Chemical Properties of Methyl propionate (CAS 554-12-1)

InChI

InChI=1S/C4H8O2/c1-3-4(5)6-2/h3H2,1-2H3

InChI Key

RJUFJBKOKNCXHH-UHFFFAOYSA-N

Formula

C4H8O2

SMILES

CCC(=O)OC

Molecular Weight¹

88.11

CAS

554-12-1

Other Names

• C2H5COOCH3
• Methyl ester of propanoic acid
• Methyl propylate
• Methylester kyseliny propionove
• NSC 9375
• Propionate de methyle
• UN 1248
• methyl propanoate
• propanoic acid, methyl ester
• propionic acid, methyl ester

• ω : Acentric Factor.
• PAff : Proton affinity (kJ/mol).
• T_ig : Autoignition Temperature (K).
• BasG : Gas basicity (kJ/mol).
• Δ_cH°_liquid : Standard liquid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• μ : Dipole Moment (debye).
• η : Dynamic viscosity (Pa×s).
• ε_r : Dielectric Constant (Relative permittivity).
• T_flash,cc : Flash Point (Closed Cup Method) (K).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• NFPA Fire : NFPA Fire Rating.
• NFPA Health : NFPA Health Rating.
• NFPA Safety : NFPA Safety Rating.
• P_c : Critical Pressure (kPa).
• P_triple : Triple Point Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• n₀ : Refractive Index.
• ρ_c : Critical density (kg/m³).
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I_p : Polar retention indices.
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• λ_gas : Gas thermal conductivity (W/m×K).
• λ_liquid : Liquid thermal conductivity (W/m×K).
• T_fus : Normal melting (fusion) point (K).
• T_triple : Triple Point Temperature (K).
• U_Qi : UNIQUAC Qi Parameter.
• U_Ri : UNIQUAC Ri Parameter.
• V_c : Critical Volume (m³/kmol).
• Z_c : Critical Compressibility.
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	[0.3490; 0.3520]
ω	0.3520		PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
ω	0.3490		ChemSep v8.3 pure component data Compiled value
PAff	830.20	kJ/mol	NIST
Tig	742.15	K	NCMS SOLV-DB
BasG	799.20	kJ/mol	NIST
ΔcH°liquid	-2246.00	kJ/mol	NIST
μ	1.70	debye	ChemSep v8.3 pure component data Compiled value
εr	5.50		NCMS SOLV-DB
Tflash,cc	271.15	K	NCMS SOLV-DB
ΔfG°	-311.00	kJ/mol	ChemSep v8.3 pure component data Compiled value
ΔfH°gas	-427.50	kJ/mol	ChemSep v8.3 pure component data Compiled value
ΔfusH°	10.48	kJ/mol	Joback Calculated Property
ΔvapH°	[32.30; 35.95]	kJ/mol
ΔvapH°	35.95	kJ/mol	NIST
ΔvapH°	34.50 ± 4.20	kJ/mol	NIST
ΔvapH°	35.82 ± 0.09	kJ/mol	NIST
ΔvapH°	32.30 ± 0.02	kJ/mol	NIST
IE	[9.90; 10.30]	eV
IE	10.15 ± 0.03	eV	NIST
IE	10.15	eV	NIST
IE	9.90 ± 0.20	eV	NIST
IE	10.15	eV	NIST
IE	10.15 ± 0.03	eV	NIST
IE	10.30	eV	NIST
log10WS	[-0.14; -0.14]
log10WS	-0.14		Aq. Solubility Prediction
log10WS	-0.14		Estimated Solubility
logPoct/wat	0.671		NCMS SOLV-DB
McVol	74.660	ml/mol	McGowan Calculated Property
NFPA Fire	3		NCMS SOLV-DB
NFPA Health	1		NCMS SOLV-DB
NFPA Safety	0		NCMS SOLV-DB
Pc	[4000.00; 4041.00]	kPa
Pc	4000.00	kPa	IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Pc	4002.34	kPa	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Pc	4000.00	kPa	ChemSep v8.3 pure component data Compiled value
Pc	4004.00 ± 101.32	kPa	NIST
Pc	4005.00 ± 40.00	kPa	NIST
Pc	4041.00 ± 101.32	kPa	NIST
Pc	4041.00 ± 101.32	kPa	NIST
Ptriple	6.34e-04	kPa	ChemSep v8.3 pure component data Compiled value
ρc	[300.44; 312.33]	kg/m3
ρc	311.89 ± 9.69	kg/m3	NIST
ρc	312.33 ± 4.41	kg/m3	NIST
ρc	300.44 ± 9.69	kg/m3	NIST
ρc	300.44 ± 9.69	kg/m3	NIST
Inp	[600.00; 642.60]
Inp	615.20		NIST
Inp	Outlier 600.00		NIST
Inp	628.20		NIST
Inp	625.70		NIST
Inp	624.00		NIST
Inp	629.00		NIST
Inp	610.00		NIST
Inp	627.00		NIST
Inp	622.00		NIST
Inp	607.00		NIST
Inp	615.00		NIST
Inp	627.00		NIST
Inp	629.00		NIST
Inp	618.00		NIST
Inp	618.00		NIST
Inp	617.00		NIST
Inp	612.00		NIST
Inp	607.00		NIST
Inp	Outlier 600.00		NIST
Inp	610.00		NIST
Inp	617.00		NIST
