Chemical Properties of Piperidine (CAS 110-89-4)

InChI

InChI=1S/C5H11N/c1-2-4-6-5-3-1/h6H,1-5H2

InChI Key

NQRYJNQNLNOLGT-UHFFFAOYSA-N

Formula

C5H11N

SMILES

C1CCNCC1

Molecular Weight¹

85.15

CAS

110-89-4

Other Names

• Cypentil
• Hexazane
• Pentamethyleneamine
• Pentamethylenimine
• Piperidin
• Pyridine, hexahydro-
• UN 2401
• azacyclohexane
• cyclopentimine
• hexahydroazine
• hexahydropyridine
• pentamethyleneimine
• perhydroazine
• perhydropyridine

• ω : Acentric Factor.
• PAff : Proton affinity (kJ/mol).
• BasG : Gas basicity (kJ/mol).
• Δ_cH°_liquid : Standard liquid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• μ : Dipole Moment (debye).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fH°_liquid : Liquid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_fusH : Enthalpy of fusion at a given temperature (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• ν : Kinematic viscosity (m²/s).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• NFPA Fire : NFPA Fire Rating.
• NFPA Health : NFPA Health Rating.
• NFPA Safety : NFPA Safety Rating.
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I : Polar retention indices.
• Δ_fusS : Entropy of fusion at a given temperature (J/mol×K).
• S°_liquid : Liquid phase molar entropy at standard conditions (J/mol×K).
• c_sound,fluid : Speed of sound in fluid (m/s).
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_boilr : Boiling point at reduced pressure (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• T_triple : Triple Point Temperature (K).
• V_c : Critical Volume (m³/kmol).
• Z_c : Critical Compressibility.
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	0.2510		KDB
PAff	954.00	kJ/mol	NIST
BasG	921.00	kJ/mol	NIST
ΔcH°liquid	[-3453.20; -3451.50]	kJ/mol
ΔcH°liquid	-3453.20 ± 0.50	kJ/mol	NIST
ΔcH°liquid	-3451.50 ± 2.30	kJ/mol	NIST
μ	1.20	debye	KDB
ΔfG°	111.09	kJ/mol	Joback Calculated Property
ΔfH°gas	[-49.03; -47.15]	kJ/mol
ΔfH°gas	-49.03	kJ/mol	KDB
ΔfH°gas	-47.15 ± 0.63	kJ/mol	NIST
ΔfH°gas	-47.15 ± 0.63	kJ/mol	NIST
ΔfH°liquid	[-88.10; -86.44]	kJ/mol
ΔfH°liquid	-86.44 ± 0.59	kJ/mol	NIST
ΔfH°liquid	-88.10 ± 2.30	kJ/mol	NIST
ΔfusH°	9.06	kJ/mol	Joback Calculated Property
ΔvapH°	[39.30; 41.00]	kJ/mol
ΔvapH°	39.30	kJ/mol	NIST
ΔvapH°	39.30 ± 0.20	kJ/mol	NIST
ΔvapH°	41.00	kJ/mol	NIST
IE	[7.80; 9.15]	eV
IE	8.03 ± 0.11	eV	NIST
