160.00; 166.40]	J/mol×K	[298.15; 298.15]
Cp,liquid	162.51	J/mol×K	298.15	NIST
Cp,liquid	160.00	J/mol×K	298.15	NIST
Cp,liquid	166.40	J/mol×K	298.15	NIST
Cp,liquid	162.30	J/mol×K	298.15	NIST
η	[0.0003130; 0.0003851]	Pa×s	[288.15; 313.15]
η	0.0003851	Pa×s	288.15	Excess molar volume, viscosity, and refractive index study for the ternary mixture {2-methyl-2-butanol (1) + tetrahydrofuran (2) + propylamine (3)} at different temperatures. Application of the ERAS-model and Peng Robinson Stryjek Vera equation of state
η	0.0003585	Pa×s	298.15	Excess molar volume, viscosity, and refractive index study for the ternary mixture {2-methyl-2-butanol (1) + tetrahydrofuran (2) + propylamine (3)} at different temperatures. Application of the ERAS-model and Peng Robinson Stryjek Vera equation of state
η	0.0003530	Pa×s	303.15	Studies of viscosities of dilute solutions of alkylamine in non-electrolyte solvents. II. Haloalkanes and other polar solvents
η	0.0003222	Pa×s	308.15	Excess molar volume, viscosity, and refractive index study for the ternary mixture {2-methyl-2-butanol (1) + tetrahydrofuran (2) + propylamine (3)} at different temperatures. Application of the ERAS-model and Peng Robinson Stryjek Vera equation of state
η	0.0003130	Pa×s	313.15	Studies of viscosities of dilute solutions of alkylamine in non-electrolyte solvents. II. Haloalkanes and other polar solvents
ΔfusH	[10.62; 10.97]	kJ/mol	[188.36; 188.40]
ΔfusH	10.97	kJ/mol	188.36	NIST
ΔfusH	10.62	kJ/mol	188.36	NIST
ΔfusH	10.97	kJ/mol	188.40	NIST
ΔvapH	[28.90; 31.30]	kJ/mol	[313.00; 328.00]
ΔvapH	30.10	kJ/mol	313.00	NIST
ΔvapH	29.55	kJ/mol	320.40	NIST
ΔvapH	29.71	kJ/mol	322.20	KDB
ΔvapH	31.30	kJ/mol	323.00	NIST
ΔvapH	28.90	kJ/mol	328.00	NIST
ρl	[696.04; 717.00]	kg/m3	[293.00; 313.15]
ρl	717.00	kg/m3	293.00	KDB
ρl	716.48	kg/m3	293.15	Volumetric properties of binary mixtures of (acetonitrile + amines) at several temperatures with application of the ERAS model
ρl	712.25	kg/m3	298.15	Speeds of Sound and Isentropic Compressibilities of n-Alkoxyethanols and Polyethers with Propylamine at 298.15K
ρl	711.21	kg/m3	298.15	Volumetric properties of binary mixtures of (acetonitrile + amines) at several temperatures with application of the ERAS model
ρl	711.80	kg/m3	298.15	Speed of sound as a function of temperature and pressure for propane derivatives
ρl	712.76	kg/m3	298.15	Excess enthalpies of binary mixtures of some propylamines + some propanols at 298.15K
ρl	705.88	kg/m3	303.15	Volumetric properties of binary mixtures of (acetonitrile + amines) at several temperatures with application of the ERAS model
ρl	706.10	kg/m3	303.15	Studies of partial molar volumes of alkylamine in non-electrolyte solvents I. Alkylamines in hydrocarbons at 303.15 and 313.15K
ρl	706.10	kg/m3	303.15	Studies of viscosities of dilute solutions of alkylamines in non-electrolyte solvents III. Alkylamines in butanols 303.15K
ρl	700.62	kg/m3	308.15	Volumetric properties of binary mixtures of (acetonitrile + amines) at several temperatures with application of the ERAS model
ρl	696.04	kg/m3	313.15	Studies of partial molar volumes of alkylamine in non-electrolyte solvents I. Alkylamines in hydrocarbons at 303.15 and 313.15K
ΔfusS	[56.40; 58.26]	J/mol×K	[188.36; 188.36]
ΔfusS	58.26	J/mol×K	188.36	NIST
ΔfusS	56.40	J/mol×K	188.36	NIST
csound,fluid	[1169.93; 1266.07]	m/s	[288.15; 308.15]
csound,fluid	1266.07	m/s	288.15	Mixing Properties for Binary Liquid Mixtures of Methyl tert-Butyl Ether with Propylamine and Dipropylamine at Temperatures from (288.15 to 308.15) K
csound,fluid	1242.02	m/s	293.15	Mixing Properties for Binary Liquid Mixtures of Methyl tert-Butyl Ether with Propylamine and Dipropylamine at Temperatures from (288.15 to 308.15) K
csound,fluid	1217.97	m/s	298.15	Mixing Properties for Binary Liquid Mixtures of Methyl tert-Butyl Ether with Propylamine and Dipropylamine at Temperatures from (288.15 to 308.15) K
csound,fluid	1193.96	m/s	303.15	Mixing Properties for Binary Liquid Mixtures of Methyl tert-Butyl Ether with Propylamine and Dipropylamine at Temperatures from (288.15 to 308.15) K
csound,fluid	1169.93	m/s	308.15	Mixing Properties for Binary Liquid Mixtures of Methyl tert-Butyl Ether with Propylamine and Dipropylamine at Temperatures from (288.15 to 308.15) K
γ	0.02	N/m	293.20	KDB

