Chemical Properties of Silane, tetrafluoro- (CAS 7783-61-1)

Silane, tetrafluoro-

InChI
InChI=1S/F4Si/c1-5(2,3)4
InChI Key
ABTOQLMXBSRXSM-UHFFFAOYSA-N
Formula
SiF4
SMILES
F[Si](F)(F)F
Molecular Weight1
104.08
CAS
7783-61-1
Other Names
  • SiF4
  • Silicon fluoride
  • Silicon fluoride (SiF4)
  • UN 1859
  • silicon tetrafluoride
  • tetrafluorosilane
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Physical Properties

Property Value Unit Source
PAff [492.00; 502.90] kJ/mol Show Hide
PAff 502.90 kJ/mol NIST
PAff 492.00 ± 8.40 kJ/mol NIST
PAff 492.90 ± 8.40 kJ/mol NIST
BasG [465.70; 476.60] kJ/mol Show Hide
BasG 476.60 kJ/mol NIST
BasG 465.70 ± 8.40 kJ/mol NIST
BasG 466.50 ± 8.40 kJ/mol NIST
SProt [21.00; 21.00] J/mol×K Show Hide
SProt 21.00 J/mol×K NIST
SProt 21.00 J/mol×K NIST
ΔfH°gas -1615.00 ± 0.80 kJ/mol NIST
ΔfH°(+) ion -134.00 ± 7.10 kJ/mol NIST
IE [15.00; 16.50] eV Show Hide
IE 15.24 ± 0.14 eV NIST
IE 15.29 ± 0.08 eV NIST
IE 15.19 eV NIST
IE 15.00 ± 1.00 eV NIST
IE 15.70 eV NIST
IE 15.81 ± 0.02 eV NIST
IE 15.92 eV NIST
IE 15.70 ± 0.10 eV NIST
IE 16.40 eV NIST
IE 16.50 eV NIST
IE 16.45 eV NIST
IE 16.46 ± 0.04 eV NIST
IE 15.19 eV NIST
logPoct/wat 1.300 Crippen Calculated Property
Pc 3714.57 ± 5.06 kPa NIST
S°gas,1 bar 282.76 ± 0.50 J/mol×K NIST
Tboil 187.00 K NIST
Tc 259.00 ± 0.02 K NIST

Cheméo can also estimate Normal melting (fusion) point, Critical Volume, Enthalpy of vaporization at standard conditions, Standard Gibbs free energy of formation, Acentric Factor, Log10 of Water solubility in mol/l for this compound, but they fall outside the models' validated range, so they are not shown here. Open the prediction tool to compute them on demand.

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
ΔsubH 25.80 kJ/mol 165.50 NIST

