Chemical Properties of Hydroquinone (CAS 123-31-9)

Hydroquinone

InChI
InChI=1S/C6H6O2/c7-5-1-2-6(8)4-3-5/h1-4,7-8H
InChI Key
QIGBRXMKCJKVMJ-UHFFFAOYSA-N
Formula
C6H6O2
SMILES
Oc1ccc(O)cc1
Molecular Weight1
110.11
CAS
123-31-9
Other Names
  • 1,4-Benzenediol (hydroquinone)
  • 1,4-Dihydroxy-benzeen
  • 1,4-Dihydroxy-benzol
  • 1,4-Dihydroxybenzen
  • 1,4-Diidrobenzene
  • 1,4-benzenediol
  • 1,4-dihydroxybenzene
  • 4-Hydroxyphenol
  • Aida
  • Arctuvin
  • Benzene, p-dihydroxy-
  • Black & White Bleaching Cream
  • Black and White Bleaching Cream
  • Derma-Blanch
  • Diak 5
  • Dihydroquinone
  • Eldopacque
  • Eldopaque
  • Eldopaque forte
  • Eldoquin
  • Eldoquin forte
  • HE 5
  • Hidroquinone
  • Hydrochinon
  • Hydrochinone
  • Hydroquinol
  • Hydroquinole
  • Idrochinone
  • NCI-C55834
  • Phiaquin
  • Quinol
  • Solaquin forte
  • Tecquinol
  • Tenox HQ
  • Tequinol
  • UN 2662
  • USAF EK-356
  • benzohydroquinone
  • benzoquinol
  • p-Dihydroquinone
  • p-Dioxobenzene
  • p-Hydroquinone
  • p-benzenediol
  • p-dihydroxybenzene
  • p-dioxybenzene
  • p-hydroxyphenol
  • p-quinol
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Physical Properties

