Chemical Properties of Methyl methacrylate (CAS 80-62-6)

Methyl methacrylate

InChI
InChI=1S/C5H8O2/c1-4(2)5(6)7-3/h1H2,2-3H3
InChI Key
VVQNEPGJFQJSBK-UHFFFAOYSA-N
Formula
C5H8O2
SMILES
C=C(C)C(=O)OC
Molecular Weight1
100.12
CAS
80-62-6
Other Names
  • 2-(Methoxycarbonyl)-1-propene
  • 2-Methyl-2-propenoic acid methyl ester
  • 2-Methylacrylic acid, methyl ester
  • 2-Methylacrylic, methyl ester
  • 2-Propenoic acid, 2-methyl-, methyl ester
  • 2-methylpropenoic acid, methyl ester
  • Acryester M
  • Acrylic acid, 2-methyl-, methyl ester
  • CH2=C(CH3)COOCH3
  • Diakon
  • MMA
  • Metakrylan metylu
  • Methacrylate de methyle
  • Methacrylic acid methyl ester
  • Methacrylsaeuremethyl ester
  • Methyl 2-methyl-2-propenoate
  • Methyl 2-methylpropenoate
  • Methyl ester of 2-methyl-2-propenoic acid
  • Methyl methacrylate monomer
  • Methyl methylacrylate
  • Methyl «alpha»-methylacrylate
  • Methyl «alpha»-methylacrylate
  • Methyl-methacrylat
  • Methyl-«alpha»-methacrylate
  • Methyl-«alpha»-methacrylate
  • Methylester kyseliny methakrylove
  • Methylmethacrylaat
  • Metil metacrilato
  • Monocite methacrylate monomer
  • NCI-C50680
  • NSC 4769
  • Paladon
  • Pegalan
  • Rcra waste number U162
  • TEB 3K
  • methacrylic acid, methyl ester
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Physical Properties

Property Value Unit Source
ω 0.3785 Relay (1.0) Calculated Property
PAff 831.40 kJ/mol NIST
BasG 800.50 kJ/mol NIST
Δcliquid -2724.60 ± 4.00 kJ/mol NIST
Δf -163.41 kJ/mol Joback Calculated Property
Δfgas [-348.70; -331.00] kJ/mol Show Hide
Δfgas -348.70 kJ/mol NIST
Δfgas -342.30 kJ/mol NIST
Δfgas -331.00 kJ/mol NIST
Δfliquid [-388.80; -382.40] kJ/mol Show Hide
Δfliquid -382.40 kJ/mol NIST
Δfliquid -388.80 ± 4.00 kJ/mol NIST
Δfus 8.90 kJ/mol Joback Calculated Property
Δvap 40.10 kJ/mol NIST
IE [9.70; 10.28] eV Show Hide
IE 9.70 eV NIST
IE 10.06 eV NIST
IE 10.28 eV NIST
log10WS -0.80 Aq. Solubility Prediction
logPoct/wat 0.735 Crippen Calculated Property
McVol 84.450 ml/mol McGowan Calculated Property
Pc 3881.95 kPa Joback Calculated Property
Inp [666.00; 732.00]   Show Hide
Inp 714.30 NIST
Inp 717.33 NIST
Inp 716.28 NIST
Inp 713.44 NIST
Inp 696.00 NIST
Inp 700.00 NIST
Inp 694.00 NIST
Inp 666.00 NIST
Inp 670.00 NIST
Inp 699.00 NIST
Inp 677.00 NIST
Inp 677.00 NIST
Inp 677.00 NIST
Inp 677.00 NIST
Inp 732.00 NIST
Inp 710.40 NIST
Inp 723.00 NIST
Inp 672.00 NIST
Inp 710.00 NIST
Inp 696.00 NIST
Inp 714.00 NIST
Inp 699.00 NIST
Inp 696.00 NIST
Inp 696.00 NIST
Inp 699.00 NIST
Inp 677.00 NIST
Inp 699.00 NIST
Inp 677.00 NIST
Inp 732.00 NIST
I [1002.00; 1010.00]   Show Hide
I 1010.00 NIST
I 1002.00 NIST
I 1008.00 NIST
I 1002.00 NIST
I 1008.00 NIST
liquid 266.20 J/mol×K NIST
Tboil 371.58 K Relay (1.0) Calculated Property
Tc 554.64 K Relay (1.0) Calculated Property
Tfus [225.00; 225.60] K Show Hide
Tfus 225.26 K Aq. Solubility Prediction
Tfus 225.60 K NIST
Tfus 225.60 K NIST
Tfus 225.00 K NIST
Tfus 225.60 ± 0.20 K NIST
Tfus 225.50 ± 0.20 K NIST
Tfus 225.15 ± 0.40 K NIST
Ttriple 225.59 ± 0.02 K NIST
Vc 0.313 m3/kmol Relay (1.0) Calculated Property