IE	8.20 ± 0.05	eV	NIST
IE	8.05 ± 0.05	eV	NIST
IE	7.80	eV	NIST
IE	7.90 ± 0.10	eV	NIST
IE	8.70	eV	NIST
IE	9.15	eV	NIST
IE	8.65 ± 0.10	eV	NIST
IE	8.67	eV	NIST
IE	8.64 ± 0.05	eV	NIST
IE	8.66 ± 0.03	eV	NIST
IE	8.66	eV	NIST
IE	8.64 ± 0.02	eV	NIST
log10WS	1.07		Aq. Solubility Prediction
logPoct/wat	0.760		Crippen Calculated Property
McVol	80.430	ml/mol	McGowan Calculated Property
NFPA Fire	3		KDB
NFPA Health	2		KDB
NFPA Safety	3		KDB
Pc	[4645.75; 4940.00]	kPa
Pc	4940.00	kPa	KDB
Pc	4655.88 ± 202.65	kPa	NIST
Pc	4645.75 ± 202.65	kPa	NIST
Inp	[742.00; 790.00]
Inp	762.00		NIST
Inp	769.00		NIST
Inp	771.00		NIST
Inp	762.00		NIST
Inp	766.00		NIST
Inp	764.00		NIST
Inp	775.00		NIST
Inp	770.00		NIST
Inp	Outlier 742.00		NIST
Inp	751.00		NIST
Inp	761.00		NIST
Inp	790.00		NIST
Inp	775.00		NIST
Inp	767.00		NIST
Inp	750.00		NIST
Inp	755.00		NIST
Inp	755.00		NIST
Inp	782.00		NIST
Inp	790.00		NIST
Inp	790.00		NIST
Inp	775.00		NIST
Inp	767.00		NIST
Inp	790.00		NIST
I	[1042.00; 1125.00]
I	1074.00		NIST
I	1097.00		NIST
I	1115.00		NIST
I	1088.00		NIST
I	1100.00		NIST
I	1125.00		NIST
I	1042.00		NIST
I	1049.00		NIST
I	1042.00		NIST
S°liquid	[209.94; 209.97]	J/mol×K
S°liquid	209.97	J/mol×K	NIST
S°liquid	209.94	J/mol×K	NIST
S°liquid	209.94	J/mol×K	NIST
Tboil	[378.82; 379.70]	K
Tboil	379.37	K	KDB
Tboil	379.20	K	NIST
Tboil	379.15 ± 1.50	K	NIST
Tboil	379.45 ± 0.15	K	NIST
Tboil	379.05 ± 0.15	K	NIST
Tboil	378.90 ± 1.50	K	NIST
Tboil	378.90 ± 0.50	K	NIST
Tboil	379.70 ± 0.50	K	NIST
Tboil	379.55 ± 0.70	K	NIST
Tboil	379.45 ± 0.40	K	NIST
Tboil	379.55 ± 0.30	K	NIST
Tboil	378.95 ± 0.30	K	NIST
Tboil	378.85 ± 0.50	K	NIST
Tboil	379.15 ± 0.60	K	NIST
Tboil	378.82 ± 0.70	K	NIST
Tboil	379.20 ± 1.00	K	NIST
Tboil	379.15 ± 1.50	K	NIST
Tc	[594.00; 594.40]	K
Tc	594.40	K	DIPPR Project 851 - Thirty Years of Vapor-Liquid Critical Point Measurements and Experimental Technique Development
Tc	594.10	K	KDB
Tc	594.10 ± 0.02	K	NIST
Tc	594.00 ± 0.30	K	NIST
Tfus	[256.00; 264.15]	K
Tfus	262.12	K	KDB
Tfus	262.12	K	NIST
Tfus	264.15 ± 1.50	K	NIST
Tfus	262.70 ± 0.60	K	NIST
Tfus	262.40 ± 0.60	K	NIST
Tfus	262.65 ± 0.20	K	NIST
Tfus	261.15 ± 2.00	K	NIST
Tfus	Outlier 256.00 ± 2.00	K	NIST
Ttriple	[262.10; 262.12]	K
Ttriple	262.10 ± 0.03	K	NIST
Ttriple	262.12 ± 0.02	K	NIST
Ttriple	262.12 ± 0.05	K	NIST
Ttriple	262.10 ± 0.03	K	NIST
Ttriple	262.12 ± 0.02	K	NIST
Vc	0.288	m3/kmol	KDB
Zc	0.2880200		KDB

