Chemical Properties of Methyl methacrylate (CAS 80-62-6)

InChI

InChI=1S/C5H8O2/c1-4(2)5(6)7-3/h1H2,2-3H3

InChI Key

VVQNEPGJFQJSBK-UHFFFAOYSA-N

Formula

C5H8O2

SMILES

C=C(C)C(=O)OC

Molecular Weight¹

100.12

CAS

80-62-6

Other Names

• 2-(methoxycarbonyl)-1-propene
• 2-Methyl-2-propenoic acid methyl ester
• 2-Methylacrylic acid, methyl ester
• 2-Methylacrylic, methyl ester
• 2-Propenoic acid, 2-methyl-, methyl ester
• 2-methylpropenoic acid, methyl ester
• Acryester M
• Acrylic acid, 2-methyl-, methyl ester
• CH2=C(CH3)COOCH3
• Diakon
• MMA
• Metakrylan metylu
• Methacrylate de methyle
• Methacrylic acid methyl ester
• Methacrylsaeuremethyl ester
• Methyl 2-methyl-2-propenoate
• Methyl ester of 2-methyl-2-propenoic acid
• Methyl methacrylate monomer
• Methyl methylacrylate
• Methyl «alpha»-methylacrylate
• Methyl-methacrylat
• Methyl-«alpha»-methacrylate
• Methylester kyseliny methakrylove
• Methylmethacrylaat
• Metil metacrilato
• Monocite methacrylate monomer
• NCI-C50680
• NSC 4769
• Paladon
• Pegalan
• Rcra waste number U162
• TEB 3K
• methacrylic acid, methyl ester
• methyl 2-methylpropenoate

