Chemical Properties of Trichloroethylene (CAS 79-01-6)

Trichloroethylene

InChI
InChI=1S/C2HCl3/c3-1-2(4)5/h1H
InChI Key
XSTXAVWGXDQKEL-UHFFFAOYSA-N
Formula
C2HCl3
SMILES
ClC=C(Cl)Cl
Molecular Weight1
131.39
CAS
79-01-6
Other Names
  • 1,1,2-Trichloroethene
  • 1,1,2-trichloroethylene
  • 1,1-Dichloro-2-chloroethylene
  • 1,2,2-Trichloroethylene
  • 1-Chloro-2,2-dichloroethylene
  • Acetylene trichloride
  • Algylen
  • Anamenth
  • Benzinol
  • Blacosolv
  • Blancosolv
  • C2HCl3
  • Cecolene
  • Chlorilen
  • Chlorylea
  • Chlorylen
  • Chorylen
  • Circosolv
  • Crawhaspol
  • Densinfluat
  • Distillex DS2
  • Dow-tri
  • Dukeron
  • Ethene, 1,1,2-trichloro-
  • Ethene, trichloro-
  • Ethinyl trichloride
  • Ethylene trichloride
  • Ethylene, trichloro-
  • Fleck-flip
  • Flock FLIP
  • Fluate
  • Gemalgene
  • Germalgene
  • Lanadin
  • Lethurin
  • NCI-C04546
  • Narcogen
  • Narkogen
  • Narkosoid
  • Nialk
  • Perm-A-chlor
  • Perm-A-clor
  • Petzinol
  • Philex
  • R 1120
  • RCRA Waste number U228
  • TCE
  • Threthylen
  • Threthylene
  • Trethylene
  • Tri
  • Tri-Clene
  • Tri-plus
  • Tri-plus M
  • Triad
  • Trial
  • Triasol
  • Trichlooretheen
  • Trichloorethyleen, tri
  • Trichloraethen
  • Trichloraethylen, tri
  • Trichloran
  • Trichloren
  • Trichlorethene
  • Trichlorethylene
  • Trichlorethylene, tri
  • Tricloretene
  • Tricloroetilene
  • Trielene
  • Trielin
  • Trielina
  • Trieline
  • Triklone
  • Triklone N
  • Trilen
  • Trilene
  • Triline
  • Trimar
  • Triol
  • UN 1710
  • Vestrol
  • Vitran
  • Westrosol
  • trichloroethene
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Physical Properties

Property Value Unit Source
ω 0.2070 Relay (1.0) Calculated Property
Δcliquid [-956.50; -947.70] kJ/mol Show Hide
Δcliquid -947.70 ± 2.90 kJ/mol NIST
Δcliquid -956.50 ± 8.40 kJ/mol NIST
η 0.0005510 Pa×s Densities and Viscosities of Binary Liquid Mixtures of Trichloroethylene and Tetrachloroethylene with Some Polar and Nonpolar Solvents
EA [0.30; 0.40] eV Show Hide
EA 0.40 ± 0.22 eV NIST
EA 0.30 eV NIST
Δf 1.84 kJ/mol Joback Calculated Property
Δfgas [-19.10; -5.90] kJ/mol Show Hide
Δfgas -18.00 ± 2.00 kJ/mol NIST
Δfgas -19.10 ± 3.00 kJ/mol NIST
Δfgas -5.90 kJ/mol NIST
Δfliquid [-53.10; -41.00] kJ/mol Show Hide
Δfliquid -52.00 ± 3.00 kJ/mol NIST
Δfliquid -53.10 ± 3.00 kJ/mol NIST
Δfliquid -41.00 kJ/mol NIST
Δfus 12.42 kJ/mol Joback Calculated Property
Δvap [33.97; 34.70] kJ/mol Show Hide
Δvap 34.62 kJ/mol NIST
Δvap 34.57 ± 0.09 kJ/mol NIST
Δvap 33.97 ± 0.13 kJ/mol NIST
Δvap 34.50 ± 0.10 kJ/mol NIST
Δvap 34.70 ± 0.42 kJ/mol NIST
IE [9.45; 9.68] eV Show Hide
IE 9.46 ± 0.02 eV NIST
IE 9.68 eV NIST
IE 9.48 eV NIST
IE 9.45 ± 0.01 eV NIST
IE 9.45 eV NIST
IE 9.47 ± 0.01 eV NIST
IE 9.60 eV NIST
log10WS [-1.96; -1.95]   Show Hide