Inp	627.00		NIST
Inp	627.00		NIST
Inp	614.00		NIST
Inp	611.60		NIST
Inp	621.00		NIST
Inp	615.00		NIST
Inp	613.00		NIST
Inp	621.00		NIST
Inp	611.00		NIST
Inp	626.00		NIST
Inp	618.00		NIST
Inp	Outlier 642.60		NIST
Inp	611.00		NIST
Inp	618.00		NIST
Inp	621.00		NIST
Inp	611.00		NIST
Inp	630.00		NIST
Inp	617.00		NIST
Inp	622.00		NIST
Inp	617.00		NIST
Inp	611.00		NIST
Inp	604.00		NIST
Inp	617.00		NIST
Inp	615.00		NIST
Inp	621.00		NIST
Inp	616.00		NIST
Inp	616.00		NIST
Inp	Outlier 639.00		NIST
Inp	Outlier 639.00		NIST
Inp	621.00		NIST
Inp	617.00		NIST
Ip	[872.00; 937.00]
Ip	Outlier 937.00		NIST
Ip	909.00		NIST
Ip	905.00		NIST
Ip	916.00		NIST
Ip	906.00		NIST
Ip	908.00		NIST
Ip	899.00		NIST
Ip	908.00		NIST
Ip	890.00		NIST
Ip	896.00		NIST
Ip	885.00		NIST
Ip	911.00		NIST
Ip	901.00		NIST
Ip	906.00		NIST
Ip	Outlier 872.00		NIST
Ip	Outlier 872.00		NIST
Ip	Outlier 872.00		NIST
Ip	896.00		NIST
Ip	904.00		NIST
Ip	904.00		NIST
Ip	905.00		NIST
Ip	905.00		NIST
Ip	911.00		NIST
Ip	896.00		NIST
Ip	900.00		NIST
Ip	885.00		NIST
Ip	905.00		NIST
Ip	910.00		NIST
Ip	Outlier 937.00		NIST
Ip	908.00		NIST
Ip	885.00		NIST
Ip	906.00		NIST
Ip	904.00		NIST
Tboil	[351.15; 353.70]	K
Tboil	352.65	K	Multiphase equilibria for mixtures containing water, acetic acid, propionic acid, methyl acetate and methyl propionate
Tboil	352.62	K	Experimental determination of vapor liquid equilibrium for methanol + methyl propionate + 1-butyl-3-methylimidazo-lium bis(trifluoromethylsulfonyl)imide at atmospheric pressure
Tboil	352.47	K	Isobaric Vapor-Liquid Phase Equilibrium Measurements for Allyl Alcohol with Chloroform, Ethyl Acetate, and Methyl Propionate at 101.3 kPa
Tboil	351.65	K	Isobaric Vapor-Liquid Equilibria and Excess Properties for the Binary Systems of Methyl Esters + Heptane
Tboil	352.60	K	ChemSep v8.3 pure component data Compiled value
Tboil	352.85	K	NCMS SOLV-DB
Tboil	351.65 ± 0.30	K	NIST
Tboil	353.10	K	NIST
Tboil	352.90	K	NIST
Tboil	352.85 ± 0.20	K	NIST
Tboil	352.53 ± 0.50	K	NIST
Tboil	352.91 ± 0.50	K	NIST
Tboil	352.15 ± 2.00	K	NIST
Tboil	352.65 ± 1.00	K	NIST
Tboil	352.70 ± 0.60	K	NIST
Tboil	353.65 ± 2.00	K	NIST
Tboil	353.15 ± 1.00	K	NIST
Tboil	Outlier 351.15 ± 10.00	K	NIST
Tboil	353.15 ± 1.00	K	NIST
Tboil	353.00 ± 2.00	K	NIST
Tboil	352.00 ± 2.00	K	NIST
Tboil	353.00 ± 0.50	K	NIST
Tboil	352.95 ± 1.00	K	NIST
Tboil	353.03 ± 0.50	K	NIST
Tboil	352.15 ± 1.00	K	NIST
Tboil	353.70 ± 0.30	K	NIST
Tboil	352.85 ± 0.50	K	NIST
Tboil	352.80 ± 0.50	K	NIST
Tboil	352.80 ± 0.50	K	NIST
Tboil	352.85 ± 0.50	K	NIST
Tboil	352.70 ± 1.00	K	NIST
Tc	[528.90; 535.90]	K
Tc	530.70	K	IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Tc	530.80	K	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tc	530.60	K	ChemSep v8.3 pure component data Compiled value
Tc	530.60	K	NIST
Tc	530.60 ± 1.00	K	NIST
Tc	530.50 ± 1.00	K	NIST
Tc	528.90 ± 2.00	K	NIST
Tc	534.20 ± 4.00	K	NIST
Tc	528.90 ± 2.00	K	NIST
Tc	Outlier 535.90 ± 4.00	K	NIST
Tfus	[185.15; 185.65]	K
Tfus	185.15	K	Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Tfus	185.65	K	ChemSep v8.3 pure component data Compiled value
Tfus	185.27	K	Aq. Solubility Prediction
Tfus	185.15	K	NCMS SOLV-DB
Tfus	185.65 ± 0.50	K	NIST
Ttriple	185.65	K	ChemSep v8.3 pure component data Compiled value
UQi	3.12		ChemSep v8.3 pure component data Compiled value
URi	3.48		ChemSep v8.3 pure component data Compiled value
Vc	[0.282; 0.282]	m3/kmol
Vc	0.282	m3/kmol	IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Vc	0.282	m3/kmol	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Vc	0.282	m3/kmol	ChemSep v8.3 pure component data Compiled value
Zc	[0.2560000; 0.2560000]
Zc	0.2560000		IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Zc	0.2560000		ChemSep v8.3 pure component data Compiled value