• ω : Acentric Factor.
• PAff : Proton affinity (kJ/mol).
• BasG : Gas basicity (kJ/mol).
• Δ_cH°_liquid : Standard liquid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• C_p,solid : Solid phase heat capacity (J/mol×K).
• μ : Dipole Moment (debye).
• η : Dynamic viscosity (Pa×s).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fH°_liquid : Liquid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_fusH : Enthalpy of fusion at a given temperature (kJ/mol).
• Δ_subH : Enthalpy of sublimation at a given temperature (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• P_triple : Triple Point Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I : Polar retention indices.
• Δ_fusS : Entropy of fusion at a given temperature (J/mol×K).
• S°_liquid : Liquid phase molar entropy at standard conditions (J/mol×K).
• c_sound,fluid : Speed of sound in fluid (m/s).
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• λ : Gas thermal conductivity (W/m×K).
• λ : Liquid thermal conductivity (W/m×K).
• T_fus : Normal melting (fusion) point (K).
• T_triple : Triple Point Temperature (K).
• U_Qi : UNIQUAC Qi Parameter.
• U_Ri : UNIQUAC Ri Parameter.
• V_c : Critical Volume (m³/kmol).
• Z_c : Critical Compressibility.
• Z_ra : Rackett Parameter.
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	0.2802		ChemSep v8.3 pure component data
PAff	831.40	kJ/mol	NIST
BasG	800.50	kJ/mol	NIST
ΔcH°liquid	-2724.60 ± 4.00	kJ/mol	NIST
μ	1.97	debye	ChemSep v8.3 pure component data
ΔfG°	-254.00	kJ/mol	ChemSep v8.3 pure component data
ΔfH°gas	[-360.00; -331.00]	kJ/mol
ΔfH°gas	-360.00	kJ/mol	ChemSep v8.3 pure component data
ΔfH°gas	-348.70	kJ/mol	NIST
ΔfH°gas	-342.30	kJ/mol	NIST
ΔfH°gas	-331.00	kJ/mol	NIST
ΔfH°liquid	[-388.80; -382.40]	kJ/mol
ΔfH°liquid	-382.40	kJ/mol	NIST
ΔfH°liquid	-388.80 ± 4.00	kJ/mol	NIST
ΔfusH°	10.48	kJ/mol	Joback Calculated Property
ΔvapH°	40.10	kJ/mol	NIST
IE	[9.70; 10.28]	eV
IE	9.70	eV	NIST
IE	10.06	eV	NIST
IE	10.28	eV	NIST
log10WS	-0.80		Aq. Solubility Prediction
logPoct/wat	0.735		Crippen Calculated Property
McVol	84.450	ml/mol	McGowan Calculated Property
Pc	3670.00	kPa	ChemSep v8.3 pure component data
Ptriple	0.02	kPa	ChemSep v8.3 pure component data
Inp	[666.00; 732.00]
Inp	714.30		NIST
Inp	717.33		NIST
Inp	716.28		NIST
Inp	713.44		NIST
Inp	696.00		NIST
Inp	700.00		NIST
Inp	694.00		NIST
Inp	666.00		NIST
Inp	670.00		NIST
Inp	699.00		NIST
Inp	677.00		NIST
Inp	677.00		NIST
Inp	677.00		NIST
Inp	677.00		NIST
Inp	732.00		NIST
Inp	710.40		NIST
Inp	723.00		NIST
Inp	672.00		NIST
Inp	710.00		NIST
Inp	696.00		NIST
Inp	714.00		NIST
Inp	699.00		NIST
Inp	696.00		NIST
Inp	696.00		NIST
Inp	699.00		NIST
Inp	677.00		NIST
Inp	699.00		NIST
Inp	710.00		NIST
Inp	732.00		NIST
Inp	714.30		NIST
Inp	700.00		NIST
Inp	677.00		NIST
I	[1002.00; 1010.00]
I	1010.00		NIST
I	1002.00		NIST
I	1008.00		NIST
I	1002.00		NIST
I	1008.00		NIST
S°liquid	266.20	J/mol×K	NIST
Tboil	[372.70; 374.15]	K
Tboil	374.15	K	ChemSep v8.3 pure component data
Tboil	373.55 ± 0.40	K	NIST
Tboil	373.55 ± 0.30	K	NIST
Tboil	373.55 ± 0.30	K	NIST
Tboil	373.70	K	NIST
Tboil	373.55 ± 0.40	K	NIST
Tboil	373.55 ± 0.30	K	NIST
Tboil	373.55 ± 0.30	K	NIST
Tboil	374.15	K	NIST
Tboil	373.25 ± 0.50	K	NIST
Tboil	Outlier 372.70 ± 3.00	K	NIST
Tboil	373.15 ± 1.20	K	NIST
Tc	[557.90; 563.15]	K
Tc	557.90	K	DIPPR Project 851 - Thirty Years of Vapor-Liquid Critical Point Measurements and Experimental Technique Development
Tc	563.15	K	ChemSep v8.3 pure component data
Tfus	[225.00; 225.60]	K
Tfus	225.15	K	ChemSep v8.3 pure component data
Tfus	225.26	K	Aq. Solubility Prediction
Tfus	225.60	K	NIST
Tfus	225.60	K	NIST
Tfus	225.00	K	NIST
Tfus	225.60 ± 0.20	K	NIST
Tfus	225.50 ± 0.20	K	NIST
Tfus	225.15 ± 0.40	K	NIST
Ttriple	[225.59; 225.60]	K
Ttriple	225.60	K	ChemSep v8.3 pure component data
Ttriple	225.59 ± 0.02	K	NIST
UQi	3.56		ChemSep v8.3 pure component data
URi	3.92		ChemSep v8.3 pure component data
Vc	0.324	m3/kmol	ChemSep v8.3 pure component data
Zc	0.2530000		ChemSep v8.3 pure component data
Zra	0.25		ChemSep v8.3 pure component data

