Chemical Properties of Nitrogen dioxide (CAS 10102-44-0)

Nitrogen dioxide

InChI
InChI=1S/NO2/c2-1-3
InChI Key
JCXJVPUVTGWSNB-UHFFFAOYSA-N
Formula
NO2
SMILES
[O]N=O
Molecular Weight1
46.01
CAS
10102-44-0
Other Names
  • Azote
  • Nitrito
  • Nitro
  • Nitrogen dioxide (NO2)
  • Nitrogen oxide
  • Nitrogen peroxide
  • Rcra waste number P078
  • Stickstoffdioxid
  • Stikstofdioxyde
  • nitrogen oxide (NO2)
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Physical Properties

Property Value Unit Source
ω [0.8340; 0.8511]   Show Hide
ω 0.8511 ChemSep v8.3 pure component data
ω 0.8340 KDB
PAff 591.00 kJ/mol NIST
BasG 560.30 kJ/mol NIST
μ [0.31; 0.40] debye Show Hide
μ 0.31 debye ChemSep v8.3 pure component data
μ 0.40 debye KDB
EA [1.80; 3.99] eV Show Hide
EA 2.27 ± 0.01 eV NIST
EA 2.30 ± 0.10 eV NIST
EA 2.27 ± 0.03 eV NIST
EA 2.36 ± 0.10 eV NIST
EA 2.35 ± 0.10 eV NIST
EA 2.40 ± 0.10 eV NIST
EA 2.28 ± 0.10 eV NIST
EA 2.38 ± 0.06 eV NIST
EA 2.30 ± 0.15 eV NIST
EA 2.11 ± 0.18 eV NIST
EA 2.80 ± 0.05 eV NIST
EA 1.80 ± 0.05 eV NIST
EA 2.60 eV NIST
EA 1.80 ± 0.20 eV NIST
EA 2.10 eV NIST
EA 2.50 ± 0.05 eV NIST
EA 2.50 ± 0.10 eV NIST
EA 2.50 ± 0.10 eV NIST
EA 2.04 eV NIST
EA 2.07 ± 0.24 eV NIST
EA 3.10 ± 0.05 eV NIST
EA Outlier 3.90 ± 0.20 eV NIST
EA Outlier 3.82 eV NIST
EA Outlier 3.99 eV NIST
ΔfG° [51.33; 52.00] kJ/mol Show Hide
ΔfG° 51.33 kJ/mol ChemSep v8.3 pure component data
ΔfG° 52.00 kJ/mol KDB
ΔfH°gas [33.18; 33.87] kJ/mol Show Hide
ΔfH°gas 33.18 kJ/mol ChemSep v8.3 pure component data
ΔfH°gas 33.87 kJ/mol KDB
ΔfusH° 8.80 kJ/mol Joback Calculated Property
IE [9.59; 11.23] eV Show Hide
IE 9.59 ± 0.00 eV NIST
IE 9.60 ± 0.03 eV NIST
IE 9.59 ± 0.00 eV NIST
IE 11.23 eV NIST
IE 10.40 ± 0.30 eV NIST
IE 9.62 ± 0.01 eV NIST
IE 9.75 ± 0.01 eV NIST
IE 11.23 eV NIST
logPoct/wat 0.098 Crippen Calculated Property
McVol 26.130 ml/mol McGowan Calculated Property
Pc [10100.00; 10132.50] kPa Show Hide
Pc 10132.50 kPa ChemSep v8.3 pure component data
Pc 10132.00 kPa Air Liquide Gas Encyclopedia
Pc 10100.00 kPa KDB
Ptriple [18.70; 18.73] kPa Show Hide
Ptriple 18.73 kPa ChemSep v8.3 pure component data
Ptriple 18.70 kPa Air Liquide Gas Encyclopedia
ρc 557.72 kg/m3 Air Liquide Gas Encyclopedia
Tboil [294.15; 295.08] K Show Hide
Tboil 294.15 K ChemSep v8.3 pure component data
Tboil 294.15 K Air Liquide Gas Encyclopedia
Tboil 294.30 K KDB
Tboil 295.08 ± 0.50 K NIST
Tc [431.00; 431.15] K Show Hide
Tc 431.15 K ChemSep v8.3 pure component data
Tc 431.15 K Air Liquide Gas Encyclopedia
Tc 431.00 K KDB
Tfus [261.90; 261.95] K Show Hide
Tfus 261.90 K ChemSep v8.3 pure component data
Tfus 261.95 K Air Liquide Gas Encyclopedia
Tfus 261.90 K KDB
Ttriple [261.90; 261.90] K Show Hide
Ttriple 261.90 K ChemSep v8.3 pure component data
Ttriple 261.90 K Air Liquide Gas Encyclopedia
UQi 1.13 ChemSep v8.3 pure component data
URi 1.05 ChemSep v8.3 pure component data
Vc [0.082; 0.168] m3/kmol Show Hide
Vc 0.082 m3/kmol ChemSep v8.3 pure component data
Vc 0.168 m3/kmol KDB
Zc [0.2330000; 0.4729330]   Show Hide
Zc 0.2330000 ChemSep v8.3 pure component data
Zc 0.4729330 KDB
Zra 0.24 KDB