Property Value Unit Source
ω 0.6598 PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tig 789.15 K NCMS SOLV-DB
ΔcH°solid [-2865.00; -2824.68] kJ/mol Show Hide
ΔcH°solid -2847.50 ± 1.20 kJ/mol NIST
ΔcH°solid Outlier -2824.68 kJ/mol NIST
ΔcH°solid -2852.40 ± 0.88 kJ/mol NIST
ΔcH°solid -2855.60 kJ/mol NIST
ΔcH°solid -2858.00 kJ/mol NIST
ΔcH°solid -2865.00 kJ/mol NIST
ΔcH°solid -2856.00 kJ/mol NIST
ΔcH°solid -2861.00 kJ/mol NIST
Tflash,cc 438.15 K NCMS SOLV-DB
ΔfG° -187.56 kJ/mol Joback Calculated Property
ΔfH°gas [-277.00; -266.90] kJ/mol Show Hide
ΔfH°gas -277.00 ± 1.40 kJ/mol NIST
ΔfH°gas -272.00 kJ/mol NIST
ΔfH°gas -268.90 kJ/mol NIST
ΔfH°gas -266.90 kJ/mol NIST
ΔfH°gas -268.40 kJ/mol NIST
ΔfH°solid [-371.10; -361.00] kJ/mol Show Hide
ΔfH°solid -371.10 ± 1.30 kJ/mol NIST
ΔfH°solid -366.10 ± 1.20 kJ/mol NIST
ΔfH°solid -363.00 ± 1.00 kJ/mol NIST
ΔfH°solid -361.00 kJ/mol NIST
ΔfH°solid -362.50 kJ/mol NIST
ΔfusH° [23.78; 27.23] kJ/mol Show Hide
ΔfusH° 27.23 kJ/mol Di-Hydroxybenzenes: Catechol, Resorcinol, and Hydroquinone. Enthalpies of Phase Transitions Revisited
ΔfusH° 23.78 kJ/mol Measurement of enthalpy curves of phase change materials via DSC and T-History: When are both methods needed to estimate the behaviour of the bulk material in applications?
ΔsubH° [94.10; 103.76] kJ/mol Show Hide
ΔsubH° 94.13 ± 0.53 kJ/mol NIST
ΔsubH° 94.10 kJ/mol NIST
ΔsubH° 94.10 ± 0.50 kJ/mol NIST
ΔsubH° 99.20 ± 1.70 kJ/mol NIST
ΔsubH° Outlier 103.76 kJ/mol NIST
ΔsubH° 94.13 ± 0.53 kJ/mol NIST
ΔsubH° 94.10 kJ/mol NIST
ΔsubH° 94.10 ± 0.50 kJ/mol NIST
ΔvapH° 84.40 ± 0.70 kJ/mol NIST
IE [7.93; 8.44] eV Show Hide
IE 7.94 ± 0.01 eV NIST
IE 7.93 ± 0.01 eV NIST
IE 7.95 ± 0.05 eV NIST
IE 7.95 ± 0.03 eV NIST
IE 8.44 eV NIST
log10WS [-0.17; -0.17]   Show Hide
log10WS -0.17 Aq. Solubility Prediction
log10WS -0.17 Estimated Solubility
logPoct/wat 0.590 NCMS SOLV-DB
McVol 83.380 ml/mol McGowan Calculated Property
NFPA Fire 1 NCMS SOLV-DB
NFPA Health 2 NCMS SOLV-DB
NFPA Safety 0 NCMS SOLV-DB
Pc 6749.97 kPa PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
pKa 10.85 NCMS SOLV-DB
Inp [207.49; 1334.00]   Show Hide
Inp 1327.00 NIST
Inp 1334.00 NIST
Inp 1241.00 NIST
Inp 1334.00 NIST
Inp 220.60 NIST
Inp 207.49 NIST
Inp 1327.00 NIST
Inp 1334.00 NIST
Inp 1241.00 NIST
Inp 220.60 NIST
Ip [2693.00; 2693.00]   Show Hide
Ip 2693.00 NIST
Ip 2693.00 NIST
Ip 2693.00 NIST
S°gas 343.10 ± 5.00 J/mol×K NIST
Tboil [558.15; 558.20] K Show Hide
Tboil 558.15 K NCMS SOLV-DB
Tboil 558.20 K NIST
Tboil 558.20 ± 1.00 K NIST
Tc 820.00 K PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tfus [443.50; 446.65] K Show Hide
Tfus 445.15 K Liquid pharmaceuticals formulation by eutectic formation
Tfus 445.00 K Enthalpies of formation of dihydroxybenzenes revisited: Combining experimental and high-level ab initio data
Tfus 444.80 K Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Tfus 445.35 K Aq. Solubility Prediction
Tfus Outlier 446.65 K NCMS SOLV-DB
Tfus 445.00 ± 0.60 K NIST
Tfus 445.00 K NIST
Tfus Outlier 443.50 ± 0.30 K NIST
Tfus 445.00 ± 0.60 K NIST
Ttriple [445.50; 445.98] K Show Hide
Ttriple 445.98 ± 0.03 K NIST
Ttriple 445.50 ± 0.30 K NIST
Ttriple 445.98 ± 0.03 K NIST
Ttriple 445.50 ± 0.30 K NIST
Vc 0.292 m3/kmol PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,solid [130.50; 150.20] J/mol×K [274.30; 323.00] Show Hide
Cp,solid 130.50 J/mol×K 274.30 NIST
Cp,solid 133.50 J/mol×K 297.90 NIST
Cp,solid 139.70 J/mol×K 298.00 NIST
Cp,solid 131.90 J/mol×K 298.15 NIST
Cp,solid 136.40 J/mol×K 298.15 NIST