log10WS -1.95 Aq. Solubility Prediction
log10WS -1.96 Estimated Solubility
logPoct/wat 2.502 Crippen Calculated Property
McVol 71.460 ml/mol McGowan Calculated Property
Pc 4665.71 kPa Joback Calculated Property
Inp [672.00; 722.00]   Show Hide
Inp 694.00 NIST
Inp 691.00 NIST
Inp 688.00 NIST
Inp 675.00 NIST
Inp 696.00 NIST
Inp 702.00 NIST
Inp 691.00 NIST
Inp 686.00 NIST
Inp 710.00 NIST
Inp 698.00 NIST
Inp 690.00 NIST
Inp 693.00 NIST
Inp 703.00 NIST
Inp 702.10 NIST
Inp 683.00 NIST
Inp 702.00 NIST
Inp 687.00 NIST
Inp 691.00 NIST
Inp 690.00 NIST
Inp 701.00 NIST
Inp 680.00 NIST
Inp 680.00 NIST
Inp 691.00 NIST
Inp Outlier 722.00 NIST
Inp 686.00 NIST
Inp 690.00 NIST
Inp 702.00 NIST
Inp 693.00 NIST
Inp 694.00 NIST
Inp 691.00 NIST
Inp 701.00 NIST
Inp 681.00 NIST
Inp 681.00 NIST
Inp 691.00 NIST
Inp 710.00 NIST
Inp 700.00 NIST
Inp 686.00 NIST
Inp 689.00 NIST
Inp 672.00 NIST
Inp 686.00 NIST
Inp 673.00 NIST
Inp 680.00 NIST
Inp 689.00 NIST
Inp 710.00 NIST
Inp 683.00 NIST
Inp 691.00 NIST
Inp 702.00 NIST
Inp 681.00 NIST
Inp 686.00 NIST
Inp 680.00 NIST
I [964.00; 1028.00]   Show Hide
I 1008.00 NIST
I 1019.00 NIST
I 1010.00 NIST
I 1010.70 NIST
I 1012.45 NIST
I 1007.14 NIST
I 999.00 NIST
I 993.00 NIST
I 1010.00 NIST
I 1010.00 NIST
I 1010.00 NIST
I 993.00 NIST
I 984.00 NIST
I 970.00 NIST
I 993.00 NIST
I 1028.00 NIST
I 999.00 NIST
I 1028.00 NIST
I Outlier 964.00 NIST
I 993.00 NIST
I 1008.00 NIST
I 1007.14 NIST
I 1010.00 NIST
I 970.00 NIST
I Outlier 964.00 NIST
Tboil [360.00; 360.55] K Show Hide
Tboil 360.40 K Excess volumes and speeds of sound of mixtures of 1,2-dibromoethane with chlorinated ethanes and ethenes at 303.15 K
Tboil 360.25 K Excess molar enthalpies of dimethylsulfoxide with chloroethanes and chloroethenes at 298.15K
Tboil 360.25 K Vapor-Liquid Equilibria and Excess Molar Enthalpies for N-Methyl-2-pyrrolidone with Chloroethanes and Chloroethenes
Tboil 360.25 K Isobaric Vapor Liquid Equilibrium for Dimethylsulfoxide with Chloroethanes and Chloroethenes
Tboil 360.40 ± 0.30 K NIST
Tboil Outlier 360.55 ± 0.40 K NIST
Tboil 360.20 ± 0.40 K NIST
Tboil 360.20 K NIST
Tboil 360.00 ± 0.40 K NIST
Tboil 360.22 ± 0.30 K NIST
Tboil 360.40 K NIST
Tboil 360.05 ± 0.20 K NIST
Tboil 360.40 ± 0.70 K NIST
Tboil 360.05 ± 0.30 K NIST
Tboil 360.10 ± 0.50 K NIST
Tboil 360.10 ± 0.50 K NIST
Tboil 360.25 ± 0.30 K NIST
Tc 571.00 K NIST
Tfus [188.25; 188.50] K Show Hide
Tfus 188.25 K Aq. Solubility Prediction
Tfus 188.50 ± 0.20 K NIST
Tfus 188.35 ± 0.30 K NIST
Vc 0.254 m3/kmol Relay (1.0) Calculated Property

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,gas [84.33; 100.24] J/mol×K [361.49; 569.29] Show Hide
Cp,gas 84.33 J/mol×K 361.49 Joback Calculated Property
Cp,gas 87.67 J/mol×K 396.12 Joback Calculated Property
Cp,gas 90.70 J/mol×K 430.76 Joback Calculated Property