Cheméo can also estimate Enthalpy of vaporization at standard conditions, Log10 of Water solubility in mol/l for this compound, but they fall outside the models' validated range, so they are not shown here. Open the prediction tool to compute them on demand.

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
ΔfusH 14.65 kJ/mol 261.95 Air Liquide Gas Encyclopedia
ΔvapH 38.12 kJ/mol 294.15 Air Liquide Gas Encyclopedia
ρg 3.40 kg/m3 294.15 Air Liquide Gas Encyclopedia
ρl [1447.58; 1450.00] kg/m3 [293.00; 294.15] Show Hide
ρl 1450.00 kg/m3 293.00 KDB
ρl 1447.58 kg/m3 294.15 Air Liquide Gas Encyclopedia

Correlations

Property Value Unit Temperature (K) Source
Cp,gas [32.96; 56.49] J/mol×K [50.00; 1500.00] ChemSep v8.3 pure component data Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is Cp,gas in J/mol×K, T in K
Coefficient A3.29630e+01
Coefficient B-5.78775e+02
Coefficient C3.54145e+00
Coefficient D7.93322e-05
Coefficient E-5.18104e-08
CommentChemSep eq 16, IdealGasHeatCapacityCp
Temperature range, min.50.00
Temperature range, max.1500.00
Cp,gas 32.96 J/mol×K 50.00 Calculated Property
Cp,gas 35.22 J/mol×K 211.11 Calculated Property
Cp,gas 40.42 J/mol×K 372.22 Calculated Property
Cp,gas 44.95 J/mol×K 533.33 Calculated Property
Cp,gas 48.42 J/mol×K 694.44 Calculated Property
Cp,gas 51.04 J/mol×K 855.56 Calculated Property
Cp,gas 53.03 J/mol×K 1016.67 Calculated Property
Cp,gas 54.54 J/mol×K 1177.78 Calculated Property
Cp,gas 55.67 J/mol×K 1338.89 Calculated Property
Cp,gas 56.49 J/mol×K 1500.00 Calculated Property
Cp,gas [36.97; 53.76] J/mol×K [298.00; 1200.00] NIST Show Hide
EquationY = A + B·t + C·t² + D·t³ + E/t², t = T/1000
Y is Cp,gas in J/mol×K, T in K
Coefficient A1.61086e+01
Coefficient B7.58953e+01
Coefficient C-5.43874e+01
Coefficient D1.43078e+01
Coefficient E2.39423e-01
ReferenceChase, 1998
CommentF=26.17464, G=240.5386, H=33.09502; Data last reviewed in September, 1964
Temperature range, min.298.00
Temperature range, max.1200.00
Cp,gas 36.97 J/mol×K 298.00 Calculated Property
Cp,gas 40.12 J/mol×K 398.22 Calculated Property
Cp,gas 43.16 J/mol×K 498.44 Calculated Property
Cp,gas 45.79 J/mol×K 598.67 Calculated Property
Cp,gas 47.96 J/mol×K 698.89 Calculated Property
Cp,gas 49.70 J/mol×K 799.11 Calculated Property
Cp,gas 51.08 J/mol×K 899.33 Calculated Property
Cp,gas 52.16 J/mol×K 999.56 Calculated Property
Cp,gas 53.02 J/mol×K 1099.78 Calculated Property
Cp,gas 53.76 J/mol×K 1200.00 Calculated Property
Cp,gas [53.73; 58.00] J/mol×K [1200.00; 6000.00] NIST Show Hide
EquationY = A + B·t + C·t² + D·t³ + E/t², t = T/1000
Y is Cp,gas in J/mol×K, T in K
Coefficient A5.68254e+01
Coefficient B7.38053e-01
Coefficient C-1.44721e-01
Coefficient D9.77700e-03
Coefficient E-5.45991e+00
ReferenceChase, 1998
CommentF=2.846456, G=290.5056, H=33.09502; Data last reviewed in September, 1964
Temperature range, min.1200.00
Temperature range, max.6000.00
Cp,gas 53.73 J/mol×K 1200.00 Calculated Property
Cp,gas 55.90 J/mol×K 1733.33 Calculated Property
