Chemical Properties of Hydrogen sulfide (CAS 7783-06-4)

Hydrogen sulfide

InChI
InChI=1S/H2S/h1H2
InChI Key
RWSOTUBLDIXVET-UHFFFAOYSA-N
Formula
H2S
SMILES
S
Molecular Weight1
34.08
CAS
7783-06-4
Other Names
  • Acide sulfhydrique
  • DIHYDROGEN MONOSULFIDE
  • Dihydrogen sulfide
  • H2S
  • HYDROSULFURIC ACID
  • Hepatic acid
  • Hepatic gas
  • Hydrogen monosulfide
  • Hydrogen sulfide (H2S)
  • Hydrogen sulphide
  • Hydrogene sulfure
  • Idrogeno solforato
  • Rcra waste number U135
  • SULFUR HYDRIDE
  • Schwefelwasserstoff
  • Sewer gas
  • Siarkowodor
  • Stink damp
  • Sulfureted hydrogen
  • Sulfuretted hydrogen
  • UN 1053
  • Zwavelwaterstof
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Physical Properties

Property Value Unit Source
ω 0.0810 KDB
PAff 705.00 kJ/mol NIST
BasG 673.80 kJ/mol NIST
μ 0.90 debye KDB
Δf -33.08 kJ/mol KDB
Rg 0.6040 KDB
Δfgas [-20.60; 20.18] kJ/mol Show Hide
Δfgas 20.18 kJ/mol KDB
Δfgas -20.60 ± 0.50 kJ/mol NIST
Δvap 7.72 kJ/mol Relay (1.0) Calculated Property
IE [10.00; 20.80] eV Show Hide
IE 10.46 ± 0.01 eV NIST
IE 10.45 ± 0.01 eV NIST
IE 10.46 ± 0.00 eV NIST
IE 10.45 ± 0.01 eV NIST
IE 10.00 ± 4.00 eV NIST
IE 10.48 eV NIST
IE 10.47 ± 0.00 eV NIST
IE 10.56 ± 0.05 eV NIST
IE 10.50 eV NIST
IE 10.43 eV NIST
IE 10.45 eV NIST
IE 10.47 eV NIST
IE 10.43 eV NIST
IE 12.76 eV NIST
IE 14.91 eV NIST
IE Outlier 20.80 eV NIST
IE 18.00 eV NIST
IE 12.81 eV NIST
IE 14.79 eV NIST
IE 10.43 ± 0.01 eV NIST
IE 10.42 eV NIST
IE 12.62 eV NIST
IE 14.82 eV NIST
IE 18.00 eV NIST
IE Outlier 20.12 eV NIST
IE 10.45 ± 0.03 eV NIST
IE 10.46 ± 0.01 eV NIST
IE 10.47 ± 0.01 eV NIST
IE 10.50 eV NIST
IE 10.43 eV NIST
IE 10.47 eV NIST
IE 10.48 eV NIST
log10WS -2.02 Relay (1.0) Calculated Property
logPoct/wat 0.113 Crippen Calculated Property
McVol 27.210 ml/mol McGowan Calculated Property
NFPA Fire 4 KDB
NFPA Health 3 KDB
Pc [8940.00; 8970.00] kPa Show Hide
Pc 8940.00 kPa KDB
Pc 8970.00 ± 18.00 kPa NIST
Pc 8962.91 ± 30.00 kPa NIST
Ptriple [23.18; 23.20] kPa Show Hide
Ptriple 23.18 kPa KDB
Ptriple 23.20 ± 0.50 kPa NIST
ρc 347.63 ± 3.41 kg/m3 NIST
Inp [338.00; 340.00]   Show Hide
Inp 340.00 NIST
Inp 338.00 NIST
Inp 338.00 NIST
I [480.00; 480.00]   Show Hide
I 480.00 NIST
I 480.00 NIST
I 480.00 NIST
gas,1 bar 205.81 ± 0.05 J/mol×K NIST
Tboil [212.87; 213.60] K Show Hide
Tboil 213.60 K KDB
Tboil 212.87 ± 0.07 K NIST
Tc [373.20; 373.40] K Show Hide
Tc 373.20 K KDB
Tc 373.30 ± 0.37 K NIST
Tc 373.40 ± 0.15 K NIST
Tfus [187.60; 190.85] K Show Hide
Tfus 187.60 K KDB
Tfus 190.85 ± 1.50 K NIST
Ttriple [187.61; 187.67] K Show Hide
Ttriple 187.67 K KDB
Ttriple 187.66 ± 0.06 K NIST
Ttriple 187.61 ± 0.03 K NIST
Vc 0.099 m3/kmol KDB
Zc 0.2852290 KDB
Zra 0.28 KDB

