Mixture of Piperidine + Water

Datasets

1. Activity coefficient
2. Excess molar enthalpy (molar enthalpy
3. ν - Kinematic viscosity, m2/s
4. ρ_l - Mass density, kg/m3 (2)
5. c_sound,fluid - Speed of Sound, m/s
6. γ - Surface tension liquid-gas, N/m
7. Partial molar volume, m3/mol (2)

Activity coefficient of Piperidine (1) [ref]

Operational conditions:

• Mole fraction = 0 (Liquid)
• Pressure, kPa = 101 (Liquid)

Temperature, K - Liquid	Activity coefficient of Piperidine (1) - Liquid
333.15	11.9
343.15	14.7
353.15	17.7
372.60	21.0

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 297.15 (Liquid)

Mole fraction of Water (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0000	0.0000
0.0500	-0.3571
0.0900	-0.5156
0.1500	-0.7535
0.2100	-1.1194
0.2500	-1.4628
0.3000	-1.6753
0.3500	-1.8273
0.4000	-1.9273
0.4500	-1.9885
0.5000	-2.1379
0.5500	-2.225
0.6000	-2.2185
0.6500	-2.1825
0.7000	-2.0704
0.7500	-1.9642
0.9300	-0.9783
0.9600	-0.6637
0.9900	-0.2331
1.0000	0.0000

Kinematic viscosity, m2/s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Piperidine (1) - Liquid	Kinematic viscosity, m2/s - Liquid
293.15	0.0000	9.8990e-07
293.15	0.0055	1.1060e-06
293.15	0.0110	1.2100e-06
293.15	0.0280	1.5020e-06
293.15	0.0573	2.2000e-06
293.15	0.0986	3.5500e-06
293.15	0.1795	5.9360e-06
293.15	0.2672	7.6210e-06
293.15	0.3536	8.0230e-06
293.15	0.4387	7.0360e-06
293.15	0.5225	6.0880e-06
293.15	0.6458	4.4900e-06
293.15	0.8455	2.5980e-06
293.15	1.0000	1.7950e-06
303.15	0.0000	8.1010e-07
303.15	0.0055	8.8170e-07
303.15	0.0110	9.5270e-07
303.15	0.0280	1.2050e-06
303.15	0.0573	1.7410e-06
303.15	0.0986	2.5530e-06
303.15	0.1795	4.0070e-06
303.15	0.2672	5.0580e-06
303.15	0.3536	5.4170e-06
303.15	0.4387	4.9680e-06
303.15	0.5225	4.3710e-06
303.15	0.6458	3.2200e-06
303.15	0.8455	1.9970e-06
303.15	1.0000	1.4880e-06
313.15	0.0000	6.6550e-07
313.15	0.0055	7.1810e-07
313.15	0.0110	7.7230e-07
313.15	0.0280	9.4210e-07
313.15	0.0573	1.3250e-06
313.15	0.0986	1.8810e-06
313.15	0.1795	2.8130e-06
313.15	0.2672	3.4800e-06
313.15	0.3536	3.7050e-06
313.15	0.4387	3.4880e-06
313.15	0.5225	3.1040e-06
313.15	0.6458	2.3330e-06
313.15	0.8455	1.6210e-06
313.15	1.0000	1.2530e-06
323.15	0.0000	5.6100e-07
323.15	0.0055	5.9810e-07
323.15	0.0110	6.3630e-07
323.15	0.0280	8.1250e-07
323.15	0.0573	1.0660e-06
323.15	0.0986	1.4700e-06
323.15	0.1795	2.1390e-06
323.15	0.2672	2.6160e-06
323.15	0.3536	2.6800e-06
323.15	0.4387	2.5260e-06
323.15	0.5225	2.3110e-06
323.15	0.6458	1.8320e-06
323.15	0.8455	1.3150e-06
323.15	1.0000	1.0640e-06