Cp,gas 56.81 J/mol×K 2266.67 Calculated Property
Cp,gas 57.28 J/mol×K 2800.00 Calculated Property
Cp,gas 57.55 J/mol×K 3333.33 Calculated Property
Cp,gas 57.72 J/mol×K 3866.67 Calculated Property
Cp,gas 57.82 J/mol×K 4400.00 Calculated Property
Cp,gas 57.89 J/mol×K 4933.33 Calculated Property
Cp,gas 57.95 J/mol×K 5466.67 Calculated Property
Cp,gas 58.00 J/mol×K 6000.00 Calculated Property
Property Value Unit Temperature (K) Source
Cp,liquid [136.33; 158.73] J/mol×K [261.00; 400.00] ChemSep v8.3 pure component data Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is Cp,liquid in J/mol×K, T in K
Coefficient A7.74350e+01
Coefficient B4.32690e+02
Coefficient C-1.53406e+00
Coefficient D2.08040e-02
Coefficient E-2.16950e-05
CommentChemSep eq 16, LiquidHeatCapacityCp
Temperature range, min.261.00
Temperature range, max.400.00
Cp,liquid 136.33 J/mol×K 261.00 Calculated Property
Cp,liquid 139.26 J/mol×K 276.44 Calculated Property
Cp,liquid 142.31 J/mol×K 291.89 Calculated Property
Cp,liquid 145.36 J/mol×K 307.33 Calculated Property
Cp,liquid 148.33 J/mol×K 322.78 Calculated Property
Cp,liquid 151.12 J/mol×K 338.22 Calculated Property
Cp,liquid 153.64 J/mol×K 353.67 Calculated Property
Cp,liquid 155.80 J/mol×K 369.11 Calculated Property
Cp,liquid 157.52 J/mol×K 384.56 Calculated Property
Cp,liquid 158.73 J/mol×K 400.00 Calculated Property
Property Value Unit Temperature (K) Source
η [0.0007090; 0.0000769] Pa×s [253.15; 400.00] ChemSep v8.3 pure component data Show Hide
EquationY = exp(A + B/T + C·ln(T) + D·T^E)
Y is η in Pa×s, T in K
Coefficient A-3.11490e+02
Coefficient B1.00410e+04
Coefficient C4.90270e+01
Coefficient D-1.05180e-04
Coefficient E2.00000e+00
CommentChemSep eq 101, LiquidViscosity
Temperature range, min.253.15
Temperature range, max.400.00
η 0.0007090 Pa×s 253.15 Calculated Property
η 0.0005598 Pa×s 269.47 Calculated Property
η 0.0004592 Pa×s 285.78 Calculated Property
η 0.0003818 Pa×s 302.10 Calculated Property
η 0.0003160 Pa×s 318.42 Calculated Property
η 0.0002567 Pa×s 334.73 Calculated Property
η 0.0002024 Pa×s 351.05 Calculated Property
η 0.0001536 Pa×s 367.37 Calculated Property
η 0.0001114 Pa×s 383.68 Calculated Property
η 0.0000769 Pa×s 400.00 Calculated Property
Property Value Unit Temperature (K) Source
ΔvapH [38.32; 0.00] kJ/mol [291.15; 431.15] ChemSep v8.3 pure component data Show Hide
EquationY = A·(1 − Tr)^(B + C·Tr + D·Tr² + E·Tr³), Tr = T/Tc
Y is ΔvapH in kJ/mol, T in K
Coefficient A5.37000e+01
Coefficient B3.00000e-01
Coefficient C0.00000e+00
Coefficient D0.00000e+00
Coefficient E0.00000e+00
Critical temperature, Tc (K)4.31150e+02
CommentChemSep eq 106, HeatOfVaporization
Temperature range, min.291.15
Temperature range, max.431.15
ΔvapH 38.32 kJ/mol 291.15 Calculated Property
ΔvapH 36.99 kJ/mol 306.71 Calculated Property
ΔvapH 35.54 kJ/mol 322.26 Calculated Property
ΔvapH 33.93 kJ/mol 337.82 Calculated Property
ΔvapH 32.12 kJ/mol 353.37 Calculated Property
ΔvapH 30.04 kJ/mol 368.93 Calculated Property
ΔvapH 27.56 kJ/mol 384.48 Calculated Property