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,gas [149.36; 192.58] J/mol×K [386.65; 572.77] Show Hide
Cp,gas 149.36 J/mol×K 386.65 Joback Calculated Property
Cp,gas 157.23 J/mol×K 417.67 Joback Calculated Property
Cp,gas 164.83 J/mol×K 448.69 Joback Calculated Property
Cp,gas 172.17 J/mol×K 479.71 Joback Calculated Property
Cp,gas 179.24 J/mol×K 510.73 Joback Calculated Property
Cp,gas 186.04 J/mol×K 541.75 Joback Calculated Property
Cp,gas 192.58 J/mol×K 572.77 Joback Calculated Property
Cp,liquid [188.49; 215.30] J/mol×K [293.00; 300.00] Show Hide
Cp,liquid 188.49 J/mol×K 293.00 NIST
Cp,liquid 191.09 J/mol×K 298.15 NIST
Cp,liquid 215.30 J/mol×K 298.15 NIST
Cp,liquid 215.30 J/mol×K 298.15 NIST
Cp,liquid 210.55 J/mol×K 298.15 NIST
Cp,liquid 192.40 J/mol×K 300.00 NIST
Cp,solid 150.20 J/mol×K 210.00 NIST
η [0.0003398; 0.0006808] Pa×s [283.15; 353.15] Show Hide
η 0.0006808 Pa×s 283.15 Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η 0.0006808 Pa×s 283.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η 0.0006337 Pa×s 288.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η 0.0006337 Pa×s 288.15 Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η 0.0005899 Pa×s 293.15 Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η 0.0005899 Pa×s 293.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η 0.0005540 Pa×s 298.15 Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η 0.0005540 Pa×s 298.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η 0.0005248 Pa×s 303.15 Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η 0.0005248 Pa×s 303.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η 0.0004956 Pa×s 308.15 Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η 0.0004956 Pa×s 308.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η 0.0004719 Pa×s 313.15 Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η 0.0004719 Pa×s 313.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η 0.0004497 Pa×s 318.15 Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η 0.0004497 Pa×s 318.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η 0.0004294 Pa×s 323.15 Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η 0.0004294 Pa×s 323.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η 0.0004100 Pa×s 328.15 Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η 0.0004100 Pa×s 328.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η 0.0003938 Pa×s 333.15 Excess Molar Volume and Viscosity Deviation for the Methanol + Methyl Methacrylate Binary System at T) (283.15 to 333.15) K
η 0.0003938 Pa×s 333.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η 0.0003636 Pa×s 343.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
η 0.0003398 Pa×s 353.15 Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure
ΔfusH [12.24; 14.44] kJ/mol [225.00; 225.59] Show Hide
ΔfusH 12.24 kJ/mol 225.00 NIST
ΔfusH 12.24 kJ/mol 225.00 NIST
ΔfusH 13.45 kJ/mol 225.50 NIST
ΔfusH 14.44 kJ/mol 225.59 NIST
ΔsubH 60.70 kJ/mol 208.50 NIST
ΔvapH [33.30; 39.00] kJ/mol [333.00; 340.50] Show Hide
ΔvapH 37.90 kJ/mol 333.00 NIST
ΔvapH 37.70 kJ/mol 333.00 NIST
ΔvapH 39.00 kJ/mol 337.00 NIST
ΔvapH 38.00 kJ/mol 339.00 NIST
ΔvapH 38.80 ± 0.10 kJ/mol 340.50 NIST
ΔvapH 36.30 ± 0.20 kJ/mol 340.50 NIST
ΔvapH 33.30 ± 0.40 kJ/mol 340.50 NIST
ρl [914.66; 949.10] kg/m3 [288.15; 318.15] Show Hide
ρl 949.10 kg/m3 288.15 Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl 943.38 kg/m3 293.15 Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
ρl 943.37 kg/m3 293.15 Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl 937.63 kg/m3 298.15 Volumetric Properties of 3-Methylbutyl Ethanoate with Ethyl Acrylate, Butyl Acrylate, Methyl Methacrylate, and Styrene at 25 C
ρl 937.63 kg/m3 298.15 Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl 937.65 kg/m3 298.15 Densities and volumes of mixing of the ternary system toluene + butyl acrylate + methyl methacrylate and its binaries at 298.15 K
ρl 937.64 kg/m3 298.15 Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
ρl 931.90 kg/m3 303.15 Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
ρl 931.89 kg/m3 303.15 Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl 926.15 kg/m3 308.15 Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl 926.16 kg/m3 308.15 Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
ρl 920.41 kg/m3 313.15 Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl 920.42 kg/m3 313.15 Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
ρl 914.66 kg/m3 318.15 Densities, ultrasonic speeds, viscosities and excess properties of binary mixtures of methyl methacrylate with N,N-dimethylformamide and N,N-dimethylacetamide at different temperatures
ρl 914.67 kg/m3 318.15 Densities, ultrasonic speeds, excess and partial molar properties of binary mixtures of acetonitrile with some alkyl methacrylates at temperatures from 293.15 K to 318.15 K
ΔfusS [59.65; 64.00] J/mol×K [225.50; 225.59] Show Hide
ΔfusS 59.65 J/mol×K 225.50 NIST
ΔfusS 64.00 J/mol×K 225.59 NIST
csound,fluid [1152.00; 1182.00] m/s [298.15; 308.15] Show Hide
csound,fluid 1181.00 m/s 298.15 Densities, Excess Molar Volumes at T = (298.15 to 313.15) K, Speeds of Sound, Excess Isentropic Compressibilities, Relative Permittivities and Deviations in Molar Polarizations at T = (298.15 and 308.15) K for Methyl Methacrylate + 2-Butoxyethanol or + Dibutyl Ether + Benzene, + Toluene and + p-Xylene
csound,fluid 1182.00 m/s 298.15 Densities, Speeds of Sound, Excess Molar Volumes, and Excess Isentropic Compressibilities at T = (298.15 and 308.15) K for Methyl Methacrylate + 1-Alkanols (1-Butanol, 1-Pentanol, and 1-Heptanol) + Cyclohexane, + Benzene, + Toluene, + p-Xylene, and + Ethylbenzene
csound,fluid 1153.00 m/s 308.15 Densities, Excess Molar Volumes at T = (298.15 to 313.15) K, Speeds of Sound, Excess Isentropic Compressibilities, Relative Permittivities and Deviations in Molar Polarizations at T = (298.15 and 308.15) K for Methyl Methacrylate + 2-Butoxyethanol or + Dibutyl Ether + Benzene, + Toluene and + p-Xylene
csound,fluid 1152.00 m/s 308.15 Densities, Speeds of Sound, Excess Molar Volumes, and Excess Isentropic Compressibilities at T = (298.15 and 308.15) K for Methyl Methacrylate + 1-Alkanols (1-Butanol, 1-Pentanol, and 1-Heptanol) + Cyclohexane, + Benzene, + Toluene, + p-Xylene, and + Ethylbenzene