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[188.49; 215.30]	J/mol×K	[293.00; 300.00]
Cp,liquid	188.49	J/mol×K	293.00	NIST
Cp,liquid	191.09	J/mol×K	298.15	NIST
Cp,liquid	215.30	J/mol×K	298.15	NIST
Cp,liquid	215.30	J/mol×K	298.15	NIST
Cp,liquid	210.55	J/mol×K	298.15	NIST
Cp,liquid	192.40	J/mol×K	300.00	NIST
Cp,solid	150.20	J/mol×K	210.00	NIST
η	[0.0003398; 0.0006808]	Pa×s	[283.15; 353.15]
η	0.0006808	Pa×s	283.15	Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η	0.0006808	Pa×s	283.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η	0.0006337	Pa×s	288.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η	0.0006337	Pa×s	288.15	Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η	0.0005899	Pa×s	293.15	Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η	0.0005899	Pa×s	293.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η	0.0005540	Pa×s	298.15	Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η	0.0005540	Pa×s	298.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η	0.0005248	Pa×s	303.15	Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η	0.0005248	Pa×s	303.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η	0.0004956	Pa×s	308.15	Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η	0.0004956	Pa×s	308.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η	0.0004719	Pa×s	313.15	Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η	0.0004719	Pa×s	313.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η	0.0004497	Pa×s	318.15	Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η	0.0004497	Pa×s	318.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η	0.0004294	Pa×s	323.15	Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η	0.0004294	Pa×s	323.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η	0.0004100	Pa×s	328.15	Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η	0.0004100	Pa×s	328.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η	0.0003938	Pa×s	333.15	Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η	0.0003938	Pa×s	333.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η	0.0003636	Pa×s	343.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η	0.0003398	Pa×s	353.15	Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
ΔfusH	[12.24; 14.44]	kJ/mol	[225.00; 225.59]
ΔfusH	12.24	kJ/mol	225.00	NIST
ΔfusH	12.24	kJ/mol	225.00	NIST
ΔfusH	13.45	kJ/mol	225.50	NIST
ΔfusH	13.45	kJ/mol	225.50	NIST
ΔfusH	14.44	kJ/mol	225.59	NIST
ΔsubH	60.70	kJ/mol	208.50	NIST
ΔvapH	[33.30; 39.00]	kJ/mol	[333.00; 340.50]
ΔvapH	37.90	kJ/mol	333.00	NIST
ΔvapH	37.70	kJ/mol	333.00	NIST
ΔvapH	39.00	kJ/mol	337.00	NIST
ΔvapH	38.00	kJ/mol	339.00	NIST
ΔvapH	38.80 ± 0.10	kJ/mol	340.50	NIST
ΔvapH	36.30 ± 0.20	kJ/mol	340.50	NIST
ΔvapH	33.30 ± 0.40	kJ/mol	340.50	NIST
ρl	[914.66; 949.10]	kg/m3	[288.15; 318.15]
ρl	949.10	kg/m3	288.15	Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl	943.38	kg/m3	293.15	Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
ρl	943.37	kg/m3	293.15	Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl	937.63	kg/m3	298.15	Volumetric Properties of 3-Methylbutyl Ethanoate with Ethyl Acrylate, Butyl Acrylate, Methyl Methacrylate, and Styrene at 25 C
ρl	937.63	kg/m3	298.15	Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl	937.65	kg/m3	298.15	Densities and volumes of mixing of the ternary system toluene + butyl acrylate + methyl methacrylate and its binaries at 298.15 K
ρl	937.64	kg/m3	298.15	Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
ρl	931.90	kg/m3	303.15	Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
ρl	931.89	kg/m3	303.15	Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl	926.15	kg/m3	308.15	Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl	926.16	kg/m3	308.15	Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
ρl	920.41	kg/m3	313.15	Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl	920.42	kg/m3	313.15	Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
ρl	914.66	kg/m3	318.15	Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl	914.67	kg/m3	318.15	Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
ΔfusS	[59.65; 64.00]	J/mol×K	[225.50; 225.59]
ΔfusS	59.65	J/mol×K	225.50	NIST
ΔfusS	59.65	J/mol×K	225.50	NIST
ΔfusS	64.00	J/mol×K	225.59	NIST
csound,fluid	[1152.00; 1182.00]	m/s	[298.15; 308.15]
csound,fluid	1181.00	m/s	298.15	Densities, Excess Molar Volumes at T = (298.15 to 313.15) K, Speeds of Sound, Excess Isentropic Compressibilities, Relative Permittivities and Deviations in Molar Polarizations at T = (298.15 and 308.15) K for Methyl Methacrylate + 2-Butoxyethanol or + Dibutyl Ether + Benzene, + Toluene and + p-Xylene
csound,fluid	1182.00	m/s	298.15	Densities, Speeds of Sound, Excess Molar Volumes, and Excess Isentropic Compressibilities at T = (298.15 and 308.15) K for Methyl Methacrylate + 1-Alkanols (1-Butanol, 1-Pentanol, and 1-Heptanol) + Cyclohexane, + Benzene, + Toluene, + p-Xylene, and + Ethylbenzene
csound,fluid	1153.00	m/s	308.15	Densities, Excess Molar Volumes at T = (298.15 to 313.15) K, Speeds of Sound, Excess Isentropic Compressibilities, Relative Permittivities and Deviations in Molar Polarizations at T = (298.15 and 308.15) K for Methyl Methacrylate + 2-Butoxyethanol or + Dibutyl Ether + Benzene, + Toluene and + p-Xylene
csound,fluid	1152.00	m/s	308.15	Densities, Speeds of Sound, Excess Molar Volumes, and Excess Isentropic Compressibilities at T = (298.15 and 308.15) K for Methyl Methacrylate + 1-Alkanols (1-Butanol, 1-Pentanol, and 1-Heptanol) + Cyclohexane, + Benzene, + Toluene, + p-Xylene, and + Ethylbenzene