ΔvapH 24.40 kJ/mol 400.04 Calculated Property
ΔvapH 19.82 kJ/mol 415.59 Calculated Property
ΔvapH 0.00 kJ/mol 431.15 Calculated Property
Property Value Unit Temperature (K) Source
Pvap [18.74; 10124.77] kPa [261.95; 431.35] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A2.04197e+01
Coefficient B-5.27208e+03
Coefficient C3.95000e+01
Temperature range, min.261.95
Temperature range, max.431.35
Pvap 18.74 kPa 261.95 Calculated Property
Pvap 52.38 kPa 280.77 Calculated Property
Pvap 130.60 kPa 299.59 Calculated Property
Pvap 295.83 kPa 318.42 Calculated Property
Pvap 617.51 kPa 337.24 Calculated Property
Pvap 1201.80 kPa 356.06 Calculated Property
Pvap 2201.67 kPa 374.88 Calculated Property
Pvap 3826.69 kPa 393.71 Calculated Property
Pvap 6351.87 kPa 412.53 Calculated Property
Pvap 10124.77 kPa 431.35 Calculated Property
Pvap [11.36; 10121.54] kPa [252.77; 431.37] ChemSep v8.3 pure component data Show Hide
EquationY = exp(A + B/T + C·ln(T) + D·T^E)
Y is Pvap in kPa, T in K
Coefficient A1.14962e+01
Coefficient B-3.50860e+03
Coefficient C8.12550e-01
Coefficient D4.99830e-06
Coefficient E2.00000e+00
CommentChemSep eq 101, VaporPressure
Temperature range, min.252.77
Temperature range, max.431.37
Pvap 11.36 kPa 252.77 Calculated Property
Pvap 34.97 kPa 272.61 Calculated Property
Pvap 93.76 kPa 292.46 Calculated Property
Pvap 225.07 kPa 312.30 Calculated Property
Pvap 493.55 kPa 332.15 Calculated Property
Pvap 1004.42 kPa 351.99 Calculated Property
Pvap 1920.80 kPa 371.84 Calculated Property
Pvap 3486.12 kPa 391.68 Calculated Property
Pvap 6053.14 kPa 411.53 Calculated Property
Pvap 10121.54 kPa 431.37 Calculated Property
Pvap [0.11; 103.91] kPa [217.60; 294.00] NIST Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.23245e+01
Coefficient B-1.24486e+03
Coefficient C-1.31930e+02
ReferenceStull, 1947
CommentCoefficents calculated by NIST from author's data.
Temperature range, min.217.60
Temperature range, max.294.00
Pvap 0.11 kPa 217.60 Calculated Property
Pvap 0.41 kPa 226.09 Calculated Property
Pvap 1.22 kPa 234.58 Calculated Property
Pvap 3.08 kPa 243.07 Calculated Property
Pvap 6.81 kPa 251.56 Calculated Property
Pvap 13.57 kPa 260.04 Calculated Property
Pvap 24.82 kPa 268.53 Calculated Property
Pvap 42.30 kPa 277.02 Calculated Property
Pvap 67.97 kPa 285.51 Calculated Property
Pvap 103.91 kPa 294.00 Calculated Property
Property Value Unit Temperature (K) Source
ρl [1519.36; 538.42] kg/m3 [261.90; 431.37] ChemSep v8.3 pure component data Show Hide
EquationY = A / B^(1 + (1 − T/C)^D)
Y is ρl in kg/m3, T in K
Coefficient A1.02036e+02
Coefficient B2.29940e-01
Coefficient C4.31380e+02
Coefficient D1.90060e-01
CommentChemSep eq 105, LiquidDensity
Temperature range, min.261.90
Temperature range, max.431.37
ρl 1519.36 kg/m3 261.90 Calculated Property
ρl 1478.53 kg/m3 280.73 Calculated Property
ρl 1434.60 kg/m3 299.56 Calculated Property
ρl 1386.82 kg/m3 318.39 Calculated Property
ρl 1334.03 kg/m3 337.22 Calculated Property
