Chemical Properties of Furan, tetrahydro-2-methyl- (CAS 96-47-9)

InChI

InChI=1S/C5H10O/c1-5-3-2-4-6-5/h5H,2-4H2,1H3

InChI Key

JWUJQDFVADABEY-UHFFFAOYSA-N

Formula

C5H10O

SMILES

CC1CCCO1

Molecular Weight¹

86.13

CAS

96-47-9

Other Names

• .alpha.-methyltetramethylene oxide
• 2-Methylfuranidine
• 2-Methyltetrahydrofurane
• 2-methyloxolane
• 2-methyltetrahydrofuran
• Furan, 2-methyl-tetrahydro-
• Methyltetrahydrofuran
• Tetrahydrofuran, 2-methyl-
• tetrahydro-2-methylfuran
• tetrahydrosylvan

• ω : Acentric Factor.
• PAff : Proton affinity (kJ/mol).
• BasG : Gas basicity (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• η : Dynamic viscosity (Pa×s).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• IE : Ionization energy (eV).
• ν : Kinematic viscosity (m²/s).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• n₀ : Refractive Index.
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I : Polar retention indices.
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• V_c : Critical Volume (m³/kmol).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	0.2547		Relay (1.0) Calculated Property
PAff	840.80	kJ/mol	NIST
BasG	811.60	kJ/mol	NIST
ΔfG°	-58.35	kJ/mol	Joback Calculated Property
ΔfH°gas	-202.31	kJ/mol	Relay (1.0) Calculated Property
ΔfusH°	10.62	kJ/mol	Joback Calculated Property
ΔvapH°	[33.70; 34.00]	kJ/mol
ΔvapH°	34.00	kJ/mol	NIST
ΔvapH°	33.70	kJ/mol	NIST
IE	9.22 ± 0.05	eV	NIST
log10WS	[0.11; 0.11]
log10WS	0.11		Aq. Solubility Prediction
log10WS	0.11		Estimated Solubility
logPoct/wat	1.185		Crippen Calculated Property
McVol	76.320	ml/mol	McGowan Calculated Property
Pc	3757.63 ± 68.94	kPa	NIST
Inp	[661.00; 682.00]
Inp	661.00		NIST
Inp	669.00		NIST
Inp	664.00		NIST
Inp	678.00		NIST
Inp	663.00		NIST
Inp	674.00		NIST
Inp	682.00		NIST
Inp	664.00		NIST
Inp	663.00		NIST
I	[876.00; 951.00]
I	925.00		NIST
I	935.00		NIST
I	876.00		NIST
I	876.00		NIST
I	951.00		NIST
I	925.00		NIST
Tboil	[338.15; 359.65]	K
Tboil	353.20	K	NIST
Tboil	352.65 ± 2.00	K	NIST
Tboil	353.10 ± 0.30	K	NIST
Tboil	353.15 ± 1.00	K	NIST
Tboil	359.65 ± 1.00	K	NIST
Tboil	Outlier 338.15 ± 2.00	K	NIST
Tc	537.00 ± 2.00	K	NIST
Tfus	137.05 ± 0.40	K	NIST
Vc	0.267 ± 0.005	m3/kmol	NIST