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[107.29; 286.45]	J/mol×K	[273.00; 1500.00]	ChemSep v8.3 pure component data
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is Cp,gas in J/mol×K, T in K
Coefficient A			4.08629e+01
Coefficient B			-4.08079e+02
Coefficient C			5.62676e+00
Coefficient D			2.65188e-04
Coefficient E			-1.10593e-07
Comment			ChemSep eq 16, IdealGasHeatCapacityCp
Temperature range, min.			273.00
Temperature range, max.			1500.00
Cp,gas	107.29	J/mol×K	273.00	Calculated Property
Cp,gas	153.01	J/mol×K	409.33	Calculated Property
Cp,gas	187.90	J/mol×K	545.67	Calculated Property
Cp,gas	214.65	J/mol×K	682.00	Calculated Property
Cp,gas	235.48	J/mol×K	818.33	Calculated Property
Cp,gas	251.83	J/mol×K	954.67	Calculated Property
Cp,gas	264.59	J/mol×K	1091.00	Calculated Property
Cp,gas	274.36	J/mol×K	1227.33	Calculated Property
Cp,gas	281.55	J/mol×K	1363.67	Calculated Property
Cp,gas	286.45	J/mol×K	1500.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[164.80; 239.68]	J/mol×K	[224.95; 373.45]	ChemSep v8.3 pure component data
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is Cp,liquid in J/mol×K, T in K
Coefficient A			4.52510e+01
Coefficient B			7.33560e+02
Coefficient C			-2.88766e+00
Coefficient D			2.41830e-02
Coefficient E			-2.03470e-05
Comment			ChemSep eq 16, LiquidHeatCapacityCp
Temperature range, min.			224.95
Temperature range, max.			373.45
Cp,liquid	164.80	J/mol×K	224.95	Calculated Property
Cp,liquid	167.16	J/mol×K	241.45	Calculated Property
Cp,liquid	171.76	J/mol×K	257.95	Calculated Property
Cp,liquid	178.15	J/mol×K	274.45	Calculated Property
Cp,liquid	186.04	J/mol×K	290.95	Calculated Property
Cp,liquid	195.16	J/mol×K	307.45	Calculated Property
Cp,liquid	205.31	J/mol×K	323.95	Calculated Property
Cp,liquid	216.27	J/mol×K	340.45	Calculated Property
Cp,liquid	227.81	J/mol×K	356.95	Calculated Property
Cp,liquid	239.68	J/mol×K	373.45	Calculated Property