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[171.20; 175.90]	J/mol×K	[298.15; 301.45]
Cp,liquid	171.21	J/mol×K	298.15	NIST
Cp,liquid	172.74	J/mol×K	298.15	NIST
Cp,liquid	171.20	J/mol×K	298.15	NIST
Cp,liquid	174.20	J/mol×K	298.15	NIST
Cp,liquid	175.90	J/mol×K	298.38	NIST
Cp,liquid	174.60	J/mol×K	301.45	NIST
ΔvapH	32.24	kJ/mol	352.90	NIST
Pvap	[11.20; 101.30]	kPa	[298.15; 352.65]
Pvap	11.20	kPa	298.15	NCMS SOLV-DB
Pvap	101.30	kPa	352.47	Isobaric Vapor-Liquid Phase Equilibrium Measurements for Allyl Alcohol with Chloroform, Ethyl Acetate, and Methyl Propionate at 101.3 kPa
Pvap	101.30	kPa	352.62	Experimental determination of vapor liquid equilibrium for methanol + methyl propionate + 1-butyl-3-methylimidazo-lium bis(trifluoromethylsulfonyl)imide at atmospheric pressure
Pvap	101.30	kPa	352.65	Multiphase equilibria for mixtures containing water, acetic acid, propionic acid, methyl acetate and methyl propionate
n0	[1.36410; 1.37700]		[298.15; 318.15]
n0	1.37421		298.15	Excess molar volumes and excess molar enthalpies for binary mixtures of 1,2-dichloropropane with methyl ethanoate, methyl propanoate, and methyl butanoate at T = 298.15K
n0	1.37400		298.15	Thermodynamic study of (alkyl esters + alpha,omega-alkyl dihalides) IV: Hex and Vex for 25 binary mixtures {xC(u-1)H(2u-1)CO2CH3 + (1-x)alpha,omega-BrCH2(CH2)(v-2)CH2Br}, where u = 1 to 5, alpha = 1 and v = omega = 2 to 6
n0	1.37430		298.15	Improvements in the Experimentation and the Representation of Thermodynamic Properties (iso-p VLE and yE) of Alkyl Propanoate + Alkane Binaries
n0	1.37700		298.15	NCMS SOLV-DB
n0	1.36410		318.15	Thermodynamic properties of (an ester + and alkane). XVII. Experimental He and Ve values for (an alkyl propanoate + an alkane) at 318.15K
n0	1.36410		318.15	Excess Properties and Isobaric Vapor-Liquid Equilibria for Binary Mixtures of Methyl Esters + tert-Butanol
ρl	909.30	kg/m3	298.15	Densities and interfacial tensions for fatty acid methyl esters (from methyl formate to methyl heptanoate) + water demixed mixtures at atmospheric pressure conditions