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Water (2) - Liquid	Mass density, kg/m3 - Liquid
283.15	0.0400	873.86
283.15	0.0800	876.89
283.15	0.1200	879.98
283.15	0.1600	883.3
283.15	0.2000	886.61
283.15	0.2500	890.99
283.15	0.3000	895.69
283.15	0.3500	900.62
283.15	0.4000	905.81
283.15	0.4500	911.29
283.15	0.5000	917.02
283.15	0.5500	923.02
283.15	0.6000	929.3
283.15	0.6500	935.92
283.15	0.6990	942.67
283.15	0.7500	950.63
283.15	0.8000	959.15
283.15	0.8400	966.73
283.15	0.8800	975.37
283.15	0.9200	985.13
283.15	0.9400	990.29
283.15	0.9600	994.83
283.15	0.9800	996.89
283.15	0.9600	994.84
283.15	0.9800	996.89
293.15	0.0400	864.63
293.15	0.0800	867.67
293.15	0.1200	870.77
293.15	0.1600	874.08
293.15	0.2000	877.4
293.15	0.2500	881.79
293.15	0.3000	886.48
293.15	0.3500	891.43
293.15	0.4000	896.63
293.15	0.4500	902.14
293.15	0.5000	907.91
293.15	0.5500	913.98
293.15	0.6000	920.34
293.15	0.6500	927.12
293.15	0.6990	933.75
293.15	0.7500	942.23
293.15	0.8000	951.06
293.15	0.8400	958.98
293.15	0.8800	968.08
293.15	0.9200	978.59
293.15	0.9400	984.38
293.15	0.9600	990.13
293.15	0.9800	994.28
293.15	0.9600	990.14
293.15	0.9800	994.3
298.15	0.0400	859.99
298.15	0.0800	863.01
298.15	0.1200	866.12
298.15	0.1600	869.42
298.15	0.2000	872.74
298.15	0.2500	877.13
298.15	0.3000	881.83
298.15	0.3500	886.77
298.15	0.4000	891.98
298.15	0.4500	897.5
298.15	0.5000	903.29
298.15	0.5500	909.4
298.15	0.6000	915.81
298.15	0.6500	922.65
298.15	0.6990	929.21
298.15	0.7500	937.96
298.15	0.8000	946.95
298.15	0.8400	955.04
298.15	0.8800	964.39
298.15	0.9200	975.27
298.15	0.9400	981.34
298.15	0.9600	987.57
298.15	0.9800	992.61
298.15	0.9600	987.59
298.15	0.9800	992.62
303.15	0.0400	855.31
303.15	0.0800	858.33
303.15	0.1200	861.43
303.15	0.1600	864.74
303.15	0.2000	868.05
303.15	0.2500	872.44
303.15	0.3000	877.14
303.15	0.3500	882.08
303.15	0.4000	887.3
303.15	0.4500	892.82
303.15	0.5000	898.64
303.15	0.5500	904.77
303.15	0.6000	911.23
303.15	0.6500	918.13
303.15	0.6990	924.46
303.15	0.7500	933.65
303.15	0.8000	942.8
303.15	0.8400	951.07
303.15	0.8800	960.66
303.15	0.9200	971.91
303.15	0.9400	978.25
303.15	0.9600	984.9
303.15	0.9800	990.69
303.15	0.9600	984.91
303.15	0.9800	990.71
308.15	0.0400	850.61
308.15	0.0800	853.62
308.15	0.1200	856.72
308.15	0.1600	860.02
308.15	0.2000	863.33
308.15	0.2500	867.71
308.15	0.3000	872.42
308.15	0.3500	877.35
308.15	0.4000	882.57
308.15	0.4500	888.11
308.15	0.5000	893.94
308.15	0.5500	900.1
308.15	0.6000	906.61
308.15	0.6500	913.57
308.15	0.6990	920.88
308.15	0.7500	929.29
308.15	0.8000	938.6
308.15	0.8400	947.04
308.15	0.8800	956.88
308.15	0.9200	968.48
308.15	0.9400	975.08
308.15	0.9600	982.11
308.15	0.9800	988.58
308.15	0.9600	982.12
308.15	0.9800	988.6
313.15	0.0400	845.88
313.15	0.0800	848.88
313.15	0.1200	851.97
313.15	0.1600	855.27
313.15	0.2000	858.57
313.15	0.2500	862.95
313.15	0.3000	867.65
313.15	0.3500	872.59
313.15	0.4000	877.81
313.15	0.4500	883.35
313.15	0.5000	889.2
313.15	0.5500	895.39
313.15	0.6000	901.94
313.15	0.6500	908.96
313.15	0.6990	916.41
313.15	0.7500	924.88
313.15	0.8000	934.35
313.15	0.8400	942.97
313.15	0.8800	953.04
313.15	0.9200	964.99
313.15	0.9400	971.83
313.15	0.9600	979.21
313.15	0.9800	986.28
313.15	0.9600	979.22
313.15	0.9800	986.29
318.15	0.0400	841.13
318.15	0.0800	844.11
318.15	0.1200	847.19
318.15	0.1600	850.48
318.15	0.2000	853.78
318.15	0.2500	858.15
318.15	0.3000	862.86
318.15	0.3500	867.78
318.15	0.4000	873.0
318.15	0.4500	878.55
318.15	0.5000	884.42
318.15	0.5500	890.63
318.15	0.6000	897.22
318.15	0.6500	904.3
318.15	0.6990	911.84
318.15	0.7500	920.42
318.15	0.8000	930.04
318.15	0.8400	938.84
318.15	0.8800	949.14
318.15	0.9200	961.43
318.15	0.9400	968.51
318.15	0.9600	976.19
318.15	0.9800	983.8
318.15	0.9800	983.81
323.15	0.0400	836.35
323.15	0.0800	839.32
323.15	0.1200	842.39
323.15	0.1600	845.67
323.15	0.2000	848.96
323.15	0.2500	853.32
323.15	0.3000	858.02
323.15	0.3500	862.94
323.15	0.4000	868.16
323.15	0.4500	873.71
323.15	0.5000	879.59
323.15	0.5500	885.82
323.15	0.6000	892.46
323.15	0.6500	899.6
323.15	0.6990	907.22
323.15	0.7500	915.9
323.15	0.8000	925.68
323.15	0.8400	934.65
323.15	0.8800	945.19
323.15	0.9200	957.8
323.15	0.9400	965.09
323.15	0.9600	973.07
323.15	0.9800	981.16
323.15	0.9600	973.09
323.15	0.9800	981.17
328.15	0.0400	831.54
328.15	0.0800	834.5
328.15	0.1200	837.55
328.15	0.1600	840.82
328.15	0.2000	844.1
328.15	0.2500	848.45
328.15	0.3000	853.15
328.15	0.3500	858.05
328.15	0.4000	863.28
328.15	0.4500	868.83
328.15	0.5000	874.72
328.15	0.5500	880.97
328.15	0.6000	887.64
328.15	0.6500	894.84
328.15	0.6990	902.54
328.15	0.7500	911.33
328.15	0.8000	921.27
328.15	0.8400	930.4
328.15	0.8800	941.16
328.15	0.9200	954.09
328.15	0.9400	961.59
328.15	0.9600	969.85
328.15	0.9800	978.37
328.15	0.9600	969.87
328.15	0.9800	978.39
333.15	0.0400	826.7
333.15	0.0800	829.64
333.15	0.1200	832.68
333.15	0.1600	835.93
333.15	0.2000	839.2
333.15	0.2500	843.54
333.15	0.3000	848.23
333.15	0.3500	853.13
333.15	0.4000	858.35
333.15	0.4500	863.9
333.15	0.5000	869.8
333.15	0.5500	876.07
333.15	0.6000	882.78
333.15	0.6500	890.03
333.15	0.6990	897.81
333.15	0.7500	906.7
333.15	0.8000	916.79
333.15	0.8400	926.09
333.15	0.8800	937.07
333.15	0.9200	950.3
333.15	0.9400	958.01
333.15	0.9600	966.53
333.15	0.9800	975.44
333.15	0.9600	966.55
333.15	0.9800	975.46
338.15	0.0400	821.84
338.15	0.0800	824.75
338.15	0.1200	827.77
338.15	0.1600	831.0
338.15	0.2000	834.26
338.15	0.2500	838.59
338.15	0.3000	843.28
338.15	0.3500	848.16
338.15	0.4000	853.37
338.15	0.4500	858.93
338.15	0.5000	864.84
338.15	0.5500	871.12
338.15	0.6000	877.86
338.15	0.6500	885.16
338.15	0.6990	893.02
338.15	0.7500	902.02
338.15	0.8000	912.26
338.15	0.8400	921.71
338.15	0.8800	932.9
338.15	0.9200	946.44
338.15	0.9400	954.35
338.15	0.9600	963.11
338.15	0.9800	972.39
338.15	0.9600	963.12
338.15	0.9800	972.4
343.15	0.0400	816.94
343.15	0.0800	819.83
343.15	0.1200	822.82
343.15	0.1600	826.04
343.15	0.2000	829.29
343.15	0.2500	833.61
343.15	0.3000	838.27
343.15	0.3500	843.15
343.15	0.4000	848.35
343.15	0.4500	853.91
343.15	0.5000	859.82
343.15	0.5500	866.13
343.15	0.6000	872.89
343.15	0.6500	880.24
343.15	0.6990	888.17
343.15	0.7500	897.28
343.15	0.8000	907.66
343.15	0.8400	917.28
343.15	0.8800	928.67
343.15	0.9200	942.5
343.15	0.9400	950.59
343.15	0.9600	959.59
343.15	0.9800	969.2
343.15	0.9600	959.61
343.15	0.9800	969.22
348.15	0.0400	812.02
348.15	0.0800	814.88
348.15	0.1200	817.86
348.15	0.1600	821.07
348.15	0.2000	824.27
348.15	0.2500	828.58
348.15	0.3000	833.23
348.15	0.3500	838.09
348.15	0.4000	843.29
348.15	0.4500	848.84
348.15	0.5000	854.75
348.15	0.5500	861.08
348.15	0.6000	867.87
348.15	0.6500	875.26
348.15	0.6990	883.26
348.15	0.7500	892.47
348.15	0.8000	903.0
348.15	0.8400	912.77
348.15	0.8800	924.38
348.15	0.9200	938.48
348.15	0.9400	946.76
348.15	0.9600	955.99
348.15	0.9800	965.91
348.15	0.9600	956.0
348.15	0.9800	965.93