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[170.70; 186.20]	J/mol×K	[290.00; 298.15]
Cp,liquid	186.20	J/mol×K	290.00	NIST
Cp,liquid	170.70	J/mol×K	290.00	NIST
Cp,liquid	182.76	J/mol×K	297.39	NIST
Cp,liquid	181.60	J/mol×K	298.00	NIST
Cp,liquid	179.86	J/mol×K	298.15	NIST
Cp,liquid	179.85	J/mol×K	298.15	NIST
Cp,liquid	179.86	J/mol×K	298.15	NIST
ΔfusH	[14.85; 14.85]	kJ/mol	[262.10; 262.12]
ΔfusH	14.85	kJ/mol	262.10	NIST
ΔfusH	14.85	kJ/mol	262.12	NIST
ΔfusH	14.85	kJ/mol	262.12	NIST
ΔfusH	14.85	kJ/mol	262.12	NIST
ΔvapH	[35.30; 38.60]	kJ/mol	[298.15; 366.00]
ΔvapH	38.60	kJ/mol	298.15	The vaporization enthalpy and vapor pressure of S (+)-methamphetamine at T = 298.15 K by correlation gas chromatography
ΔvapH	36.60	kJ/mol	338.00	NIST
ΔvapH	35.30	kJ/mol	357.00	NIST
ΔvapH	37.60	kJ/mol	366.00	NIST
ν	[0.0000011; 0.0000018]	m2/s	[293.15; 323.15]
ν	0.0000018	m2/s	293.15	Densities and Viscosities of Aqueous Solutions of Pyrrolidine and Piperidine from (20 to 50) deg C
ν	0.0000015	m2/s	303.15	Densities and Viscosities of Aqueous Solutions of Pyrrolidine and Piperidine from (20 to 50) deg C
ν	0.0000013	m2/s	313.15	Densities and Viscosities of Aqueous Solutions of Pyrrolidine and Piperidine from (20 to 50) deg C
ν	0.0000011	m2/s	323.15	Densities and Viscosities of Aqueous Solutions of Pyrrolidine and Piperidine from (20 to 50) deg C
Pvap	[1.75; 10.73]	kPa	[283.64; 318.34]
Pvap	1.75	kPa	283.64	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	2.29	kPa	288.07	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	3.06	kPa	293.12	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	3.13	kPa	293.55	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	3.13	kPa	293.59	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	3.79	kPa	297.05	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	4.68	kPa	300.97	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	5.06	kPa	302.66	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	6.01	kPa	305.98	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	6.05	kPa	306.01	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	8.34	kPa	312.85	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Pvap	10.73	kPa	318.34	Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
ρl	[794.34; 879.98]	kg/m3	[273.15; 363.15]
ρl	879.98	kg/m3	273.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	879.53	kg/m3	273.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	879.08	kg/m3	274.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	878.62	kg/m3	274.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	878.17	kg/m3	275.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	877.71	kg/m3	275.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	877.26	kg/m3	276.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	876.80	kg/m3	276.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	876.35	kg/m3	277.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	875.89	kg/m3	277.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	875.44	kg/m3	278.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	874.98	kg/m3	278.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	874.52	kg/m3	279.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	874.07	kg/m3	279.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	873.61	kg/m3	280.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	873.15	kg/m3	280.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	872.69	kg/m3	281.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	872.24	kg/m3	281.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	871.78	kg/m3	282.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	871.32	kg/m3	282.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	870.86	kg/m3	283.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	870.40	kg/m3	283.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	869.94	kg/m3	284.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	869.49	kg/m3	284.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	869.03	kg/m3	285.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	868.57	kg/m3	285.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	868.11	kg/m3	286.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	867.65	kg/m3	286.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	867.18	kg/m3	287.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	866.72	kg/m3	287.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	866.26	kg/m3	288.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	865.80	kg/m3	288.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	865.34	kg/m3	289.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	864.88	kg/m3	289.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	864.42	kg/m3	290.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	863.96	kg/m3	290.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	863.49	kg/m3	291.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	863.03	kg/m3	291.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	862.57	kg/m3	292.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	862.10	kg/m3	292.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	862.00	kg/m3	293.00	KDB
ρl	861.64	kg/m3	293.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	873.50	kg/m3	293.65	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	861.18	kg/m3	293.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	860.71	kg/m3	294.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	860.25	kg/m3	294.64	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	859.79	kg/m3	295.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	859.32	kg/m3	295.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	867.10	kg/m3	296.05	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	858.86	kg/m3	296.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	858.39	kg/m3	296.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	857.93	kg/m3	297.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	857.46	kg/m3	297.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	857.00	kg/m3	298.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	864.60	kg/m3	298.15	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	856.53	kg/m3	298.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	856.06	kg/m3	299.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	855.60	kg/m3	299.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	856.30	kg/m3	300.05	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	855.13	kg/m3	300.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	854.66	kg/m3	300.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	854.20	kg/m3	301.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	853.73	kg/m3	301.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	853.26	kg/m3	302.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	852.79	kg/m3	302.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	852.40	kg/m3	302.65	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	852.33	kg/m3	303.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	851.86	kg/m3	303.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	851.39	kg/m3	304.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	852.60	kg/m3	304.55	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	850.92	kg/m3	304.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	850.45	kg/m3	305.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	849.98	kg/m3	305.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	849.51	kg/m3	306.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	852.50	kg/m3	306.45	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	849.04	kg/m3	306.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	848.57	kg/m3	307.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	848.10	kg/m3	307.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	847.63	kg/m3	308.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	850.60	kg/m3	308.25	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	847.16	kg/m3	308.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	846.69	kg/m3	309.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	846.22	kg/m3	309.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	845.75	kg/m3	310.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	846.30	kg/m3	310.35	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	845.28	kg/m3	310.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	844.81	kg/m3	311.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	844.33	kg/m3	311.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	843.86	kg/m3	312.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	843.39	kg/m3	312.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	842.92	kg/m3	313.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	842.45	kg/m3	313.