Property	Value	Unit	Temperature (K)	Source
η	[0.0008668; 0.0001473]	Pa×s	[260.00; 463.00]	ChemSep v8.3 pure component data
Equation			Y = exp(A + B/T + C·ln(T) + D·T^E) Y is η in Pa×s, T in K
Coefficient A			-8.23420e+00
Coefficient B			7.80750e+02
Coefficient C			-3.03930e-01
Coefficient D			-1.91270e-06
Coefficient E			2.00000e+00
Comment			ChemSep eq 101, LiquidViscosity
Temperature range, min.			260.00
Temperature range, max.			463.00
η	0.0008668	Pa×s	260.00	Calculated Property
η	0.0006497	Pa×s	282.56	Calculated Property
η	0.0005045	Pa×s	305.11	Calculated Property
η	0.0004028	Pa×s	327.67	Calculated Property
η	0.0003288	Pa×s	350.22	Calculated Property
η	0.0002732	Pa×s	372.78	Calculated Property
η	0.0002304	Pa×s	395.33	Calculated Property
η	0.0001966	Pa×s	417.89	Calculated Property
η	0.0001695	Pa×s	440.44	Calculated Property
η	0.0001473	Pa×s	463.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
ΔvapH	[44.79; 11.76]	kJ/mol	[224.95; 548.05]	ChemSep v8.3 pure component data
Equation			Y = A·(1 − Tr)^(B + C·Tr + D·Tr² + E·Tr³), Tr = T/Tc Y is ΔvapH in kJ/mol, T in K
Coefficient A			5.39729e+01
Coefficient B			-8.62845e-02
Coefficient C			1.85779e+00
Coefficient D			-2.12770e+00
Coefficient E			7.75243e-01
Critical temperature, Tc (K)			5.63150e+02
Comment			ChemSep eq 106, HeatOfVaporization
Temperature range, min.			224.95
Temperature range, max.			548.05
ΔvapH	44.79	kJ/mol	224.95	Calculated Property
ΔvapH	42.22	kJ/mol	260.85	Calculated Property
ΔvapH	39.55	kJ/mol	296.75	Calculated Property
ΔvapH	36.81	kJ/mol	332.65	Calculated Property
ΔvapH	33.98	kJ/mol	368.55	Calculated Property
ΔvapH	31.00	kJ/mol	404.45	Calculated Property
ΔvapH	27.78	kJ/mol	440.35	Calculated Property
ΔvapH	24.07	kJ/mol	476.25	Calculated Property
ΔvapH	19.37	kJ/mol	512.15	Calculated Property
ΔvapH	11.76	kJ/mol	548.05	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Pvap	[0.02; 3654.99]	kPa	[224.95; 566.00]	ChemSep v8.3 pure component data
Equation			Y = exp(A + B/T + C·ln(T) + D·T^E) Y is Pvap in kPa, T in K
Coefficient A			1.22593e+02
Coefficient B			-8.90782e+03
Coefficient C			-1.61750e+01
Coefficient D			1.20980e-05
Coefficient E			2.00000e+00
Comment			ChemSep eq 101, VaporPressure
Temperature range, min.			224.95
Temperature range, max.			566.00
Pvap	0.02	kPa	224.95	Calculated Property
Pvap	0.56	kPa	262.84	Calculated Property
Pvap	5.87	kPa	300.74	Calculated Property
Pvap	31.73	kPa	338.63	Calculated Property
Pvap	111.80	kPa	376.53	Calculated Property
Pvap	296.33	kPa	414.42	Calculated Property
Pvap	648.30	kPa	452.32	Calculated Property
Pvap	1245.76	kPa	490.21	Calculated Property
Pvap	2194.81	kPa	528.11	Calculated Property
Pvap	3654.99	kPa	566.00	Calculated Property
Pvap	[0.02; 3783.32]	kPa	[224.95; 564.00]	KDB Vapor Pressure Data
Equation			ln(Y) = A + B/T + C·ln(T) + D·T² + E/T² Y is Pvap in kPa, T in K
Coefficient A			1.28053e+02
Coefficient B			-8.95480e+03
Coefficient C			-1.71457e+01
Coefficient D			1.47176e-05
Coefficient E			0.00000e+00
Temperature range, min.			224.95
Temperature range, max.			564.00
Pvap	0.02	kPa	224.95	Calculated Property
Pvap	0.58	kPa	262.62	Calculated Property
Pvap	5.74	kPa	300.29	Calculated Property
Pvap	29.95	kPa	337.97	Calculated Property
Pvap	103.59	kPa	375.64	Calculated Property
Pvap	273.70	kPa	413.31	Calculated Property
Pvap	605.13	kPa	450.98	Calculated Property
Pvap	1189.92	kPa	488.66	Calculated Property
Pvap	2170.45	kPa	526.33	Calculated Property
Pvap	3783.32	kPa	564.00	Calculated Property
Pvap	[9.90; 78.21]	kPa	[312.40; 362.30]	NIST
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.69881e+01
Coefficient B			-4.47982e+03
Coefficient C			-7.56900e+00
Reference			Brockhaus and Jenckel, 1956
Comment			Coefficents calculated by NIST from author's data.
Temperature range, min.			312.40
Temperature range, max.			362.30
Pvap	9.90	kPa	312.40	Calculated Property
Pvap	12.87	kPa	317.94	Calculated Property
Pvap	16.57	kPa	323.49	Calculated Property
Pvap	21.17	kPa	329.03	Calculated Property
Pvap	26.81	kPa	334.58	Calculated Property
Pvap	33.69	kPa	340.12	Calculated Property
Pvap	42.02	kPa	345.67	Calculated Property
Pvap	52.03	kPa	351.21	Calculated Property
Pvap	64.00	kPa	356.76	Calculated Property
Pvap	78.21	kPa	362.30	Calculated Property