ρl 1274.44 kg/m3 356.05 Calculated Property
ρl 1204.88 kg/m3 374.88 Calculated Property
ρl 1118.86 kg/m3 393.71 Calculated Property
ρl 998.20 kg/m3 412.54 Calculated Property
ρl 538.42 kg/m3 431.37 Calculated Property
Property Value Unit Temperature (K) Source
γ [0.03; 0.00] N/m [261.90; 422.24] ChemSep v8.3 pure component data Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is γ in N/m, T in K
Coefficient A-9.33460e-02
Coefficient B-8.00910e+01
Coefficient C-1.09500e+00
Coefficient D-2.60370e-03
Coefficient E2.07710e-07
CommentChemSep eq 16, SurfaceTension
Temperature range, min.261.90
Temperature range, max.422.24
γ 0.03 N/m 261.90 Calculated Property
γ 0.03 N/m 279.72 Calculated Property
γ 0.03 N/m 297.53 Calculated Property
γ 0.02 N/m 315.35 Calculated Property
γ 0.02 N/m 333.16 Calculated Property
γ 0.02 N/m 350.98 Calculated Property
γ 0.01 N/m 368.79 Calculated Property
γ 0.01 N/m 386.61 Calculated Property
γ 0.01 N/m 404.42 Calculated Property
γ 0.00 N/m 422.24 Calculated Property
Property Value Unit Temperature (K) Source
λ [0.04; 0.09] W/m×K [420.00; 1000.00] ChemSep v8.3 pure component data Show Hide
EquationY = A·T^B / (1 + C/T + D/T²)
Y is λ in W/m×K, T in K
Coefficient A7.08510e-02
Coefficient B-2.14300e-01
Coefficient C-1.25800e+03
Coefficient D4.29500e+05
CommentChemSep eq 102, VaporThermalConductivity
Temperature range, min.420.00
Temperature range, max.1000.00
λ 0.04 W/m×K 420.00 Calculated Property
λ 0.08 W/m×K 484.44 Calculated Property
λ 0.14 W/m×K 548.89 Calculated Property
λ 0.20 W/m×K 613.33 Calculated Property
λ 0.22 W/m×K 677.78 Calculated Property
λ 0.20 W/m×K 742.22 Calculated Property
λ 0.17 W/m×K 806.67 Calculated Property
λ 0.14 W/m×K 871.11 Calculated Property
λ 0.11 W/m×K 935.56 Calculated Property
λ 0.09 W/m×K 1000.00 Calculated Property
Property Value Unit Temperature (K) Source
λ [0.16; 0.12] W/m×K [270.00; 350.00] ChemSep v8.3 pure component data Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is λ in W/m×K, T in K
Coefficient A1.16110e-01
Coefficient B1.27610e+05
Coefficient C-1.40910e+03
Coefficient D5.17770e+00
Coefficient E-6.37380e-03
CommentChemSep eq 16, LiquidThermalConductivity
Temperature range, min.270.00
Temperature range, max.350.00
λ 0.16 W/m×K 270.00 Calculated Property
λ 0.15 W/m×K 278.89 Calculated Property
λ 0.15 W/m×K 287.78 Calculated Property
λ 0.14 W/m×K 296.67 Calculated Property
λ 0.13 W/m×K 305.56 Calculated Property
λ 0.12 W/m×K 314.44 Calculated Property
λ 0.12 W/m×K 323.33 Calculated Property
λ 0.12 W/m×K 332.22 Calculated Property
λ 0.12 W/m×K 341.11 Calculated Property
λ 0.12 W/m×K 350.00 Calculated Property

Similar Compounds

Nitrogen oxide anion. NO3 anion. Nitrogen trioxide. Potassium nitrite. Nitrous acid. Silver nitrite. Nitric oxide. Nitric oxide anion. dinitrogen trioxide. nitric acid. Fluorine nitrate. Potassium nitrate. Silver nitrate. Sodium nitrate. Chlorine nitrate.

Find more compounds similar to Nitrogen dioxide.

Mixtures

Sources

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