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	842.20	kg/m3	313.75	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	841.97	kg/m3	314.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	841.50	kg/m3	314.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	840.80	kg/m3	315.15	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	841.03	kg/m3	315.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	840.54	kg/m3	315.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	840.07	kg/m3	316.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	839.60	kg/m3	316.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	839.12	kg/m3	317.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	837.70	kg/m3	317.35	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	838.64	kg/m3	317.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	837.69	kg/m3	318.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	835.30	kg/m3	319.15	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	837.22	kg/m3	319.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	836.74	kg/m3	319.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	836.27	kg/m3	320.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	835.79	kg/m3	320.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	833.50	kg/m3	321.15	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	835.31	kg/m3	321.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	834.84	kg/m3	321.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	834.36	kg/m3	322.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	833.88	kg/m3	322.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	831.40	kg/m3	323.05	Thermodynamic properties of aqueous solutions of pyridine and piperidine
ρl	833.41	kg/m3	323.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	832.93	kg/m3	323.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	832.45	kg/m3	324.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	831.97	kg/m3	324.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	831.49	kg/m3	325.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	831.02	kg/m3	325.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	830.54	kg/m3	326.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	830.06	kg/m3	326.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	829.58	kg/m3	327.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	829.10	kg/m3	327.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	828.62	kg/m3	328.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	828.14	kg/m3	328.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	827.66	kg/m3	329.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	827.18	kg/m3	329.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	826.70	kg/m3	330.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	826.22	kg/m3	330.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	825.74	kg/m3	331.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	825.25	kg/m3	331.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	824.77	kg/m3	332.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	824.29	kg/m3	332.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	823.81	kg/m3	333.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	823.32	kg/m3	333.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	822.84	kg/m3	334.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	822.36	kg/m3	334.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	821.87	kg/m3	335.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	821.39	kg/m3	335.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	820.91	kg/m3	336.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	820.42	kg/m3	336.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	819.94	kg/m3	337.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	819.45	kg/m3	337.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	818.97	kg/m3	338.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	818.48	kg/m3	338.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	818.00	kg/m3	339.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	817.51	kg/m3	339.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	817.03	kg/m3	340.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	816.54	kg/m3	340.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	816.05	kg/m3	341.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	815.57	kg/m3	341.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	815.08	kg/m3	342.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	814.59	kg/m3	342.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	814.10	kg/m3	343.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	813.62	kg/m3	343.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	813.13	kg/m3	344.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	812.64	kg/m3	344.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	812.15	kg/m3	345.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	811.66	kg/m3	345.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	811.17	kg/m3	346.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	810.68	kg/m3	346.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	810.19	kg/m3	347.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	809.70	kg/m3	347.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	809.21	kg/m3	348.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	808.72	kg/m3	348.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	808.23	kg/m3	349.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	807.74	kg/m3	349.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	807.25	kg/m3	350.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	806.75	kg/m3	350.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	806.26	kg/m3	351.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	805.77	kg/m3	351.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	805.28	kg/m3	352.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	804.78	kg/m3	352.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	804.29	kg/m3	353.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	803.79	kg/m3	353.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	803.30	kg/m3	354.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	802.80	kg/m3	354.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	802.31	kg/m3	355.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	801.81	kg/m3	355.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	801.32	kg/m3	356.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	800.82	kg/m3	356.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	800.33	kg/m3	357.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	799.83	kg/m3	357.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	799.33	kg/m3	358.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	798.83	kg/m3	358.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	798.34	kg/m3	359.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	797.84	kg/m3	359.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	797.34	kg/m3	360.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	796.84	kg/m3	360.66	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	796.34	kg/m3	361.16	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	795.84	kg/m3	361.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	795.34	kg/m3	362.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	794.84	kg/m3	362.65	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ρl	794.34	kg/m3	363.15	Volumetric properties of (piperidine + water) binary system: Measurements and modeling
ΔfusS	[56.64; 56.67]	J/mol×K	[262.12; 262.12]
ΔfusS	56.67	J/mol×K	262.12	NIST
ΔfusS	56.64	J/mol×K	262.12	NIST
ΔfusS	56.67	J/mol×K	262.12	NIST
csound,fluid	[1257.40; 1384.40]	m/s	[293.00; 323.00]
csound,fluid	1384.40	m/s	293.00	Speed of sound and isentropic compressibility of aqueous solutions of pyrrolidine and piperidine
csound,fluid	1342.30	m/s	303.00	Speed of sound and isentropic compressibility of aqueous solutions of pyrrolidine and piperidine
csound,fluid	1299.90	m/s	313.00	Speed of sound and isentropic compressibility of aqueous solutions of pyrrolidine and piperidine
csound,fluid	1257.40	m/s	323.00	Speed of sound and isentropic compressibility of aqueous solutions of pyrrolidine and piperidine
γ	[0.03; 0.03]	N/m	[293.15; 323.15]
γ	0.03	N/m	293.15	Surface Behavior of Aqueous Solutions of Pyrrolidine and Piperidine
γ	0.03	N/m	298.15	Surface Behavior of Aqueous Solutions of Pyrrolidine and Piperidine
γ	0.03	N/m	298.15	Densities, Viscosities, Surface Tensions, and Speeds of Sound of Aqueous Solutions of Piperidine + Pyrrolidine + Water
γ	0.03	N/m	303.15	Surface Behavior of Aqueous Solutions of Pyrrolidine and Piperidine
γ	0.03	N/m	313.15	Surface Behavior of Aqueous Solutions of Pyrrolidine and Piperidine
γ	0.03	N/m	323.15	Surface Behavior of Aqueous Solutions of Pyrrolidine and Piperidine