Property	Value	Unit	Temperature (K)	Source
ρl	[1019.03; 507.56]	kg/m3	[224.95; 548.05]	ChemSep v8.3 pure component data
Equation			Y = A / B^(1 + (1 − T/C)^D) Y is ρl in kg/m3, T in K
Coefficient A			9.17541e+01
Coefficient B			2.72050e-01
Coefficient C			5.63150e+02
Coefficient D			3.20100e-01
Comment			ChemSep eq 105, LiquidDensity
Temperature range, min.			224.95
Temperature range, max.			548.05
ρl	1019.03	kg/m3	224.95	Calculated Property
ρl	980.04	kg/m3	260.85	Calculated Property
ρl	939.45	kg/m3	296.75	Calculated Property
ρl	896.87	kg/m3	332.65	Calculated Property
ρl	851.77	kg/m3	368.55	Calculated Property
ρl	803.33	kg/m3	404.45	Calculated Property
ρl	750.22	kg/m3	440.35	Calculated Property
ρl	689.93	kg/m3	476.25	Calculated Property
ρl	616.68	kg/m3	512.15	Calculated Property
ρl	507.56	kg/m3	548.05	Calculated Property

Property	Value	Unit	Temperature (K)	Source
γ	[0.04; 5.00e-04]	N/m	[224.95; 548.05]	ChemSep v8.3 pure component data
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is γ in N/m, T in K
Coefficient A			-3.54250e-02
Coefficient B			-5.88770e+01
Coefficient C			-1.57630e+00
Coefficient D			-3.70630e-03
Coefficient E			1.29390e-06
Comment			ChemSep eq 16, SurfaceTension
Temperature range, min.			224.95
Temperature range, max.			548.05
γ	0.04	N/m	224.95	Calculated Property
γ	0.03	N/m	260.85	Calculated Property
γ	0.03	N/m	296.75	Calculated Property
γ	0.02	N/m	332.65	Calculated Property
γ	0.02	N/m	368.55	Calculated Property
γ	0.01	N/m	404.45	Calculated Property
γ	0.01	N/m	440.35	Calculated Property
γ	0.01	N/m	476.25	Calculated Property
γ	0.00	N/m	512.15	Calculated Property
γ	5.00e-04	N/m	548.05	Calculated Property

Property	Value	Unit	Temperature (K)	Source
λ	[0.01; 0.08]	W/m×K	[225.60; 1000.00]	ChemSep v8.3 pure component data
Equation			Y = A·T^B / (1 + C/T + D/T²) Y is λ in W/m×K, T in K
Coefficient A			2.35060e-03
Coefficient B			6.11680e-01
Coefficient C			8.48430e+02
Coefficient D			2.52520e+05
Comment			ChemSep eq 102, VaporThermalConductivity
Temperature range, min.			225.60
Temperature range, max.			1000.00
λ	0.01	W/m×K	225.60	Calculated Property
λ	0.01	W/m×K	311.64	Calculated Property
λ	0.02	W/m×K	397.69	Calculated Property
λ	0.03	W/m×K	483.73	Calculated Property
λ	0.03	W/m×K	569.78	Calculated Property
λ	0.04	W/m×K	655.82	Calculated Property
λ	0.05	W/m×K	741.87	Calculated Property
λ	0.06	W/m×K	827.91	Calculated Property
λ	0.07	W/m×K	913.96	Calculated Property
λ	0.08	W/m×K	1000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
λ	[0.15; 0.12]	W/m×K	[290.15; 363.45]	ChemSep v8.3 pure component data
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is λ in W/m×K, T in K
Coefficient A			9.37440e-02
Coefficient B			-5.12970e+01
Coefficient C			-1.82890e-01
Coefficient D			-7.83510e-03
Coefficient E			-3.04050e-06
Comment			ChemSep eq 16, LiquidThermalConductivity
Temperature range, min.			290.15
Temperature range, max.			363.45
λ	0.15	W/m×K	290.15	Calculated Property
λ	0.15	W/m×K	298.29	Calculated Property
λ	0.14	W/m×K	306.44	Calculated Property
λ	0.14	W/m×K	314.58	Calculated Property
λ	0.14	W/m×K	322.73	Calculated Property
λ	0.13	W/m×K	330.87	Calculated Property
λ	0.13	W/m×K	339.02	Calculated Property
λ	0.13	W/m×K	347.16	Calculated Property
λ	0.12	W/m×K	355.31	Calculated Property
λ	0.12	W/m×K	363.45	Calculated Property

Similar Compounds

Find more compounds similar to Methyl methacrylate.

