Chemical Properties of Ethanol, 2-[2-(2-methoxyethoxy)ethoxy]- (CAS 112-35-6)

InChI

InChI=1S/C7H16O4/c1-9-4-5-11-7-6-10-3-2-8/h8H,2-7H2,1H3

InChI Key

JLGLQAWTXXGVEM-UHFFFAOYSA-N

Formula

C7H16O4

SMILES

COCCOCCOCCO

Molecular Weight¹

164.20

CAS

112-35-6

Other Names

• 2-[2-(2-methoxyethoxy)ethoxy]ethanol
• 3,6,9-trioxa-1-decanol
• 3,6,9-trioxadecanol
• Dowanol TMAT
• NSC 97395
• Poly-Solv TM
• Triethylene glycol methyl ether
• methoxytriethylene glycol
• methoxytriglycol
• methyltrioxitol
• triethylene glycol monomethyl ether
• triglycol monomethyl ether

• ω : Acentric Factor.
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• η : Dynamic viscosity (Pa×s).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• n₀ : Refractive Index.
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I_p : Polar retention indices.
• c_sound,fluid : Speed of sound in fluid (m/s).
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_boilr : Boiling point at reduced pressure (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• V_c : Critical Volume (m³/kmol).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	0.7709		Relay (1.0) Calculated Property
ΔfH°gas	-729.48	kJ/mol	Relay (1.0) Calculated Property
ΔfusH°	21.54	kJ/mol	Joback Calculated Property
ΔvapH°	69.99	kJ/mol	Relay (1.0) Calculated Property
IE	9.87	eV	Relay (1.0) Calculated Property
log10WS	0.78		Relay (1.0) Calculated Property
logPoct/wat	-0.342		Crippen Calculated Property
McVol	132.970	ml/mol	McGowan Calculated Property
Pc	2925.00	kPa	Joback Calculated Property
Inp	[1150.00; 1225.60]
Inp	1225.60		NIST
Inp	1150.00		NIST
Inp	1219.00		NIST
Inp	1225.60		NIST
Inp	1219.00		NIST
Ip	[1963.00; 1963.00]
Ip	1963.00		NIST
Ip	1963.00		NIST
Tboil	[518.40; 522.20]	K
Tboil	522.20	K	NIST
Tboil	518.40 ± 0.60	K	NIST
Tboil	521.00 ± 3.00	K	NIST
Tc	710.93	K	Relay (1.0) Calculated Property
Tfus	229.15	K	Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Vc	0.507	m3/kmol	Relay (1.0) Calculated Property

Cheméo can also estimate Standard Gibbs free energy of formation for this compound, but it falls outside the models' validated range, so it is not shown here. Open the prediction tool to compute it on demand.