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Piperidine (1) - Liquid	Mass density, kg/m3 - Liquid
293.15	0.0000	998.21
293.15	0.0055	997.07
293.15	0.0110	995.89
293.15	0.0280	992.43
293.15	0.0573	985.56
293.15	0.0986	974.58
293.15	0.1795	955.67
293.15	0.2672	940.18
293.15	0.3536	927.85
293.15	0.4387	917.5
293.15	0.5225	906.51
293.15	0.6458	892.99
293.15	0.8454	875.08
293.15	1.0000	863.81
303.15	0.0000	995.65
303.15	0.0055	994.34
303.15	0.0110	992.89
303.15	0.0280	987.87
303.15	0.0573	979.56
303.15	0.0986	967.57
303.15	0.1795	947.6
303.15	0.2672	931.55
303.15	0.3536	918.89
303.15	0.4387	908.0
303.15	0.5225	897.28
303.15	0.6458	883.65
303.15	0.8454	865.74
303.15	1.0000	854.5
313.15	0.0000	992.21
313.15	0.0055	990.68
313.15	0.0110	989.03
313.15	0.0280	982.66
313.15	0.0573	973.25
313.15	0.0986	960.35
313.15	0.1795	939.32
313.15	0.2672	922.71
313.15	0.3536	909.73
313.15	0.4387	899.0
313.15	0.5225	887.84
313.15	0.6458	874.16
313.15	0.8454	856.27
313.15	1.0000	845.08
323.15	0.0000	988.02
323.15	0.0055	986.17
323.15	0.0110	984.42
323.15	0.0280	976.92
323.15	0.0573	966.6
323.15	0.0986	952.86
323.15	0.1795	930.84
323.15	0.2672	913.66
323.15	0.3536	900.37
323.15	0.4387	889.0
323.15	0.5225	878.22
323.15	0.6458	864.51
323.15	0.8454	846.67
323.15	1.0000	835.56