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[70.20; 252.90]	J/mol×K	[185.65; 1200.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is Cp,gas in J/mol×K, T in K
Coefficient A			1.13650e+01
Coefficient B			-2.58450e+02
Coefficient C			5.40724e+00
Coefficient D			3.35080e-04
Coefficient E			-7.42810e-08
Temperature range, min.			185.65
Temperature range, max.			1200.00
Cp,gas	70.20	J/mol×K	185.65	Calculated Property
Cp,gas	114.33	J/mol×K	298.36	Calculated Property
Cp,gas	146.15	J/mol×K	411.06	Calculated Property
Cp,gas	170.37	J/mol×K	523.77	Calculated Property
Cp,gas	189.82	J/mol×K	636.47	Calculated Property
Cp,gas	206.09	J/mol×K	749.18	Calculated Property
Cp,gas	220.09	J/mol×K	861.88	Calculated Property
Cp,gas	232.34	J/mol×K	974.59	Calculated Property
Cp,gas	243.21	J/mol×K	1087.29	Calculated Property
Cp,gas	252.90	J/mol×K	1200.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[172.16; 230.38]	J/mol×K	[253.71; 423.71]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is Cp,liquid in J/mol×K, T in K
Coefficient A			1.40380e+02
Coefficient B			1.17370e+03
Coefficient C			-6.09720e+00
Coefficient D			2.08630e-02
Coefficient E			-5.64200e-06
Temperature range, min.			253.71
Temperature range, max.			423.71
Cp,liquid	172.16	J/mol×K	253.71	Calculated Property
Cp,liquid	172.72	J/mol×K	272.60	Calculated Property
Cp,liquid	174.55	J/mol×K	291.49	Calculated Property
Cp,liquid	177.58	J/mol×K	310.38	Calculated Property
Cp,liquid	181.86	J/mol×K	329.27	Calculated Property
Cp,liquid	187.55	J/mol×K	348.15	Calculated Property
Cp,liquid	194.87	J/mol×K	367.04	Calculated Property
Cp,liquid	204.16	J/mol×K	385.93	Calculated Property
Cp,liquid	215.82	J/mol×K	404.82	Calculated Property
Cp,liquid	230.38	J/mol×K	423.71	Calculated Property

Property	Value	Unit	Temperature (K)	Source
η	[0.0008007; 0.0001502]	Pa×s	[250.00; 430.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = exp(A + B/T + C·ln(T) + D·T^E) Y is η in Pa×s, T in K
Coefficient A			-8.28680e+00
Coefficient B			8.07930e+02
Coefficient C			-3.64440e-01
Coefficient D			-1.00380e-06
Coefficient E			2.00000e+00
Temperature range, min.			250.00
Temperature range, max.			430.00
η	0.0008007	Pa×s	250.00	Calculated Property
η	0.0006064	Pa×s	270.00	Calculated Property
η	0.0004753	Pa×s	290.00	Calculated Property
η	0.0003829	Pa×s	310.00	Calculated Property
η	0.0003155	Pa×s	330.00	Calculated Property
η	0.0002649	Pa×s	350.00	Calculated Property
η	0.0002258	Pa×s	370.00	Calculated Property
η	0.0001951	Pa×s	390.00	Calculated Property
η	0.0001704	Pa×s	410.00	Calculated Property
η	0.0001502	Pa×s	430.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
ΔvapH	[42.76; 0.80]	kJ/mol	[185.65; 530.55]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A·(1 − Tr)^(B + C·Tr + D·Tr² + E·Tr³), Tr = T/Tc Y is ΔvapH in kJ/mol, T in K
Coefficient A			7.63030e+01
Coefficient B			2.91960e+00
Coefficient C			-6.55930e+00
Coefficient D			6.82350e+00
Coefficient E			-2.69260e+00
Critical temperature, Tc (K)			5.30600e+02
Temperature range, min.			185.65
Temperature range, max.			530.55
ΔvapH	42.76	kJ/mol	185.65	Calculated Property
ΔvapH	40.30	kJ/mol	223.97	Calculated Property
ΔvapH	38.08	kJ/mol	262.29	Calculated Property
ΔvapH	35.84	kJ/mol	300.62	Calculated Property
ΔvapH	33.37	kJ/mol	338.94	Calculated Property