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[153.50; 166.20]	J/mol×K	[288.15; 323.15]
Cp,liquid	153.50	J/mol×K	288.15	Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Dimethyl Sulfoxide + Tetrahydropyran and + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
Cp,liquid	155.30	J/mol×K	293.15	Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Dimethyl Sulfoxide + Tetrahydropyran and + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
Cp,liquid	155.30	J/mol×K	293.15	Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Poly(ethylene glycols) + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
Cp,liquid	156.90	J/mol×K	298.15	Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Dimethyl Sulfoxide + Tetrahydropyran and + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
Cp,liquid	158.70	J/mol×K	303.15	Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Dimethyl Sulfoxide + Tetrahydropyran and + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
Cp,liquid	158.60	J/mol×K	303.15	Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Poly(ethylene glycols) + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
Cp,liquid	160.20	J/mol×K	308.15	Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Dimethyl Sulfoxide + Tetrahydropyran and + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
Cp,liquid	162.10	J/mol×K	313.15	Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Dimethyl Sulfoxide + Tetrahydropyran and + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
Cp,liquid	162.10	J/mol×K	313.15	Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Poly(ethylene glycols) + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
Cp,liquid	164.20	J/mol×K	318.15	Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Dimethyl Sulfoxide + Tetrahydropyran and + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
Cp,liquid	166.20	J/mol×K	323.15	Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Dimethyl Sulfoxide + Tetrahydropyran and + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
η	[0.0004088; 0.0005618]	Pa×s	[283.15; 313.15]
η	0.0005618	Pa×s	283.15	Excess Enthalpy, Density, Speed of Sound, and Viscosity for 2-Methyltetrahydrofuran + 1-Butanol at (283.15, 298.15, and, 313.15) K
η	0.0004776	Pa×s	298.15	Excess Enthalpy, Density, Speed of Sound, and Viscosity for 2-Methyltetrahydrofuran + 1-Butanol at (283.15, 298.15, and, 313.15) K
η	0.0004088	Pa×s	313.15	Excess Enthalpy, Density, Speed of Sound, and Viscosity for 2-Methyltetrahydrofuran + 1-Butanol at (283.15, 298.15, and, 313.15) K
ν	[0.0000005; 0.0000006]	m2/s	[298.15; 313.15]
ν	0.0000006	m2/s	298.15	Viscosities of Binary Mixtures of Isomeric Butanols or Isomeric Chlorobutanes with 2-Methyltetrahydrofuran
ν	0.0000005	m2/s	313.15	Viscosities of Binary Mixtures of Isomeric Butanols or Isomeric Chlorobutanes with 2-Methyltetrahydrofuran
Pvap	[4.93; 21.69]	kPa	[279.00; 310.11]
Pvap	4.93	kPa	279.00	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	4.93	kPa	279.01	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	5.60	kPa	281.41	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	5.63	kPa	281.44	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	6.57	kPa	284.34	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	7.83	kPa	287.83	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	7.85	kPa	287.84	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	9.26	kPa	291.17	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	11.65	kPa	295.94	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	13.37	kPa	298.94	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	15.76	kPa	302.62	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	18.28	kPa	306.05	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	21.69	kPa	310.11	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
n0	[1.40280; 1.40299]		[298.00; 298.15]
n0	1.40299		298.00	Quaternary and ternary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + acetic acid + water between 298 and 343 K
n0	1.40280		298.15	Ternary and binary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + water between 298 and 343 K
n0	1.40287		298.15	Thermophysical properties of the binary mixtures of 2-methyl-tetrahydrofuran with benzene and halobenzenes
ρl	[848.10; 855.00]	kg/m3	[293.15; 298.15]
ρl	855.00	kg/m3	293.15	Isothermal Vapor-Liquid Equilibrium Data for the Binary Systems Consisting of 1,1,2,3,3,3-Hexafluoro-1-propene and Either Methylcyclohexane, Cyclohexane, n-Hexane, 2-Methyltetrahydrofuran, or 2,2,3,3,4,4,4-Heptafluoro-1-butanol
ρl	851.60	kg/m3	295.00	High-pressure vapor-liquid equilibria of the second generation biofuel blends (2-methylfuran + iso-octane) and (2-methyltetrahydrofuran + di-n-butyl ether): Experiments and PCP-SAFT modeling
ρl	848.10	kg/m3	298.15	Excess molar enthalpies of the ternary mixtures: {tetrahydrofuran or 2-methyltetrahydrofuran + methyl tert-butyl ether + n-dodecane} at the temperature 298.15 K
ρl	848.10	kg/m3	298.15	Excess molar enthalpies of the ternary mixtures: (tetrahydrofuran or 2-methyltetrahydrofuran + methyl tert-butyl ether + n-octane) at the temperature 298.15 K
ρl	848.10	kg/m3	298.15	Excess molar enthalpies of the ternary mixtures (1-hexene + tetrahydrofuran or 2-methyltetrahydrofuran + methyl tert-butyl ether) at the temperature 298.15K.
ρl	849.20	kg/m3	298.15	Thermodynamic study of 2-methyl-tetrahydrofuran with isomeric chlorobutanes
ρl	849.40	kg/m3	298.15	Study of the Surface Tension of Chlorocyclohexane or Bromocyclohexane with Some Cyclic Ethers

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[95.69; 280.10]	J/mol×K	[273.00; 1000.00]	Joback Predicted correlation
Equation			Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is Cp,gas in J/mol×K, T in K
Coefficient A			-4.48200e+01
Coefficient B			6.07520e-01
Coefficient C			-3.61700e-04
Coefficient D			7.91000e-08
Coefficient E			0.00000e+00
Temperature range, min.			273.00
Temperature range, max.			1000.00
Cp,gas	95.69	J/mol×K	273.00	Calculated Property
Cp,gas	128.34	J/mol×K	353.78	Calculated Property
Cp,gas	157.37	J/mol×K	434.56	Calculated Property
Cp,gas	183.02	J/mol×K	515.33	Calculated Property
Cp,gas	205.56	J/mol×K	596.11	Calculated Property
Cp,gas	225.21	J/mol×K	676.89	Calculated Property
Cp,gas	242.24	J/mol×K	757.67	Calculated Property
Cp,gas	256.90	J/mol×K	838.44	Calculated Property
Cp,gas	269.44	J/mol×K	919.22	Calculated Property
Cp,gas	280.10	J/mol×K	1000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 202.64]	kPa	[258.70; 374.84]	The Yaws Handbook of Vapor Pressure
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.47976e+01
Coefficient B			-3.18218e+03
Coefficient C			-3.93870e+01
Temperature range, min.			258.70
Temperature range, max.			374.84
Pvap	1.33	kPa	258.70	Calculated Property
Pvap	2.99	kPa	271.60	Calculated Property
Pvap	6.14	kPa	284.51	Calculated Property
Pvap	11.76	kPa	297.41	Calculated Property
Pvap	21.16	kPa	310.32	Calculated Property
Pvap	36.10	kPa	323.22	Calculated Property
Pvap	58.78	kPa	336.13	Calculated Property
Pvap	91.90	kPa	349.03	Calculated Property
Pvap	138.64	kPa	361.94	Calculated Property
Pvap	202.64	kPa	374.84	Calculated Property

Similar Compounds

Find more compounds similar to Furan, tetrahydro-2-methyl-.