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Piperidine (1) - Liquid	Speed of sound, m/s - Liquid
293.00	0.0000	1482.5
293.00	0.0060	1506.5
293.00	0.0110	1531.1
293.00	0.0280	1590.1
293.00	0.0570	1596.3
293.00	0.0990	1593.6
293.00	0.1800	1575.4
293.00	0.2670	1550.2
293.00	0.3540	1525.1
293.00	0.4390	1499.8
293.00	0.5230	1477.0
293.00	0.6460	1445.3
293.00	0.8460	1406.2
293.00	1.0000	1384.4
303.00	0.0000	1509.2
303.00	0.0060	1528.7
303.00	0.0110	1548.7
303.00	0.0280	1588.3
303.00	0.0570	1587.1
303.00	0.0990	1576.5
303.00	0.1800	1547.9
303.00	0.2670	1517.2
303.00	0.3540	1489.1
303.00	0.4390	1461.1
303.00	0.5230	1438.0
303.00	0.6460	1405.2
303.00	0.8460	1365.1
303.00	1.0000	1342.3
313.00	0.0000	1529.0
313.00	0.0060	1544.8
313.00	0.0110	1560.4
313.00	0.0280	1584.5
313.00	0.0570	1576.0
313.00	0.0990	1557.5
313.00	0.1800	1519.2
313.00	0.2670	1483.5
313.00	0.3540	1452.5
313.00	0.4390	1424.0
313.00	0.5230	1398.6
313.00	0.6460	1364.8
313.00	0.8460	1323.6
313.00	1.0000	1299.9
323.00	0.0000	1542.6
323.00	0.0060	1555.1
323.00	0.0110	1566.8
323.00	0.0280	1578.3
323.00	0.0570	1562.7
323.00	0.0990	1536.6
323.00	0.1800	1489.3
323.00	0.2670	1449.0
323.00	0.3540	1415.4
323.00	0.4390	1384.9
323.00	0.5230	1358.9
323.00	0.6460	1324.2
323.00	0.8460	1282.0
323.00	1.0000	1257.4