Cp,solid 150.20 J/mol×K 323.00 NIST
ΔfusH [26.48; 27.23] kJ/mol [444.95; 453.00] Show Hide
ΔfusH 26.50 kJ/mol 444.95 NIST
ΔfusH 26.50 kJ/mol 444.95 NIST
ΔfusH 27.23 kJ/mol 445.10 NIST
ΔfusH 27.11 kJ/mol 445.10 NIST
ΔfusH 27.11 kJ/mol 445.10 NIST
ΔfusH 27.11 kJ/mol 445.50 NIST
ΔfusH 27.11 kJ/mol 445.50 NIST
ΔfusH 26.48 kJ/mol 453.00 NIST
ΔfusH 26.48 kJ/mol 453.00 NIST
ΔsubH [93.70; 104.00] kJ/mol [322.00; 370.50] Show Hide
ΔsubH 103.80 kJ/mol 322.00 NIST
ΔsubH 100.60 ± 1.30 kJ/mol 332.00 NIST
ΔsubH 93.70 ± 0.50 kJ/mol 334.00 NIST
ΔsubH 93.70 ± 0.50 kJ/mol 334.00 NIST
ΔsubH 103.80 kJ/mol 335.50 NIST
ΔsubH 104.00 ± 1.00 kJ/mol 342.00 NIST
ΔsubH 99.00 ± 2.00 kJ/mol 351.00 NIST
ΔsubH 101.30 kJ/mol 370.50 NIST
ΔvapH 70.50 kJ/mol 503.50 NIST
Psub [5.13e-05; 3.53e-04] kPa [322.80; 339.40] Show Hide
Psub 5.56e-05 kPa 322.80 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 5.45e-05 kPa 322.80 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 5.13e-05 kPa 322.80 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 6.59e-05 kPa 324.80 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 7.43e-05 kPa 324.90 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 6.93e-05 kPa 324.90 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 9.44e-05 kPa 326.90 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 8.72e-05 kPa 326.90 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 8.46e-05 kPa 326.90 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 1.13e-04 kPa 328.90 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 1.09e-04 kPa 329.00 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 1.05e-04 kPa 329.00 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 1.38e-04 kPa 331.00 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 1.38e-04 kPa 331.00 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 1.42e-04 kPa 331.10 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 1.77e-04 kPa 333.10 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 1.72e-04 kPa 333.20 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 1.69e-04 kPa 333.20 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 2.32e-04 kPa 335.20 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 2.17e-04 kPa 335.20 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 2.12e-04 kPa 335.20 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 2.62e-04 kPa 337.20 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 2.75e-04 kPa 337.30 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 2.64e-04 kPa 337.30 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 3.53e-04 kPa 339.20 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 3.40e-04 kPa 339.40 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Psub 3.33e-04 kPa 339.40 Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method
Pvap 1.33e-06 kPa 293.15 NCMS SOLV-DB
ρl 1328.00 kg/m3 293.15 Measurements of Liquid Liquid Equilibria for the Quaternary System 2-Methoxy-2-methylpropane + Phenol + Hydroquinone + Water at 313.15 K
ρs [1332.00; 1338.00] kg/m3 [293.20; 298.15] Show Hide
ρs 1332.00 kg/m3 293.20 Ternary and Quaternary Liquid-Liquid Equilibria for Systems of Methyl Butyl Ketone + Water + Hydroquinone + Phenol at 313.2 K and Atmospheric Pressure
ρs 1338.00 kg/m3 298.15 Liquid liquid equilibria for the quaternary system methyl isobutyl ketone water phenol hydroquinone
ΔfusS [59.00; 60.90] J/mol×K [444.95; 445.50] Show Hide
ΔfusS 59.00 J/mol×K 444.95 NIST
ΔfusS 59.00 J/mol×K 444.95 NIST
ΔfusS 60.90 J/mol×K 445.50 NIST
ΔfusS 60.90 J/mol×K 445.50 NIST