Correlations

Property Value Unit Temperature (K) Source
Pvap [0.02; 3783.32] kPa [224.95; 564.00] KDB Vapor Pressure Data Show Hide
Equationln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A1.28053e+02
Coefficient B-8.95480e+03
Coefficient C-1.71457e+01
Coefficient D1.47176e-05
Temperature range, min.224.95
Temperature range, max.564.00
Pvap 0.02 kPa 224.95 Calculated Property
Pvap 0.58 kPa 262.62 Calculated Property
Pvap 5.74 kPa 300.29 Calculated Property
Pvap 29.95 kPa 337.97 Calculated Property
Pvap 103.59 kPa 375.64 Calculated Property
Pvap 273.70 kPa 413.31 Calculated Property
Pvap 605.13 kPa 450.98 Calculated Property
Pvap 1189.92 kPa 488.66 Calculated Property
Pvap 2170.45 kPa 526.33 Calculated Property
Pvap 3783.32 kPa 564.00 Calculated Property

Similar Compounds

Methyl 2-(bromomethyl)acrylate. 2-Propenoic acid, 2-methyl-, ethenyl ester. Methacrylic acid, ethyl ester. 2,2,2-Trifluoroethyl methacrylate. Methacrylic acid, 2,2,2-trichloroethyl ester. Methacrylic anhydride. Methyl tiglate. 2-Butenoic acid, 2-methyl-, methyl ester. Methyl tiglate. Methacrylic acid, 2-hydroxyethyl ester. 2-Propenoic acid, 2-methyl-, 1,2-ethanediyl ester. 2-Propenoic acid, 2-methyl-, 2-propenyl ester. 2-Methyl-2-propenoic acid. 2-Propenoic acid, 2-methyl-, 2-chloroethyl ester. Butanoic acid, 2-methylene-, methyl ester.

Find more compounds similar to Methyl methacrylate.

Mixtures

Find more mixtures with Methyl methacrylate.

Sources

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