Cp,gas 93.46 J/mol×K 465.39 Joback Calculated Property
Cp,gas 95.95 J/mol×K 500.02 Joback Calculated Property
Cp,gas 98.20 J/mol×K 534.65 Joback Calculated Property
Cp,gas 100.24 J/mol×K 569.29 Joback Calculated Property
Cp,liquid [120.10; 131.12] J/mol×K [260.64; 329.56] Show Hide
Cp,liquid 126.71 J/mol×K 260.64 Heat capacities of selected chlorohydrocarbons
Cp,liquid 126.63 J/mol×K 260.64 Heat capacities of selected chlorohydrocarbons
Cp,liquid 126.63 J/mol×K 260.64 Heat capacities of selected chlorohydrocarbons
Cp,liquid 126.63 J/mol×K 260.64 Heat capacities of selected chlorohydrocarbons
Cp,liquid 126.71 J/mol×K 265.75 Heat capacities of selected chlorohydrocarbons
Cp,liquid 126.80 J/mol×K 265.75 Heat capacities of selected chlorohydrocarbons
Cp,liquid 126.71 J/mol×K 265.75 Heat capacities of selected chlorohydrocarbons
Cp,liquid 126.96 J/mol×K 265.75 Heat capacities of selected chlorohydrocarbons
Cp,liquid 126.71 J/mol×K 270.85 Heat capacities of selected chlorohydrocarbons
Cp,liquid 126.96 J/mol×K 270.85 Heat capacities of selected chlorohydrocarbons
Cp,liquid 126.63 J/mol×K 270.85 Heat capacities of selected chlorohydrocarbons
Cp,liquid 127.04 J/mol×K 270.85 Heat capacities of selected chlorohydrocarbons
Cp,liquid 127.13 J/mol×K 275.96 Heat capacities of selected chlorohydrocarbons
Cp,liquid 127.04 J/mol×K 275.96 Heat capacities of selected chlorohydrocarbons
Cp,liquid 126.96 J/mol×K 275.96 Heat capacities of selected chlorohydrocarbons
Cp,liquid 127.38 J/mol×K 275.96 Heat capacities of selected chlorohydrocarbons
Cp,liquid 127.38 J/mol×K 281.06 Heat capacities of selected chlorohydrocarbons
Cp,liquid 127.38 J/mol×K 281.06 Heat capacities of selected chlorohydrocarbons
Cp,liquid 127.46 J/mol×K 281.06 Heat capacities of selected chlorohydrocarbons
Cp,liquid 127.79 J/mol×K 281.06 Heat capacities of selected chlorohydrocarbons
Cp,liquid 127.96 J/mol×K 286.17 Heat capacities of selected chlorohydrocarbons
Cp,liquid 127.96 J/mol×K 286.17 Heat capacities of selected chlorohydrocarbons
Cp,liquid 127.88 J/mol×K 286.17 Heat capacities of selected chlorohydrocarbons
Cp,liquid 128.38 J/mol×K 286.17 Heat capacities of selected chlorohydrocarbons
Cp,liquid 121.00 J/mol×K 290.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 128.21 J/mol×K 291.27 Heat capacities of selected chlorohydrocarbons
Cp,liquid 128.46 J/mol×K 291.27 Heat capacities of selected chlorohydrocarbons
Cp,liquid 128.38 J/mol×K 291.27 Heat capacities of selected chlorohydrocarbons
Cp,liquid 128.29 J/mol×K 291.27 Heat capacities of selected chlorohydrocarbons
Cp,liquid 128.54 J/mol×K 296.38 Heat capacities of selected chlorohydrocarbons
Cp,liquid 128.38 J/mol×K 296.38 Heat capacities of selected chlorohydrocarbons