Pressure Dependent Properties

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[88.28; 286.92]	J/mol×K	[273.00; 1000.00]	Joback Predicted correlation
Equation			Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is Cp,gas in J/mol×K, T in K
Coefficient A			-5.62800e+01
Coefficient B			6.14000e-01
Coefficient C			-3.24000e-04
Coefficient D			5.32000e-08
Coefficient E			0.00000e+00
Temperature range, min.			273.00
Temperature range, max.			1000.00
Cp,gas	88.28	J/mol×K	273.00	Calculated Property
Cp,gas	122.74	J/mol×K	353.78	Calculated Property
Cp,gas	153.72	J/mol×K	434.56	Calculated Property
Cp,gas	181.37	J/mol×K	515.33	Calculated Property
Cp,gas	205.87	J/mol×K	596.11	Calculated Property
Cp,gas	227.38	J/mol×K	676.89	Calculated Property
Cp,gas	246.07	J/mol×K	757.67	Calculated Property
Cp,gas	262.11	J/mol×K	838.44	Calculated Property
Cp,gas	275.67	J/mol×K	919.22	Calculated Property
Cp,gas	286.92	J/mol×K	1000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Pvap	[0.53; 202.63]	kPa	[262.65; 404.57]	The Yaws Handbook of Vapor Pressure
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.44573e+01
Coefficient B			-3.29413e+03
Coefficient C			-4.43940e+01
Temperature range, min.			262.65
Temperature range, max.			404.57
Pvap	0.53	kPa	262.65	Calculated Property
Pvap	1.46	kPa	278.42	Calculated Property
Pvap	3.56	kPa	294.19	Calculated Property
Pvap	7.79	kPa	309.96	Calculated Property
Pvap	15.61	kPa	325.73	Calculated Property
Pvap	29.07	kPa	341.49	Calculated Property
Pvap	50.83	kPa	357.26	Calculated Property
Pvap	84.24	kPa	373.03	Calculated Property
Pvap	133.30	kPa	388.80	Calculated Property
Pvap	202.63	kPa	404.57	Calculated Property
Pvap	[0.52; 4743.85]	kPa	[262.65; 594.05]	KDB Vapor Pressure Data
Equation			ln(Y) = A + B/T + C·ln(T) + D·T² + E/T² Y is Pvap in kPa, T in K
Coefficient A			5.93402e+01
Coefficient B			-6.31943e+03
Coefficient C			-6.49354e+00
Coefficient D			3.50313e-06
Coefficient E			0.00000e+00
Temperature range, min.			262.65
Temperature range, max.			594.05
Pvap	0.52	kPa	262.65	Calculated Property
Pvap	4.60	kPa	299.47	Calculated Property
Pvap	23.71	kPa	336.29	Calculated Property
Pvap	84.52	kPa	373.12	Calculated Property
Pvap	232.34	kPa	409.94	Calculated Property
Pvap	528.86	kPa	446.76	Calculated Property
Pvap	1046.82	kPa	483.58	Calculated Property
Pvap	1865.23	kPa	520.41	Calculated Property
Pvap	3067.60	kPa	557.23	Calculated Property
Pvap	4743.85	kPa	594.05	Calculated Property
Pvap	[9.58; 270.08]	kPa	[315.51; 416.76]	NIST
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.37738e+01
Coefficient B			-2.85423e+03
Coefficient C			-6.76220e+01
Reference			Osborn and Douslin, 1968
Temperature range, min.			315.51
Temperature range, max.			416.76
Pvap	9.58	kPa	315.51	Calculated Property
Pvap	15.79	kPa	326.76	Calculated Property
Pvap	24.97	kPa	338.01	Calculated Property
Pvap	38.07	kPa	349.26	Calculated Property
Pvap	56.19	kPa	360.51	Calculated Property
Pvap	80.57	kPa	371.76	Calculated Property
Pvap	112.61	kPa	383.01	Calculated Property
Pvap	153.79	kPa	394.26	Calculated Property
Pvap	205.72	kPa	405.51	Calculated Property
Pvap	270.08	kPa	416.76	Calculated Property