Mixtures

• Acetic acid + Water + Furan, tetrahydro-2-methyl-
• Water + Furan, tetrahydro-2-methyl-
• Furfural + Water + Furan, tetrahydro-2-methyl-
• Benzene, fluoro- + Furan, tetrahydro-2-methyl-
• Benzene, chloro- + Furan, tetrahydro-2-methyl-
• Benzene + Furan, tetrahydro-2-methyl-
• Propane, 2-methoxy-2-methyl- + Furan, tetrahydro-2-methyl-
• Dodecane + Propane, 2-methoxy-2-methyl- + Furan, tetrahydro-2-methyl-
• 1-Hexene + Propane, 2-methoxy-2-methyl- + Furan, tetrahydro-2-methyl-
• n-Butyl ether + Furan, tetrahydro-2-methyl-
• Pentane, 2,2,4-trimethyl- + Cyclohexane + Furan, tetrahydro-2-methyl-
• Octane + Propane, 2-methoxy-2-methyl- + Furan, tetrahydro-2-methyl-
• Butane, 2-chloro- + Furan, tetrahydro-2-methyl-
• Propane, 1-chloro-2-methyl- + Furan, tetrahydro-2-methyl-
• Butane, 1-chloro- + Furan, tetrahydro-2-methyl-
• Propane, 2-chloro-2-methyl- + Furan, tetrahydro-2-methyl-
• Propene, hexafluoro- + Furan, tetrahydro-2-methyl-
• 1-Butanol + Furan, tetrahydro-2-methyl-
• Dimethyl Sulfoxide + Furan, tetrahydro-2-methyl-
• 1-Propanol, 2-methyl- + Furan, tetrahydro-2-methyl-

Find more mixtures with Furan, tetrahydro-2-methyl-.

Sources

• Cheméo Relay (1.0)
• Crippen Method
• High-pressure vapor-liquid equilibria of the second generation biofuel blends (2-methylfuran + iso-octane) and (2-methyltetrahydrofuran + di-n-butyl ether): Experiments and PCP-SAFT modeling
• Liquid-liquid equilibrium of 2-methyltetrahydrofuran/water over wide temperature range: Measurements and rigorous regression
• Excess molar enthalpies of the ternary mixtures: (methyl tert-butyl ether or 2-methyltetrahydrofuran + cyclohexane + 2,2,4- trimethylpentane} at the temperature 298.15 K
• Excess molar enthalpies of the ternary mixtures: {tetrahydrofuran or 2-methyltetrahydrofuran + methyl tert-butyl ether + n-dodecane} at the temperature 298.15 K
• Excess molar enthalpies of the ternary mixtures: (tetrahydrofuran or 2-methyltetrahydrofuran + methyl tert-butyl ether + n-octane) at the temperature 298.15 K
• Excess molar enthalpies of the ternary mixtures (1-hexene + tetrahydrofuran or 2-methyltetrahydrofuran + methyl tert-butyl ether) at the temperature 298.15K.
• Ternary and binary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + water between 298 and 343 K
• Quaternary and ternary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + acetic acid + water between 298 and 343 K
• Thermodynamic study of 2-methyl-tetrahydrofuran with isomeric chlorobutanes
• Thermophysical properties of the binary mixtures of 2-methyl-tetrahydrofuran with benzene and halobenzenes
• Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
• Solubility Measurement and Thermodynamic Modeling of N-(4-Methylphenyl-Z-3-chloro-2-(phenylthio)propenamide in 12 Pure Solvents at Temperatures Ranging from 278.15 to 318.15 K
• Isothermal Vapor-Liquid Equilibrium Data for the Binary Systems Consisting of 1,1,2,3,3,3-Hexafluoro-1-propene and Either Methylcyclohexane, Cyclohexane, n-Hexane, 2-Methyltetrahydrofuran, or 2,2,3,3,4,4,4-Heptafluoro-1-butanol
• Viscosities of Binary Mixtures of Isomeric Butanols or Isomeric Chlorobutanes with 2-Methyltetrahydrofuran
• Study of the Surface Tension of Chlorocyclohexane or Bromocyclohexane with Some Cyclic Ethers
• Excess Enthalpy, Density, Speed of Sound, and Viscosity for 2-Methyltetrahydrofuran + 1-Butanol at (283.15, 298.15, and, 313.15) K
• Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Dimethyl Sulfoxide + Tetrahydropyran and + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
• Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Poly(ethylene glycols) + 2-Methyltetrahydrofuran at (293.15, 303.15, and 313.15) K
• Joback Method
• Aqueous Solubility Prediction Method
• Estimated Solubility Method
• McGowan Method
• NIST Webbook
• The Yaws Handbook of Vapor Pressure

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