Cp,liquid 128.46 J/mol×K 296.38 Heat capacities of selected chlorohydrocarbons
Cp,liquid 128.96 J/mol×K 296.38 Heat capacities of selected chlorohydrocarbons
Cp,liquid 124.70 J/mol×K 298.00 NIST
Cp,liquid 120.10 J/mol×K 298.00 NIST
Cp,liquid 124.00 J/mol×K 298.15 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 125.00 J/mol×K 300.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 128.79 J/mol×K 301.48 Heat capacities of selected chlorohydrocarbons
Cp,liquid 129.04 J/mol×K 301.48 Heat capacities of selected chlorohydrocarbons
Cp,liquid 128.96 J/mol×K 301.48 Heat capacities of selected chlorohydrocarbons
Cp,liquid 128.54 J/mol×K 301.48 Heat capacities of selected chlorohydrocarbons
Cp,liquid 129.21 J/mol×K 309.14 Heat capacities of selected chlorohydrocarbons
Cp,liquid 130.29 J/mol×K 309.14 Heat capacities of selected chlorohydrocarbons
Cp,liquid 129.04 J/mol×K 309.14 Heat capacities of selected chlorohydrocarbons
Cp,liquid 131.12 J/mol×K 319.35 Heat capacities of selected chlorohydrocarbons
Cp,liquid 130.29 J/mol×K 319.35 Heat capacities of selected chlorohydrocarbons
Cp,liquid 130.29 J/mol×K 319.35 Heat capacities of selected chlorohydrocarbons
Cp,liquid 130.95 J/mol×K 329.56 Heat capacities of selected chlorohydrocarbons
Cp,liquid 131.12 J/mol×K 329.56 Heat capacities of selected chlorohydrocarbons
ΔfusH [8.45; 8.45] kJ/mol [188.50; 188.50] Show Hide
ΔfusH 8.45 kJ/mol 188.50 NIST
ΔfusH 8.45 kJ/mol 188.50 NIST
ΔfusH 8.45 kJ/mol 188.50 NIST
ΔvapH [31.40; 36.20] kJ/mol [324.50; 360.40] Show Hide
ΔvapH 36.20 kJ/mol 324.50 NIST
ΔvapH 34.20 kJ/mol 328.50 NIST
ΔvapH 35.60 kJ/mol 329.00 NIST
ΔvapH 34.60 kJ/mol 354.00 NIST
ΔvapH 32.13 kJ/mol 360.19 NIST
ΔvapH 31.40 kJ/mol 360.40 NIST
n0 [1.46900; 1.47820]   [293.15; 308.15] Show Hide
n0 1.47820 293.15 Bubble points of some binary mixtures formed by o-cresol at 95.75 kPa
n0 1.47820 293.15 Excess Gibbs energies of selected binary mixtures formed by N,N-dimethyl formamide at 95.5 kPa
n0 1.47520 298.15 Density, Viscosity, Refractive Index, and Speed of Sound in the Binary Mixtures of Tri-n-butylamine + Triethylamine, + Tetrahydrofuran, + Tetradecane, + Tetrachloroethylene, + Pyridine, or + Trichloroethylene at (298.15, 303.15, and 308.15) K
n0 1.47820 298.15 Activity coefficients and excess Gibbs free energy of some binary mixtures formed by p-cresol at 95.23 kPa
n0 1.47820 298.15 Bubble Temperature Measurements on the Binary Mixtures of n-Heptane or Nitrobenzene or Chlorobenzene with Some Chloroethanes and Chloroethylenes at (94.6 to 95.8) kPa
n0 1.47500 298.15 Bubble-Temperature Measurements on Some Binary Mixtures Formed by Tetrahydrofuran or Amyl Alcohol with Hydrocarbons, Chlorohydrocarbons, or Butanols at (94.6 or 95.8) kPa
n0 1.47820 298.15 Bubble points of the binary mixtures formed by ethylbenzene with some chloroaliphatics and substituted benzenes at p = 94.7 kPa