Mixtures

• Benzonitrile + Methyl methacrylate
• sodium chloride + Methyl methacrylate + Water
• Methyl methacrylate + Water
• 1-Butanol + Methyl methacrylate + Water
• 1-Propanol + Methyl methacrylate + Water
• Formamide, N,N-dimethyl- + Methyl methacrylate
• N,N-Dimethylacetamide + Methyl methacrylate
• Toluene + Methyl methacrylate
• Methyl methacrylate + 2-Propenoic acid, butyl ester
• Toluene + Methyl methacrylate + 2-Propenoic acid, butyl ester
• Acetonitrile + Methyl methacrylate
• 1-Butanol, 3-methyl-, acetate + Methyl methacrylate
• Carbon dioxide + Methyl methacrylate
• 1-Butanol + Methyl methacrylate + Cyclohexane
• Benzene + 1-Butanol + Methyl methacrylate
• Toluene + 1-Butanol + Methyl methacrylate
• p-Xylene + 1-Butanol + Methyl methacrylate
• 1-Butanol + Benzene, ethyl- + Methyl methacrylate
• 1-Pentanol + Methyl methacrylate + Cyclohexane
• Benzene + 1-Pentanol + Methyl methacrylate

Find more mixtures with Methyl methacrylate.

Sources

• KDB Vapor Pressure Data
• ChemSep v8.3 pure component data Converted from ChemSep v8.3 pure component data, H. Kooijman and R. Taylor (2021, 2022), Artistic License 2.0; see how the values differ.
• Crippen Method
• Volumetric Properties of 3-Methylbutyl Ethanoate with Ethyl Acrylate, Butyl Acrylate, Methyl Methacrylate, and Styrene at 25 C
• Liquid liquid equilibria for the ternary systems water + 1-propanol + methyl methacrylate, +butyl methacrylate, and +isobutyl methacrylate
• Liquid liquid equilibria of water + 1-butanol + methyl methacrylate or butyl methacrylate or isobutyl methacrylate at 288.15K and 318.15K
• Activity coefficients and partial molar excess enthalpies at infinite dilution for four esters in water
• Liquid-liquid equilibria for systems of water + methanol + methyl anthranilate at several temperatures
• Densities and volumes of mixing of the ternary system toluene + butyl acrylate + methyl methacrylate and its binaries at 298.15 K
• Combined effects of salinity and temperature on the solubility of organic compounds
• Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
• Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
• Densities, speeds of sound and excess properties of (benzonitrile + methyl methacrylate, or + ethyl methacrylate, or + n-butyl methacrylate) binary mixtures at temperatures from 293.15 K to 318.15 K
• DIPPR Project 851 - Thirty Years of Vapor-Liquid Critical Point Measurements and Experimental Technique Development
• Densities, Excess Molar Volumes at T = (298.15 to 313.15) K, Speeds of Sound, Excess Isentropic Compressibilities, Relative Permittivities and Deviations in Molar Polarizations at T = (298.15 and 308.15) K for Methyl Methacrylate + 2-Butoxyethanol or + Dibutyl Ether + Benzene, + Toluene and + p-Xylene
• Methyl Methacrylate + Carbon Dioxide Phase Equilibria at High Pressures
• Densities, Speeds of Sound, Excess Molar Volumes, and Excess Isentropic Compressibilities at T = (298.15 and 308.15) K for Methyl Methacrylate + 1-Alkanols (1-Butanol, 1-Pentanol, and 1-Heptanol) + Cyclohexane, + Benzene, + Toluene, + p-Xylene, and + Ethylbenzene
• Determination of Henry's Law Constants Using Internal Standards with Benchmark Values
• Liquid-Liquid Equilibria for the Ternary Systems Water + 2-Propanol + Methyl Methacrylate, + Butyl Methacrylate, and + Isobutyl Methacrylate
• Liquid-Liquid Equilibria of Water + 2-Butanol + (Methyl Methacrylate or Butyl Methacrylate or Isobutyl Methacrylate) at (288.2 and 318.2) K
• Phase Behavior Studies of 2-Hydroxyethyl Methacrylate and Methyl Methacrylate in High-Pressure Carbon Dioxide
• Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
• Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
• Joback Method
• KDB
• Aqueous Solubility Prediction Method
• McGowan Method
• NIST Webbook

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