Surface tension liquid-gas, N/m [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Piperidine (1) - Liquid	Surface tension liquid-gas, N/m - Liquid
293.15	0.0000	0.0727
293.15	0.0076	0.0573
293.15	0.0130	0.0438
293.15	0.0228	0.0386
293.15	0.0458	0.0378
293.15	0.0920	0.0354
293.15	0.1542	0.0343
293.15	0.2672	0.0339
293.15	0.3780	0.0333
293.15	0.5657	0.0314
293.15	0.7524	0.0310
293.15	1.0000	0.0301
298.15	0.0000	0.0721
298.15	0.0076	0.0568
298.15	0.0130	0.0436
298.15	0.0228	0.0383
298.15	0.0458	0.0372
298.15	0.0920	0.0350
298.15	0.1542	0.0340
298.15	0.2672	0.0334
298.15	0.3780	0.0328
298.15	0.5657	0.0312
298.15	0.7524	0.0304
298.15	1.0000	0.0296
303.15	0.0000	0.0713
303.15	0.0076	0.0565
303.15	0.0130	0.0433
303.15	0.0228	0.0380
303.15	0.0458	0.0366
303.15	0.0920	0.0345
303.15	0.1542	0.0337
303.15	0.2672	0.0329
303.15	0.3780	0.0322
303.15	0.5657	0.0309
303.15	0.7524	0.0298
303.15	1.0000	0.0291
313.15	0.0000	0.0693
313.15	0.0076	0.0556
313.15	0.0130	0.0416
313.15	0.0228	0.0374
313.15	0.0458	0.0358
313.15	0.0920	0.0337
313.15	0.1542	0.0327
313.15	0.2672	0.0321
313.15	0.3780	0.0314
313.15	0.5657	0.0300
313.15	0.7524	0.0290
313.15	1.0000	0.0279
323.15	0.0000	0.0679
323.15	0.0076	0.0546
323.15	0.0130	0.0414
323.15	0.0228	0.0372
323.15	0.0458	0.0344
323.15	0.0920	0.0326
323.15	0.1542	0.0318
323.15	0.2672	0.0313
323.15	0.3780	0.0304
323.15	0.5657	0.0292
323.15	0.7524	0.0281
323.15	1.0000	0.0270

Partial molar volume, m3/mol of Piperidine (1) [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Partial molar volume, m3/mol of Piperidine (1) - Liquid
294.75	0.0001
305.65	0.0001
315.35	0.0001

Partial molar volume, m3/mol of Water (2) [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Partial molar volume, m3/mol of Water (2) - Liquid
294.75	9.0600e-06
305.65	9.0700e-06
315.35	9.2900e-06

Sources

• Temperature dependences of limiting activity coefficients and Henry s law constants for N-methylpyrrolidone, pyridine, and piperidine in water
• Thermodynamic properties of aqueous solutions of pyridine and piperidine
• Volumetric properties of (piperidine + water) binary system: Measurements and modeling
• Surface Behavior of Aqueous Solutions of Pyrrolidine and Piperidine
• Densities and Viscosities of Aqueous Solutions of Pyrrolidine and Piperidine from (20 to 50) deg C
• Speed of sound and isentropic compressibility of aqueous solutions of pyrrolidine and piperidine

Note: These property values are available through the Cheméo API. A free account gives you an access key.