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
η [0.0000119; 0.0000268] Pa×s [291.61; 682.03] Show Hide
η 0.0000119 Pa×s 291.61 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000119 Pa×s 292.30 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000119 Pa×s 292.46 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000119 Pa×s 292.77 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000121 Pa×s 296.89 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000121 Pa×s 297.01 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000132 Pa×s 323.94 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000132 Pa×s 323.96 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000143 Pa×s 350.47 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000143 Pa×s 350.59 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000154 Pa×s 378.01 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000154 Pa×s 378.19 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000166 Pa×s 405.76 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000166 Pa×s 405.86 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000177 Pa×s 433.66 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000177 Pa×s 433.81 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000188 Pa×s 461.72 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000188 Pa×s 461.92 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000199 Pa×s 490.09 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000199 Pa×s 490.20 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000210 Pa×s 518.68 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000210 Pa×s 518.75 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000219 Pa×s 542.48 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000219 Pa×s 542.61 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000227 Pa×s 565.19 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000228 Pa×s 565.29 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000238 Pa×s 593.95 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000238 Pa×s 594.02 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000248 Pa×s 623.07 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000248 Pa×s 623.19 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000258 Pa×s 652.30 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000258 Pa×s 652.32 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000268 Pa×s 681.36 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
η 0.0000268 Pa×s 682.03 Reference Viscosities of Gaseous Methane and Hydrogen Sulfide at Low Density in the Temperature Range from (292 to 682) K
ΔsubH [22.50; 25.40] kJ/mol [135.00; 175.50] Show Hide
ΔsubH 22.50 kJ/mol 135.00 NIST
ΔsubH 25.40 kJ/mol 175.50 NIST
ΔvapH [18.60; 21.90] kJ/mol [200.00; 295.50] Show Hide
ΔvapH 21.90 kJ/mol 200.00 NIST
ΔvapH 19.50 kJ/mol 206.50 NIST
ΔvapH 18.60 kJ/mol 295.50 NIST
Pvap [167.30; 8932.10] kPa [222.83; 373.15] Show Hide
Pvap 167.30 kPa 222.83 Phase Equilibria of H2S-Hydrocarbons (Propane, n-Butane, and n-Pentane) Binary Systems at Low Temperatures
Pvap 167.40 kPa 223.19 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 209.10 kPa 228.20 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 257.40 kPa 233.11 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 313.90 kPa 238.04 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 384.00 kPa 243.02 Phase Equilibria of H2S-Hydrocarbons (Propane, n-Butane, and n-Pentane) Binary Systems at Low Temperatures
Pvap 380.10 kPa 243.04 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 380.20 kPa 243.18 Phase Equilibria of H2S-Hydrocarbons (Propane, n-Butane, and n-Pentane) Binary Systems at Low Temperatures
Pvap 379.40 kPa 243.20 Phase Equilibria of H2S-Hydrocarbons (Propane, n-Butane, and n-Pentane) Binary Systems at Low Temperatures
Pvap 456.70 kPa 248.01 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 544.20 kPa 252.97 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 644.50 kPa 258.01 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 757.70 kPa 263.00 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 885.70 kPa 268.02 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 1033.00 kPa 273.08 Measurement of VLE (TPx or TPxy data) for hydrogen sulfide + (dimethylsulfide or ethylmethylsulfide or carbon disulfide) and methane solubilities in (dimethylsulfide or ethylmethylsulfide or methylmercaptan or ethylmercaptan)
Pvap 1030.20 kPa 273.12 Phase Equilibria of H2S-Hydrocarbons (Propane, n-Butane, and n-Pentane) Binary Systems at Low Temperatures
Pvap 1029.30 kPa 273.13 Phase Equilibria of H2S-Hydrocarbons (Propane, n-Butane, and n-Pentane) Binary Systems at Low Temperatures
Pvap 1032.30 kPa 273.17 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 1194.10 kPa 278.24 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 1371.10 kPa 283.26 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 1566.60 kPa 288.31 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 1767.90 kPa 293.10 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 1779.50 kPa 293.30 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 1793.70 kPa 293.43 Phase Equilibria of H2S-Hydrocarbons (Propane, n-Butane, and n-Pentane) Binary Systems at Low Temperatures
Pvap 2024.00 kPa 298.40 Measurement of VLE (TPx or TPxy data) for hydrogen sulfide + (dimethylsulfide or ethylmethylsulfide or carbon disulfide) and methane solubilities in (dimethylsulfide or ethylmethylsulfide or methylmercaptan or ethylmercaptan)
Pvap 2022.20 kPa 298.41 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 2259.60 kPa 303.08 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 2847.20 kPa 313.11 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 3540.40 kPa 323.18 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 3564.00 kPa 323.50 Measurement of VLE (TPx or TPxy data) for hydrogen sulfide + (dimethylsulfide or ethylmethylsulfide or carbon disulfide) and methane solubilities in (dimethylsulfide or ethylmethylsulfide or methylmercaptan or ethylmercaptan)
Pvap 4339.50 kPa 333.17 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 5261.20 kPa 343.16 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 5812.00 kPa 348.45 Measurement of VLE (TPx or TPxy data) for hydrogen sulfide + (dimethylsulfide or ethylmethylsulfide or carbon disulfide) and methane solubilities in (dimethylsulfide or ethylmethylsulfide or methylmercaptan or ethylmercaptan)
Pvap 6319.20 kPa 353.17 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 7533.00 kPa 363.16 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
Pvap 8932.10 kPa 373.15 Vapour liquid equilibrium data for the hydrogen sulphide + n-heptane system at temperatures from 293.25 to 373.22K and pressures up to about 6.9MPa
ρl 906.00 kg/m3 222.00 KDB