Pressure Dependent Properties

Property Value Unit Pressure (kPa) Source
Tboilr [558.00; 558.20] K [97.30; 97.30] Show Hide
Tboilr 558.20 K 97.30 NIST
Tboilr 558.00 K 97.30 NIST

Correlations

Property Value Unit Temperature (K) Source
Cp,gas [106.73; 258.23] J/mol×K [273.00; 1000.00] Joback Predicted correlation Show Hide
EquationY = A + B·T + C·T² + D·T³ + E·T⁴
Y is Cp,gas in J/mol×K, T in K
Coefficient A-6.86100e+01
Coefficient B8.63600e-01
Coefficient C-9.13560e-04
Coefficient D3.76800e-07
Coefficient E0.00000e+00
Temperature range, min.273.00
Temperature range, max.1000.00
Cp,gas 106.73 J/mol×K 273.00 Calculated Property
Cp,gas 139.26 J/mol×K 353.78 Calculated Property
Cp,gas 165.08 J/mol×K 434.56 Calculated Property
Cp,gas 185.39 J/mol×K 515.33 Calculated Property
Cp,gas 201.38 J/mol×K 596.11 Calculated Property
Cp,gas 214.24 J/mol×K 676.89 Calculated Property
Cp,gas 225.16 J/mol×K 757.67 Calculated Property
Cp,gas 235.34 J/mol×K 838.44 Calculated Property
Cp,gas 245.97 J/mol×K 919.22 Calculated Property
Cp,gas 258.23 J/mol×K 1000.00 Calculated Property
Property Value Unit Temperature (K) Source
η [0.0001729; 0.0000084] Pa×s [445.04; 574.00] Joback Predicted correlation Show Hide
EquationY = exp(A + B/T + C·ln(T) + D·T^E)
Y is η in Pa×s, T in K
Coefficient A-2.21125e+01
Coefficient B5.98564e+03
Coefficient C0.00000e+00
Coefficient D0.00000e+00
Coefficient E0.00000e+00
CommentLiquid phase. Joback/Reid (1987), valid from Tf to 0.7·Tc.
Temperature range, min.445.04
Temperature range, max.574.00
η 0.0001729 Pa×s 445.04 Calculated Property
η 0.0001136 Pa×s 459.37 Calculated Property
η 0.0000766 Pa×s 473.70 Calculated Property
η 0.0000529 Pa×s 488.03 Calculated Property
η 0.0000373 Pa×s 502.36 Calculated Property
η 0.0000268 Pa×s 516.69 Calculated Property
η 0.0000196 Pa×s 531.01 Calculated Property
η 0.0000146 Pa×s 545.34 Calculated Property
η 0.0000110 Pa×s 559.67 Calculated Property
η 0.0000084 Pa×s 574.00 Calculated Property
Property Value Unit Temperature (K) Source
Pvap [1.29; 103.16] kPa [432.30; 559.00] NIST Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.81782e+01
Coefficient B-7.02169e+03
Coefficient C-4.04850e+01
Referencevon Terres, Gebert, et al., 1955
CommentCoefficents calculated by NIST from author's data.
Temperature range, min.432.30
Temperature range, max.559.00
Pvap 1.29 kPa 432.30 Calculated Property
Pvap 2.41 kPa 446.38 Calculated Property
Pvap 4.30 kPa 460.46 Calculated Property
Pvap 7.40 kPa 474.53 Calculated Property
Pvap 12.30 kPa 488.61 Calculated Property
Pvap 19.82 kPa 502.69 Calculated Property
Pvap 31.05 kPa 516.77 Calculated Property
Pvap 47.41 kPa 530.84 Calculated Property
Pvap 70.69 kPa 544.92 Calculated Property
Pvap 103.16 kPa 559.00 Calculated Property

Similar Compounds

Phenol-d6-. Phenol. Resorcinol. Phenol, 4,4'-oxybis-. 1,2,4-Benzenetriol. 1,2-Benzenediol. Phenol, 4-iodo-. Mequinol. 4-(Trifluoromethoxy)phenol. PHENOL, 4-PHENOXY-. Phenol, 4-bromo-. Phenol, 4-chloro-. phenoxide anion. Phenol, 4-fluoro-. 2,6-Dihydroxynaphthalene.

Find more compounds similar to Hydroquinone.

Mixtures

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