ΔvapH	30.54	kJ/mol	377.26	Calculated Property
ΔvapH	27.21	kJ/mol	415.58	Calculated Property
ΔvapH	23.17	kJ/mol	453.91	Calculated Property
ΔvapH	17.65	kJ/mol	492.23	Calculated Property
ΔvapH	0.80	kJ/mol	530.55	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 202.65]	kPa	[259.99; 375.95]	The Yaws Handbook of Vapor Pressure
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.45878e+01
Coefficient B			-3.06195e+03
Coefficient C			-4.58670e+01
Temperature range, min.			259.99
Temperature range, max.			375.95
Pvap	1.33	kPa	259.99	Calculated Property
Pvap	3.00	kPa	272.87	Calculated Property
Pvap	6.20	kPa	285.76	Calculated Property
Pvap	11.88	kPa	298.64	Calculated Property
Pvap	21.37	kPa	311.53	Calculated Property
Pvap	36.42	kPa	324.41	Calculated Property
Pvap	59.21	kPa	337.30	Calculated Property
Pvap	92.39	kPa	350.18	Calculated Property
Pvap	139.03	kPa	363.07	Calculated Property
Pvap	202.65	kPa	375.95	Calculated Property
Pvap	[6.02e-04; 3952.03]	kPa	[185.65; 530.60]	ChemSep v8.3 pure component data Compiled value
Equation			Y = exp(A + B/T + C·ln(T) + D·T^E) Y is Pvap in kPa, T in K
Coefficient A			8.50659e+01
Coefficient B			-7.07199e+03
Coefficient C			-1.04626e+01
Coefficient D			7.76743e-06
Coefficient E			2.00000e+00
Temperature range, min.			185.65
Temperature range, max.			530.60
Pvap	6.02e-04	kPa	185.65	Calculated Property
Pvap	0.06	kPa	223.98	Calculated Property
Pvap	1.44	kPa	262.31	Calculated Property
Pvap	12.75	kPa	300.63	Calculated Property
Pvap	62.85	kPa	338.96	Calculated Property
Pvap	211.16	kPa	377.29	Calculated Property
Pvap	547.28	kPa	415.62	Calculated Property
Pvap	1185.12	kPa	453.94	Calculated Property
Pvap	2262.42	kPa	492.27	Calculated Property
Pvap	3952.03	kPa	530.60	Calculated Property
Pvap	[6.36e-04; 3916.85]	kPa	[185.65; 530.60]	KDB Vapor Pressure Data
Equation			ln(Y) = A + B/T + C·ln(T) + D·T² + E/T² Y is Pvap in kPa, T in K
Coefficient A			8.37412e+01
Coefficient B			-7.00860e+03
Coefficient C			-1.02625e+01
Coefficient D			7.55664e-06
Coefficient E			0.00000e+00
Temperature range, min.			185.65
Temperature range, max.			530.60
Pvap	6.36e-04	kPa	185.65	Calculated Property
Pvap	0.07	kPa	223.98	Calculated Property
Pvap	1.47	kPa	262.31	Calculated Property
Pvap	12.87	kPa	300.63	Calculated Property
Pvap	63.10	kPa	338.96	Calculated Property
Pvap	211.31	kPa	377.29	Calculated Property
Pvap	546.28	kPa	415.62	Calculated Property
Pvap	1180.29	kPa	453.94	Calculated Property
Pvap	2248.03	kPa	492.27	Calculated Property
Pvap	3916.85	kPa	530.60	Calculated Property
Pvap	[9.21; 99.27]	kPa	[293.74; 351.90]	NIST
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.39073e+01
Coefficient B			-2.66176e+03
Coefficient C			-6.59790e+01
Reference			Polák and Mertl, 1965
Comment			Coefficents calculated by NIST from author's data.
Temperature range, min.			293.74
Temperature range, max.			351.90
Pvap	9.21	kPa	293.74	Calculated Property
Pvap	12.72	kPa	300.20	Calculated Property
Pvap	17.26	kPa	306.66	Calculated Property
Pvap	23.04	kPa	313.13	Calculated Property
Pvap	30.32	kPa	319.59	Calculated Property
Pvap	39.35	kPa	326.05	Calculated Property
Pvap	50.44	kPa	332.51	Calculated Property
Pvap	63.89	kPa	338.98	Calculated Property
Pvap	80.05	kPa	345.44	Calculated Property
Pvap	99.27	kPa	351.90	Calculated Property