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[352.20; 367.60]	J/mol×K	[275.15; 339.15]
Cp,liquid	352.20	J/mol×K	275.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	352.60	J/mol×K	277.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	352.90	J/mol×K	279.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	353.20	J/mol×K	281.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	353.60	J/mol×K	283.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	353.90	J/mol×K	285.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	354.30	J/mol×K	287.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	354.70	J/mol×K	289.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	355.10	J/mol×K	291.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	355.50	J/mol×K	293.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	355.90	J/mol×K	295.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	356.30	J/mol×K	297.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	356.60	J/mol×K	298.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	356.80	J/mol×K	299.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	357.20	J/mol×K	301.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	357.70	J/mol×K	303.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	358.10	J/mol×K	305.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	358.60	J/mol×K	307.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	359.10	J/mol×K	309.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	359.60	J/mol×K	311.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	360.10	J/mol×K	313.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	360.60	J/mol×K	315.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	361.20	J/mol×K	317.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	361.70	J/mol×K	319.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	362.20	J/mol×K	321.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	362.80	J/mol×K	323.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	363.40	J/mol×K	325.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	364.00	J/mol×K	327.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	364.50	J/mol×K	329.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	365.10	J/mol×K	331.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	365.80	J/mol×K	333.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	366.40	J/mol×K	335.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	367.00	J/mol×K	337.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
Cp,liquid	367.60	J/mol×K	339.15	Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
n0	[1.43620; 1.43673]		[298.15; 298.15]
n0	1.43673		298.15	Excess molar volumes and excess molar enthalpies of the binary mixtures of 1,2-dichloropropane with di- and triethylene glycol mono-alkyl ethers at T=298.15K
n0	1.43620		298.15	Physical and excess properties of a room temperature ionic liquid (1-methyl-3-octylimidazolium tetrafluoroborate) with n-alkoxyethanols (C1Em, m = 1 to 3) at T = (298.15 to 318.15) K
ρl	[1030.01; 1047.29]	kg/m3	[293.15; 313.15]
ρl	1047.29	kg/m3	293.15	Volumetric properties of binary mixtures of alkoxyethanols with ethyl tert-butyl ether at various temperatures
ρl	1043.06	kg/m3	298.15	Speeds of Sound and Isentropic Compressibilities of n-Alkoxyethanols and Polyethers with Propylamine at 298.15K
ρl	1042.97	kg/m3	298.15	Volumetric properties of binary mixtures of alkoxyethanols with ethyl tert-butyl ether at various temperatures
ρl	1038.65	kg/m3	303.15	Volumetric properties of binary mixtures of alkoxyethanols with ethyl tert-butyl ether at various temperatures
ρl	1034.33	kg/m3	308.15	Volumetric properties of binary mixtures of alkoxyethanols with ethyl tert-butyl ether at various temperatures
ρl	1030.01	kg/m3	313.15	Volumetric properties of binary mixtures of alkoxyethanols with ethyl tert-butyl ether at various temperatures
csound,fluid	[1376.00; 1470.00]	m/s	[288.15; 318.15]
csound,fluid	1470.00	m/s	288.15	Volumetric and Acoustic Properties of Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate [bmim][BF4] with Alkoxyalkanols at Different Temperatures
csound,fluid	1452.00	m/s	293.15	Volumetric and Acoustic Properties of Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate [bmim][BF4] with Alkoxyalkanols at Different Temperatures
csound,fluid	1436.00	m/s	298.15	Volumetric and Acoustic Properties of Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate [bmim][BF4] with Alkoxyalkanols at Different Temperatures
csound,fluid	1421.00	m/s	303.15	Volumetric and Acoustic Properties of Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate [bmim][BF4] with Alkoxyalkanols at Different Temperatures
csound,fluid	1408.00	m/s	308.15	Volumetric and Acoustic Properties of Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate [bmim][BF4] with Alkoxyalkanols at Different Temperatures
csound,fluid	1393.00	m/s	313.15	Volumetric and Acoustic Properties of Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate [bmim][BF4] with Alkoxyalkanols at Different Temperatures
csound,fluid	1376.00	m/s	318.15	Volumetric and Acoustic Properties of Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate [bmim][BF4] with Alkoxyalkanols at Different Temperatures
γ	[0.04; 0.04]	N/m	[298.15; 318.15]
γ	0.04	N/m	298.15	Experimental Surface Tensions and Derived Surface Properties of Binary Mixtures of Water + Alkoxyethanols (C1Em, m = 1, 2, 3) and Water + Ethylene Glycol Dimethyl Ether (C1E1C1) at (298.15, 308.15, and 318.15) K
γ	0.04	N/m	308.15	Experimental Surface Tensions and Derived Surface Properties of Binary Mixtures of Water + Alkoxyethanols (C1Em, m = 1, 2, 3) and Water + Ethylene Glycol Dimethyl Ether (C1E1C1) at (298.15, 308.15, and 318.15) K
γ	0.04	N/m	318.15	Experimental Surface Tensions and Derived Surface Properties of Binary Mixtures of Water + Alkoxyethanols (C1Em, m = 1, 2, 3) and Water + Ethylene Glycol Dimethyl Ether (C1E1C1) at (298.15, 308.15, and 318.15) K