Datasets

Viscosity, Pa*s

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Viscosity, Pa*s - Liquid
303.15	101.33	0.0004
Reference

Correlations

Property	Value	Unit	Temperature (K)	Source
Pvap	[0.02; 4633.74]	kPa	[190.15; 496.95]	KDB Vapor Pressure Data
Equation			ln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A			5.49672e+01
Coefficient B			-5.34711e+03
Coefficient C			-5.90378e+00
Coefficient D			3.59300e-06
Temperature range, min.			190.15
Temperature range, max.			496.95
Pvap	0.02	kPa	190.15	Calculated Property
Pvap	0.52	kPa	224.24	Calculated Property
Pvap	5.57	kPa	258.33	Calculated Property
Pvap	32.00	kPa	292.42	Calculated Property
Pvap	121.48	kPa	326.51	Calculated Property
Pvap	345.78	kPa	360.59	Calculated Property
Pvap	800.92	kPa	394.68	Calculated Property
Pvap	1595.02	kPa	428.77	Calculated Property
Pvap	2837.43	kPa	462.86	Calculated Property
Pvap	4633.74	kPa	496.95	Calculated Property

Similar Compounds

Find more compounds similar to Propylamine.

Mixtures

• Propylamine + Ethanol, 2-methoxy-
• Propylamine + Ethanol, 2-(2-methoxyethoxy)-
• Propylamine + Ethanol, 2-[2-(2-methoxyethoxy)ethoxy]-
• Ethanol, 2-(2-ethoxyethoxy)- + Propylamine
• Propylamine + Ethanol, 2-(2-butoxyethoxy)-
• Propylamine + Diethyl carbitol
• Propylamine + Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-
• Propylamine + Tetrahydrofuran
• Propylamine + Amylene hydrate
• Propylamine + Amylene hydrate + Tetrahydrofuran
• Propylamine + Heptane
• Acetonitrile + Propylamine
• Propylamine + Carbon Tetrachloride
• Trichloromethane + Propylamine
• Propylamine + Cyclohexane
• Benzene + Propylamine
• Propylene Glycol + Propylamine
• 1,3-Propanediol + Propylamine
• Propylamine + 1-Butanol
• Propylamine + 1,4-Dioxane

Find more mixtures with Propylamine.

Sources

• KDB Vapor Pressure Data
• Cheméo Relay (1.0)
• Crippen Method
• Crippen Method
• Speeds of Sound and Isentropic Compressibilities of n-Alkoxyethanols and Polyethers with Propylamine at 298.15K
• Thermodynamic study of heptane + amine mixtures. V. Excess and solvation Gibbs energies
• Excess molar volume, viscosity, and refractive index study for the ternary mixture {2-methyl-2-butanol (1) + tetrahydrofuran (2) + propylamine (3)} at different temperatures. Application of the ERAS-model and Peng Robinson Stryjek Vera equation of state
• Thermodynamic study of (heptane + amine) mixtures. II. Excess and partial molar volumes at 298.15 K
• Volumetric properties of binary mixtures of (acetonitrile + amines) at several temperatures with application of the ERAS model
• Speed of sound as a function of temperature and pressure for propane derivatives
• Studies of viscosities of dilute solutions of alkylamine in non-electrolyte solvents. II. Haloalkanes and other polar solvents
• Studies of partial molar volumes of alkylamine in non-electrolyte solvents I. Alkylamines in hydrocarbons at 303.15 and 313.15K
• Excess enthalpies of binary mixtures of some propylamines + some propanols at 298.15K
• Studies of viscosities of dilute solutions of alkylamines in non-electrolyte solvents III. Alkylamines in butanols 303.15K
• Studies of viscosities of dilute solutions of alkylamines in non-electrolyte solvents: IV. Alkylamines in 1,4-dioxane and oxolane at 303.15K
• Gas-Liquid Critical Temperatures of Some Alkenes, Amines, and Cyclic Hydrocarbons
• Mixing Properties for Binary Liquid Mixtures of Methyl tert-Butyl Ether with Propylamine and Dipropylamine at Temperatures from (288.15 to 308.15) K
• Joback Method
• KDB
• McGowan Method
• NIST Webbook

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