Property	Value	Unit	Temperature (K)	Source
ρl	[1024.94; 321.17]	kg/m3	[185.65; 530.55]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A / B^(1 + (1 − T/C)^D) Y is ρl in kg/m3, T in K
Coefficient A			6.42683e+01
Coefficient B			2.32840e-01
Coefficient C			5.30600e+02
Coefficient D			2.44220e-01
Temperature range, min.			185.65
Temperature range, max.			530.55
ρl	1024.94	kg/m3	185.65	Calculated Property
ρl	987.52	kg/m3	223.97	Calculated Property
ρl	947.95	kg/m3	262.29	Calculated Property
ρl	905.72	kg/m3	300.62	Calculated Property
ρl	860.05	kg/m3	338.94	Calculated Property
ρl	809.75	kg/m3	377.26	Calculated Property
ρl	752.75	kg/m3	415.58	Calculated Property
ρl	684.85	kg/m3	453.91	Calculated Property
ρl	594.55	kg/m3	492.23	Calculated Property
ρl	321.17	kg/m3	530.55	Calculated Property

Property	Value	Unit	Temperature (K)	Source
γ	[0.04; 0.02]	N/m	[185.15; 353.15]	Jasper (1972), surface tension of pure liquid compounds Compiled value
Equation			Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is γ in N/m, T in K
Coefficient A			6.19423e-02
Coefficient B			-1.25800e-04
Coefficient C			0.00000e+00
Coefficient D			0.00000e+00
Coefficient E			0.00000e+00
Temperature range, min.			185.15
Temperature range, max.			353.15
γ	0.04	N/m	185.15	Calculated Property
γ	0.04	N/m	203.82	Calculated Property
γ	0.03	N/m	222.48	Calculated Property
γ	0.03	N/m	241.15	Calculated Property
γ	0.03	N/m	259.82	Calculated Property
γ	0.03	N/m	278.48	Calculated Property
γ	0.02	N/m	297.15	Calculated Property
γ	0.02	N/m	315.82	Calculated Property
γ	0.02	N/m	334.48	Calculated Property
γ	0.02	N/m	353.15	Calculated Property
γ	[0.04; 0.00]	N/m	[185.65; 512.44]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is γ in N/m, T in K
Coefficient A			-1.52500e-02
Coefficient B			3.21310e+01
Coefficient C			-2.95560e+00
Coefficient D			2.63390e-04
Coefficient E			-5.16710e-06
Temperature range, min.			185.65
Temperature range, max.			512.44
γ	0.04	N/m	185.65	Calculated Property
γ	0.03	N/m	221.96	Calculated Property
γ	0.03	N/m	258.27	Calculated Property
γ	0.02	N/m	294.58	Calculated Property
γ	0.02	N/m	330.89	Calculated Property
γ	0.02	N/m	367.20	Calculated Property
γ	0.01	N/m	403.51	Calculated Property
γ	0.01	N/m	439.82	Calculated Property
γ	0.00	N/m	476.13	Calculated Property
γ	0.00	N/m	512.44	Calculated Property

Property	Value	Unit	Temperature (K)	Source
λgas	[0.00; 0.11]	W/m×K	[185.65; 1000.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A·T^B / (1 + C/T + D/T²) Y is λgas in W/m×K, T in K
Coefficient A			-1.97620e+02
Coefficient B			-1.34130e-01
Coefficient C			1.01740e+05
Coefficient D			-8.21560e+08
Temperature range, min.			185.65
Temperature range, max.			1000.00
λgas	0.00	W/m×K	185.65	Calculated Property
λgas	0.01	W/m×K	276.13	Calculated Property
λgas	0.02	W/m×K	366.62	Calculated Property
λgas	0.02	W/m×K	457.10	Calculated Property
λgas	0.03	W/m×K	547.58	Calculated Property
λgas	0.04	W/m×K	638.07	Calculated Property
λgas	0.06	W/m×K	728.55	Calculated Property
λgas	0.07	W/m×K	819.03	Calculated Property
λgas	0.09	W/m×K	909.52	Calculated Property
λgas	0.11	W/m×K	1000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
λliquid	[0.17; 0.10]	W/m×K	[185.65; 475.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is λliquid in W/m×K, T in K
Coefficient A			3.45990e-02
Coefficient B			2.75770e+01
Coefficient C			-2.12070e+00
Coefficient D			9.88910e-04
Coefficient E			-5.17030e-06
Temperature range, min.			185.65
Temperature range, max.			475.00
λliquid	0.17	W/m×K	185.65	Calculated Property
λliquid	0.17	W/m×K	217.80	Calculated Property
λliquid	0.16	W/m×K	249.95	Calculated Property
λliquid	0.15	W/m×K	282.10	Calculated Property
λliquid	0.14	W/m×K	314.25	Calculated Property
λliquid	0.13	W/m×K	346.40	Calculated Property
λliquid	0.12	W/m×K	378.55	Calculated Property
λliquid	0.12	W/m×K	410.70	Calculated Property
λliquid	0.11	W/m×K	442.85	Calculated Property
λliquid	0.10	W/m×K	475.00	Calculated Property

Similar Compounds

Find more compounds similar to Methyl propionate.

Mixtures

• Carbon dioxide + Methyl propionate
• Methyl propionate + Ethylene
• Acetic acid + Methyl propionate
• Methyl propionate + Propanoic acid
• Methyl propionate + Acetic acid, methyl ester
• Methyl propionate + Water
• Methyl propionate + Acetic acid, methyl ester + Water
• Methyl propionate + Methyl Alcohol
• Carbon monoxide + Methyl propionate
• Propane, 1,2-dichloro- + Methyl propionate
• Methyl propionate + Heptane
• Methyl propionate + Nonane
• Undecane + Methyl propionate
• Tridecane + Methyl propionate
• Pentadecane + Methyl propionate
• Heptadecane + Methyl propionate
• Ethane, 1,2-dibromo- + Methyl propionate
• Propane, 1,3-dibromo- + Methyl propionate
• Methyl propionate + Butane, 1,4-dibromo-
• Pentane, 1,5-dibromo- + Methyl propionate

Find more mixtures with Methyl propionate.