Datasets

Kinematic viscosity, m2/s

Fixed Measured
Temperature, K - Gas Pressure, kPa - Gas Kinematic viscosity, m2/s - Gas
215.00 198.15 1.0560e-06
215.00 283.66 7.3200e-07
215.00 378.50 5.2400e-07
215.00 461.43 4.3700e-07
215.00 551.52 3.6020e-07
215.00 649.39 3.0310e-07
215.00 746.64 2.5900e-07
230.00 271.49 8.8800e-07
230.00 424.62 5.6300e-07
230.00 578.31 3.9850e-07
230.00 742.99 2.8350e-07
230.00 897.83 2.4990e-07
230.00 1088.35 2.9000e-07
230.00 1250.99 1.7580e-07
245.00 248.32 1.0930e-06
245.00 393.67 6.6020e-07
245.00 542.46 4.9200e-07
245.00 703.75 3.6950e-07
245.00 873.41 2.9490e-07
245.00 1034.47 2.4570e-07
245.00 1220.05 2.0780e-07
245.00 1434.33 1.7380e-07
245.00 1599.80 1.5510e-07
245.00 1777.83 1.3990e-07
245.00 1958.48 1.2460e-07
260.00 206.14 1.3380e-06
260.00 410.06 7.4900e-07
260.00 617.98 4.8200e-07
260.00 830.76 3.5430e-07
260.00 1047.12 2.7410e-07
260.00 1252.04 2.2990e-07
260.00 1498.23 1.9110e-07
260.00 1794.29 1.5750e-07
260.00 2026.63 1.3920e-07
260.00 2282.25 1.2470e-07
260.00 2541.67 1.0970e-07
274.58 524.86 6.3600e-07
274.58 642.96 5.0900e-07
274.58 744.26 4.2440e-07
274.58 845.26 3.8840e-07
274.58 947.16 3.4790e-07
274.58 1048.29 3.1100e-07
274.58 1150.31 2.8600e-07
274.58 1252.18 2.5940e-07
274.58 1353.82 2.4220e-07
274.58 1454.61 2.2790e-07
274.58 1556.05 2.0930e-07
274.58 1657.90 2.0060e-07
274.58 1764.42 1.8190e-07
274.58 1878.13 1.7040e-07
274.58 1998.50 1.6390e-07
274.58 2141.86 1.5180e-07
274.58 2244.21 1.4240e-07
274.58 2354.11 1.3610e-07
274.58 2474.02 1.3050e-07
274.58 2776.62 1.1500e-07
274.58 2951.29 1.0760e-07
300.00 386.04 1.1400e-06
300.00 581.57 7.4200e-07
300.00 775.29 5.2000e-07
300.00 975.51 4.0400e-07
300.00 1173.93 3.2470e-07
300.00 1443.44 2.6900e-07
300.00 1648.68 2.3740e-07
300.00 1872.11 2.1070e-07
300.00 2157.89 1.7100e-07
300.00 2526.14 1.5300e-07
324.96 582.54 8.8400e-07
324.96 731.36 6.0000e-07
324.96 1070.79 4.2200e-07
324.96 1257.38 3.6000e-07
324.96 1487.57 3.1000e-07
324.96 1769.00 2.5860e-07
324.96 1936.20 2.4170e-07
324.96 2114.40 2.1100e-07
324.96 2322.23 1.9890e-07
324.96 2540.96 1.8430e-07
Reference