Correlations

Property Value Unit Temperature (K) Source
Pvap [22.75; 8960.69] kPa [187.68; 373.53] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Pvp) = A + B/(T + C)
Coefficient A1.43785e+01
Coefficient B-1.84720e+03
Coefficient C-2.35400e+01
Temperature range, min.187.68
Temperature range, max.373.53
Pvap 22.75 kPa 187.68 Calculated Property
Pvap 80.02 kPa 208.33 Calculated Property
Pvap 218.56 kPa 228.98 Calculated Property
Pvap 496.84 kPa 249.63 Calculated Property
Pvap 984.42 kPa 270.28 Calculated Property
Pvap 1754.98 kPa 290.93 Calculated Property
Pvap 2879.79 kPa 311.58 Calculated Property
Pvap 4422.55 kPa 332.23 Calculated Property
Pvap 6436.08 kPa 352.88 Calculated Property
Pvap 8960.69 kPa 373.53 Calculated Property

Similar Compounds

Mercapto-d. Mercapto radical. Carbon monosulfide. Boron sulfide. Sulfur trifluoride. Mercaptomethyl radical. Sulfur pentafluoride. Methanethiol, trifluoro-. trithiocarbonic acid. Thiophosgene. Methanethiol. Chromium oxide. Difluorosilane thiol. Methyl hydrogen disulfide. Methanedithiol.

Find more compounds similar to Hydrogen sulfide.

Mixtures

Find more mixtures with Hydrogen sulfide.

Sources

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Outlier This icon means that the value is more than 2 standard deviations away from the property mean.