Pressure Dependent Properties

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[212.69; 454.64]	J/mol×K	[273.00; 1000.00]	Joback Predicted correlation
Equation			Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is Cp,gas in J/mol×K, T in K
Coefficient A			7.83160e+01
Coefficient B			5.13220e-01
Coefficient C			-5.44000e-05
Coefficient D			-8.25000e-08
Coefficient E			0.00000e+00
Temperature range, min.			273.00
Temperature range, max.			1000.00
Cp,gas	212.69	J/mol×K	273.00	Calculated Property
Cp,gas	249.42	J/mol×K	353.78	Calculated Property
Cp,gas	284.30	J/mol×K	434.56	Calculated Property
Cp,gas	317.06	J/mol×K	515.33	Calculated Property
Cp,gas	347.45	J/mol×K	596.11	Calculated Property
Cp,gas	375.20	J/mol×K	676.89	Calculated Property
Cp,gas	400.05	J/mol×K	757.67	Calculated Property
Cp,gas	421.75	J/mol×K	838.44	Calculated Property
Cp,gas	440.03	J/mol×K	919.22	Calculated Property
Cp,gas	454.64	J/mol×K	1000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
η	[0.1502887; 0.0001494]	Pa×s	[229.15; 475.91]	Joback Predicted correlation
Equation			Y = exp(A + B/T + C·ln(T) + D·T^E) Y is η in Pa×s, T in K
Coefficient A			-1.52289e+01
Coefficient B			3.05542e+03
Coefficient C			0.00000e+00
Coefficient D			0.00000e+00
Coefficient E			0.00000e+00
Comment			Liquid phase. Joback/Reid (1987), valid from Tf to 0.7·Tc.
Temperature range, min.			229.15
Temperature range, max.			475.91
η	0.1502887	Pa×s	229.15	Calculated Property
η	0.0361500	Pa×s	256.57	Calculated Property
η	0.0114493	Pa×s	283.99	Calculated Property
η	0.0044399	Pa×s	311.40	Calculated Property
η	0.0020070	Pa×s	338.82	Calculated Property
η	0.0010218	Pa×s	366.24	Calculated Property
η	0.0005715	Pa×s	393.66	Calculated Property
η	0.0003448	Pa×s	421.07	Calculated Property
η	0.0002212	Pa×s	448.49	Calculated Property
η	0.0001494	Pa×s	475.91	Calculated Property

Similar Compounds

Find more compounds similar to Ethanol, 2-[2-(2-methoxyethoxy)ethoxy]-.

Mixtures

• Propane, 2-ethoxy-2-methyl- + Ethanol, 2-[2-(2-methoxyethoxy)ethoxy]-
• Ethanol, 2-[2-(2-methoxyethoxy)ethoxy]- + Water
• Propane, 1,2-dichloro- + Ethanol, 2-[2-(2-methoxyethoxy)ethoxy]-
• Propylamine + Ethanol, 2-[2-(2-methoxyethoxy)ethoxy]-

Sources

• Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) ChEDL chemicals 1.5.2, from Bradley, J.-C.; Williams, A.; Lang, A. Jean-Claude Bradley Open Melting Point Dataset. Figshare, 2014 (CC0).
• Cheméo Relay (1.0)
• Crippen Method
• Crippen Method
• Speeds of Sound and Isentropic Compressibilities of n-Alkoxyethanols and Polyethers with Propylamine at 298.15K
• Excess molar volumes and excess molar enthalpies of the binary mixtures of 1,2-dichloropropane with di- and triethylene glycol mono-alkyl ethers at T=298.15K
• Volumetric properties of binary mixtures of alkoxyethanols with ethyl tert-butyl ether at various temperatures
• Physical and excess properties of a room temperature ionic liquid (1-methyl-3-octylimidazolium tetrafluoroborate) with n-alkoxyethanols (C1Em, m = 1 to 3) at T = (298.15 to 318.15) K
• Thermophysical properties of ionic liquid {1-butyl-3-methylimidazolium bromide [bmim][Br] in alkoxyalkanols + water} mixtures at different temperatures
• Partial molar volumes of organic solutes in water. XXX. Two poly(ethylene glycol) monoalkyl ethers, C4E2 and C1E3, at temperatures T = 298 K to 573 K and pressures up to 30 MPa
• Measurement and Prediction of Molar Heat Capacities of Liquid Polyoxyethylene Glycol Monoalkyl Ethers (CnEm)
• Experimental Surface Tensions and Derived Surface Properties of Binary Mixtures of Water + Alkoxyethanols (C1Em, m = 1, 2, 3) and Water + Ethylene Glycol Dimethyl Ether (C1E1C1) at (298.15, 308.15, and 318.15) K
• Volumetric and Acoustic Properties of Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate [bmim][BF4] with Alkoxyalkanols at Different Temperatures
• Joback Method
• McGowan Method
• NIST Webbook

Note: Cheméo is only indexing the data, follow the source links to retrieve the latest data. The source is also providing more information like the publication year, authors and more. Take the time to validate and double check the source of the data.
Calculated This icon marks a calculated value or equation: a prediction, not a measurement.
Compiled This icon marks a compiled value or equation: taken from a data compilation such as ChemSep, not from an original measurement report.
These property values are available through the Cheméo API. A free account gives you an access key.