Correlations

Property Value Unit Temperature (K) Source
Cp,gas [73.59; 102.31] J/mol×K [298.00; 1000.00] NIST Show Hide
EquationY = A + B·t + C·t² + D·t³ + E/t², t = T/1000
Y is Cp,gas in J/mol×K, T in K
Coefficient A4.29860e+01
Coefficient B1.59280e+02
Coefficient C-1.51137e+02
Coefficient D5.16063e+01
Coefficient E-4.27040e-01
ReferenceChase, 1998
Temperature range, min.298.00
Temperature range, max.1000.00
Cp,gas 73.59 J/mol×K 298.00 Calculated Property
Cp,gas 81.23 J/mol×K 376.00 Calculated Property
Cp,gas 86.90 J/mol×K 454.00 Calculated Property
Cp,gas 91.21 J/mol×K 532.00 Calculated Property
Cp,gas 94.47 J/mol×K 610.00 Calculated Property
Cp,gas 96.93 J/mol×K 688.00 Calculated Property
Cp,gas 98.78 J/mol×K 766.00 Calculated Property
Cp,gas 100.18 J/mol×K 844.00 Calculated Property
Cp,gas 101.31 J/mol×K 922.00 Calculated Property
Cp,gas 102.31 J/mol×K 1000.00 Calculated Property
Cp,gas [102.26; 107.92] J/mol×K [1000.00; 6000.00] NIST Show Hide
EquationY = A + B·t + C·t² + D·t³ + E/t², t = T/1000
Y is Cp,gas in J/mol×K, T in K
Coefficient A1.07272e+02
Coefficient B4.71612e-01
Coefficient C-9.79600e-02
Coefficient D6.92100e-03
Coefficient E-5.38887e+00
ReferenceChase, 1998
Temperature range, min.1000.00
Temperature range, max.6000.00
Cp,gas 102.26 J/mol×K 1000.00 Calculated Property
Cp,gas 105.57 J/mol×K 1555.56 Calculated Property
Cp,gas 106.69 J/mol×K 2111.11 Calculated Property
Cp,gas 107.21 J/mol×K 2666.67 Calculated Property
Cp,gas 107.49 J/mol×K 3222.22 Calculated Property
Cp,gas 107.65 J/mol×K 3777.78 Calculated Property
Cp,gas 107.75 J/mol×K 4333.33 Calculated Property
Cp,gas 107.82 J/mol×K 4888.89 Calculated Property
Cp,gas 107.87 J/mol×K 5444.44 Calculated Property
Cp,gas 107.92 J/mol×K 6000.00 Calculated Property
Property Value Unit Temperature (K) Source
Pvap [0.01; 3672.24] kPa [117.15; 259.00] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.34694e+01
Coefficient B-1.05775e+03
Coefficient C-5.79400e+01
Temperature range, min.117.15
Temperature range, max.259.00
Pvap 0.01 kPa 117.15 Calculated Property
Pvap 0.53 kPa 132.91 Calculated Property
Pvap 6.12 kPa 148.67 Calculated Property
Pvap 34.36 kPa 164.43 Calculated Property
Pvap 123.64 kPa 180.19 Calculated Property
Pvap 332.10 kPa 195.96 Calculated Property
Pvap 728.47 kPa 211.72 Calculated Property
Pvap 1380.78 kPa 227.48 Calculated Property
Pvap 2347.44 kPa 243.24 Calculated Property
Pvap 3672.24 kPa 259.00 Calculated Property
Pvap [20.97; 234.18] kPa [163.16; 186.91] NIST Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A2.38954e+01
Coefficient B-3.78475e+03
Coefficient C1.83440e+01
ReferencePace and Mosser, 1963
Temperature range, min.163.16
Temperature range, max.186.91
Pvap 20.97 kPa 163.16 Calculated Property
Pvap 28.28 kPa 165.80 Calculated Property
Pvap 37.81 kPa 168.44 Calculated Property
Pvap 50.14 kPa 171.08 Calculated Property
Pvap 65.98 kPa 173.72 Calculated Property
Pvap 86.18 kPa 176.35 Calculated Property
Pvap 111.76 kPa 178.99 Calculated Property
Pvap 143.94 kPa 181.63 Calculated Property
Pvap 184.18 kPa 184.27 Calculated Property
Pvap 234.18 kPa 186.91 Calculated Property
Pvap [0.13; 97.57] kPa [129.00; 178.30] NIST Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A2.09760e+01
Coefficient B-2.81045e+03
Coefficient C-6.88400e+00
ReferenceStull, 1947
Temperature range, min.129.00
Temperature range, max.178.30
Pvap 0.13 kPa 129.00 Calculated Property
Pvap 0.35 kPa 134.48 Calculated Property
Pvap 0.87 kPa 139.96 Calculated Property
Pvap 2.00 kPa 145.43 Calculated Property
Pvap 4.32 kPa 150.91 Calculated Property
Pvap 8.83 kPa 156.39 Calculated Property
Pvap 17.15 kPa 161.87 Calculated Property
Pvap 31.85 kPa 167.34 Calculated Property
Pvap 56.79 kPa 172.82 Calculated Property
Pvap 97.57 kPa 178.30 Calculated Property

Similar Compounds

Difluorooxosilane. silicon fluoride. F2Si=CH2. Silane, trifluoromethyl-. Bromine monoxide. Difluorosilane thiol. Trichlorofluorosilane. Digallium monotelluride. Selenium difluoride. Hypobromous acid. Sodium nitrate. Strontium monohydroxide. Nitrogen dioxide. Nitrogen oxide anion. Mercury, chloromethyl-.

Find more compounds similar to Silane, tetrafluoro-.

Sources

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