Sources

• KDB Vapor Pressure Data
• Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) ChEDL chemicals 1.5.2, from Bradley, J.-C.; Williams, A.; Lang, A. Jean-Claude Bradley Open Melting Point Dataset. Figshare, 2014 (CC0).
• IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 ChEDL chemicals 1.5.2, from Kudchadker, A. P.; Ambrose, D.; Tsonopoulos, C. Vapor-Liquid Critical Properties of Elements and Compounds. 7. Oxygen Compounds Other Than Alkanols and Cycloalkanols. J. Chem. Eng. Data 2001, 46, 457-479.
• Jasper (1972), surface tension of pure liquid compounds ChEDL chemicals 1.5.2, from Jasper, J. J. The Surface Tension of Pure Liquid Compounds. J. Phys. Chem. Ref. Data 1972, 1, 841-1010 (as transcribed in Lange's Handbook).
• PSRK revision IV (2005), critical constants and acentric factors of 1000 components ChEDL chemicals 1.5.2, from Horstmann, S.; Jabłoniec, A.; Krafczyk, J.; Fischer, K.; Gmehling, J. PSRK Group Contribution Equation of State: Comprehensive Revision and Extension IV, Including Critical Constants and α-Function Parameters for 1000 Components. Fluid Phase Equilib. 2005, 227, 157-164.
• ChemSep v8.3 pure component data Converted from ChemSep v8.3 pure component data, H. Kooijman and R. Taylor (2021, 2022), Artistic License 2.0; see how the values differ.
• Multiphase equilibria for mixtures containing water, acetic acid, propionic acid, methyl acetate and methyl propionate
• Excess molar volumes and excess molar enthalpies for binary mixtures of 1,2-dichloropropane with methyl ethanoate, methyl propanoate, and methyl butanoate at T = 298.15K
• Experimental determination and calculation of the critical curves for the binary systems of CO2 containing ketone, alkane, ester and alcohol, respectively
• Solubility of ethylene in methyl propionate
• Activity coefficients at infinite dilution of organic solvents and water in 1-butyl-3-methylimidazolium dicyanamide. A literature review of hexane/hex-1-ene separation
• Bubble point pressures of binary system of methanol and methyl propionate
• High selective water/butan-1-ol separation on investigation of limiting activity coefficients with [P8,8,8,8][[NTf2] ionic liquid
• Separation of binary mixtures based on limiting activity coefficients data using specific ammonium-based ionic liquid and modelling of thermodynamic functions
• Thermodynamics and activity coefficients at infinite dilution for organic solutes in the ionic liquid 1-butyl-1-methylpyrrolidinium dicyanamide
• New ionic liquid [P4,4,4,4][NTf2] in bio-butanol extraction on investigation of limiting activity coefficients
• Ammonium ionic liquids in extraction of bio-butan-1-ol from water phase using activity coefficients at infinite dilution
• Thermodynamic properties of (an ester + and alkane). XVII. Experimental He and Ve values for (an alkyl propanoate + an alkane) at 318.15K
• Thermodynamic study of (alkyl esters + alpha,omega-alkyl dihalides) IV: Hex and Vex for 25 binary mixtures {xC(u-1)H(2u-1)CO2CH3 + (1-x)alpha,omega-BrCH2(CH2)(v-2)CH2Br}, where u = 1 to 5, alpha = 1 and v = omega = 2 to 6
• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid 4-(2-methoxyethyl)-4-methylmorpholinium bis(trifluoromethylsulfonyl)-amide
• Measurements of activity coefficients at infinite dilution for organic solutes and water in the ionic liquid 1-hexyl-3-methylimidazolium tetracyanoborate
• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid 1-(2-methoxyethyl)-1-methylpiperidinium bis(trifluoromethylsulfonyl)-amide
• Low pressure carbon dioxide solubility in pure electrolyte solvents for lithium-ion batteries as a function of temperature. Measurement and prediction
• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid 1-(2-methoxyethyl)-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)-amide
• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid 4-(2-methoxyethyl)-4-methylmorpholinium trifluorotris(perfluoroethyl)phosphate
• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid 1-(2-methoxyethyl)- 1-methylpiperidinium trifluorotris(perfluoroethyl)phosphate
• Isothermal (vapour + liquid) equilibria for the binary systems of (carbon monoxide + methyl propionate) and (carbon monoxide + ethyl propionate)
• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid 1-(2-methoxyethyl)- 1-methylpyrrolidinium trifluorotris(perfluoroethyl)phosphate
• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid 1-(2-hydroxyethyl)- 3-methylimidazolium trifluorotris(perfluoroethyl)phosphate
• Measurements of activity coefficients at infinite dilution for organic solutes and water in the ionic liquid 1-butyl-1-methylpyrrolidinium tricyanomethanide
• Thermodynamics and activity coefficients at infinite dilution for organic solutes and water in the ionic liquid 1-butyl-1-methylmorpholinium tricyanomethanide
• Thermodynamics and activity coefficients at infinite dilution for organic solutes, water and diols in the ionic liquid choline bis(trifluoromethylsulfonyl)imide
• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid 4-(3-hydroxypropyl)-4-methylmorpholinium bis(trifluoromethylsulfonyl)-amide
• Activity coefficients at infinite dilution for organic solutes and water in 1-ethyl-1-methylpyrrolidinium lactate
• Activity coefficients at infinite dilution, physicochemical and thermodynamic properties for organic solutes and water in the ionic liquid ethyl-dimethyl-(2-methoxyethyl)ammonium trifluorotris-(perfluoroethyl)phosphate
• A 1-alkylcyanopyridinium-based ionic liquid in the separation processes
• Thermodynamics and selectivity of separation based on activity coefficients at infinite dilution of various solutes in 1-allyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide ionic liquid
• Thermodynamics and limiting activity coefficients measurements for organic solutes and water in the ionic liquid 1-dodecyl-3-methylimidzolium bis(trifluoromethylsulfonyl) imide
• Separation of binary mixtures hexane/hex-1-ene, cyclohexane/cyclohexene and ethylbenzene/styrene based on limiting activity coefficients
• Separation of water/butan-1-ol based on activity coefficients at infinite dilution in 1,3-didecyl-2-methylimidazolium dicyanamide ionic liquid
• Separation of binary mixtures hexane/hex-1-ene, cyclohexane/cyclohexene and ethylbenzene/styrene based on gamma infinity data measurements
• Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid trihexyl-tetradecyl-phosphonium tricyanomethanide
• Densities and interfacial tensions for fatty acid methyl esters (from methyl formate to methyl heptanoate) + water demixed mixtures at atmospheric pressure conditions
• Thermodynamic study of molecular interaction-selectivity in separation processes based on limiting activity coefficients
• The use of ionic liquids for separation of binary hydrocarbons mixtures based on gamma infinity data measurements
• Improving the method of solution calorimetry for evaluation of the enthalpies of phase transitions and condensed state enthalpies of formation
• Experimental determination of vapor liquid equilibrium for methanol + methyl propionate + 1-butyl-3-methylimidazo-lium bis(trifluoromethylsulfonyl)imide at atmospheric pressure
• Examination of hydrogen-bonding interactions between dissolved solutes and alkylbenzene solvents based on Abraham model correlations derived from measured enthalpies of solvation
• Effect of halogen substitution on the enthalpies of solvation and hydrogen bonding of organic solutes in chlorobenzene and 1,2-dichlorobenzene derived using multi-parameter correlations
• Isobaric Vapor-Liquid Phase Equilibrium Measurements for Allyl Alcohol with Chloroform, Ethyl Acetate, and Methyl Propionate at 101.3 kPa
• Solubility and Thermodynamic Modeling of Dimethyl Terephthalate in Pure Solvents and the Evaluation of the Mixing Properties of the Solutions
• Isobaric Vapor-Liquid Equilibria and Excess Properties for the Binary Systems of Methyl Esters + Heptane
• Excess Properties and Isobaric Vapor-Liquid Equilibria for Binary Mixtures of Methyl Esters + tert-Butanol
• Thermodynamic Properties of Mixtures Containing Ionic Liquids. 8. Activity Coefficients at Infinite Dilution of Hydrocarbons, Alcohols, Esters, and Aldehydes in 1-Hexyl-3-methylimidazolium Bis(trifluoromethylsulfonyl) Imide Using Gas-Liquid Chromatography
• Thermodynamic Properties of Mixtures Containing Ionic Liquids. 9. Activity Coefficients at Infinite Dilution of Hydrocarbons, Alcohols, Esters, and Aldehydes in Trimethyl-butylammonium Bis(trifluoromethylsulfonyl) Imide Using Gas-Liquid Chromatography and Static Method
• Experimental Study of Thermodynamic Properties of Mixtures Containing Ionic Liquid 1-Ethyl-3-methylimidazolium Ethyl Sulfate Using Gas-Liquid Chromatography and Transpiration Method
• Improvements in the Experimentation and the Representation of Thermodynamic Properties (iso-p VLE and yE) of Alkyl Propanoate + Alkane Binaries
• Vapor-Liquid Equilibrium Data of (Carbon Dioxide + Methyl Propionate) and (Carbon Dioxide + Propyl Propionate) at Pressures from (1.00 to 12.00) MPa and Temperatures from (313.0 to 373.0) K
• Joback Method
• Aqueous Solubility Prediction Method
• Estimated Solubility Method
• McGowan Method
• NIST Webbook
• NCMS SOLV-DB
• The Yaws Handbook of Vapor Pressure

Note: Cheméo is only indexing the data, follow the source links to retrieve the latest data. The source is also providing more information like the publication year, authors and more. Take the time to validate and double check the source of the data.
Outlier This icon means that the value is more than 2 standard deviations away from the property mean.
Calculated This icon marks a calculated value or equation: a prediction, not a measurement.
Compiled This icon marks a compiled value or equation: taken from a data compilation such as ChemSep, not from an original measurement report.
These property values are available through the Cheméo API. A free account gives you an access key.