Similar Compounds

Find more compounds similar to Piperidine.

Mixtures

• Piperidine + Water
• Piperidine + Heptane
• Piperidine + Methyl Alcohol
• Morpholine + Piperidine
• Morpholine + Piperidine + Cyclohexane
• Piperidine + 1,4-Dioxane + Cyclohexane
• Piperidine + 1,4-Dioxane
• Pyrrolidine + Piperidine
• Pyrrolidine + Piperidine + Water
• Piperidine + Cyclohexane
• Tetrahydropyran + Piperidine
• Tetrahydropyran + Piperidine + Cyclohexane

Sources

• KDB Vapor Pressure Data
• Crippen Method
• Temperature dependences of limiting activity coefficients and Henry s law constants for N-methylpyrrolidone, pyridine, and piperidine in water
• Thermodynamic properties of aqueous solutions of pyridine and piperidine
• Thermodynamic study of heptane + amine mixtures. V. Excess and solvation Gibbs energies
• Volumetric properties of (piperidine + water) binary system: Measurements and modeling
• The vaporization enthalpy and vapor pressure of S (+)-methamphetamine at T = 298.15 K by correlation gas chromatography
• Thermodynamic functions of hydrogen bonding of amines in methanol: head space analysis and solution calorimetry
• Examination of hydrogen-bonding interactions between dissolved solutes and alkylbenzene solvents based on Abraham model correlations derived from measured enthalpies of solvation
• Enthalpies of solution and enthalpies of solvation of organic solutes in ethylene glycol at 298.15 K: Prediction and analysis of intermolecular interaction contributions
• Analysis of solute-pyridine intermolecular interactions based on experimental enthalpies of solution and enthalpies of solvation of solutes dissolved in pyridine
• Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
• DIPPR Project 851 - Thirty Years of Vapor-Liquid Critical Point Measurements and Experimental Technique Development
• Surface Behavior of Aqueous Solutions of Pyrrolidine and Piperidine
• Densities and Viscosities of Aqueous Solutions of Pyrrolidine and Piperidine from (20 to 50) deg C
• Speed of sound and isentropic compressibility of aqueous solutions of pyrrolidine and piperidine
• Experimental Measurements and Correlations of Excess Molar Enthalpies for the Binary and Ternary Mixtures of (Cyclohexane, 1,4-Dioxane and Piperidine) or (Cyclohexane, Morpholine and Piperidine) at 308.15 K and Atmospheric Pressure
• Densities, Viscosities, Surface Tensions, and Speeds of Sound of Aqueous Solutions of Piperidine + Pyrrolidine + Water
• Excess Molar Enthalpies for the Binary and Ternary Mixtures of Cyclohexane, Tetrahydropyran, and Piperidine at 308.15 K and Atmospheric Pressure: Experimental Measurements and Correlations
• Joback Method
• KDB
• Aqueous Solubility Prediction Method
• McGowan Method
• NIST Webbook
• The Yaws Handbook of Vapor Pressure

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