n0 1.47600 298.15 Density, Viscosity, Refractive Index, and Speed of Sound for Binary Mixtures of 1,4-Dioxane with Different Organic Liquids at (298.15, 303.15, and 308.15) K
n0 1.47500 298.15 Densities, Excess Molar Volumes, Viscosity, and Refractive Indices of Binary Mixtures of Ethanoic Acid and Trichloroethylene with Dimethylbenzenes at Different Temperatures
n0 1.47220 303.15 Density, Viscosity, Refractive Index, and Speed of Sound in the Binary Mixtures of Tri-n-butylamine + Triethylamine, + Tetrahydrofuran, + Tetradecane, + Tetrachloroethylene, + Pyridine, or + Trichloroethylene at (298.15, 303.15, and 308.15) K
n0 1.47290 303.15 Density, Viscosity, Refractive Index, and Speed of Sound for Binary Mixtures of 1,4-Dioxane with Different Organic Liquids at (298.15, 303.15, and 308.15) K
n0 1.47500 303.15 Vapor-Liquid Equilibria of Binary Mixtures Formed by Hexan-1-ol with Chloroethanes and Chloroethenes at 95.6 kPa
n0 1.46900 308.15 Density, Viscosity, Refractive Index, and Speed of Sound in the Binary Mixtures of Tri-n-butylamine + Triethylamine, + Tetrahydrofuran, + Tetradecane, + Tetrachloroethylene, + Pyridine, or + Trichloroethylene at (298.15, 303.15, and 308.15) K
n0 1.46980 308.15 Density, Viscosity, Refractive Index, and Speed of Sound for Binary Mixtures of 1,4-Dioxane with Different Organic Liquids at (298.15, 303.15, and 308.15) K
ρl [1430.40; 1455.90] kg/m3 [298.15; 313.15] Show Hide
ρl 1455.65 kg/m3 298.15 Studies of Viscosities and Excess Molar Volumes of the Binary Mixtures of 1-Heptanol + 1,2-Dichloroethane, + 1,1,1-Trichloroethane, + 1,1,2,2-Tetrachloroethane, + Trichloroethylene and Tetrachloroethylene at (293.15, 298.15, and 303.15) K for the Liquid Region and at Ambient Pressure
ρl 1455.90 kg/m3 298.15 Excess Molar Volumes and Sound Speed in (Phenylacetonitrile + 1,2-Dichloroethane), (Phenylacetonitrile + 1,1,2-Trichloroethane), (Phenylacetonitrile + 1,1,2,2-Tetrachloroethane), (Phenylacetonitrile + Trichloroethene), and (Phenylacetonitrile + Tetrachloroethene) at Temperatures of (303.15, 308.15, and 313.15) K
ρl 1450.90 kg/m3 303.15 Excess Volumes and Excess Isentropic Compressibilities of Binary Liquid Mixtures of Trichloroethylene with Esters at 303.15 K
ρl 1447.50 kg/m3 303.15 Excess Molar Volumes and Sound Speed in (Phenylacetonitrile + 1,2-Dichloroethane), (Phenylacetonitrile + 1,1,2-Trichloroethane), (Phenylacetonitrile + 1,1,2,2-Tetrachloroethane), (Phenylacetonitrile + Trichloroethene), and (Phenylacetonitrile + Tetrachloroethene) at Temperatures of (303.15, 308.15, and 313.15) K
ρl 1437.80 kg/m3 308.15 Excess Molar Volumes and Sound Speed in (Phenylacetonitrile + 1,2-Dichloroethane), (Phenylacetonitrile + 1,1,2-Trichloroethane), (Phenylacetonitrile + 1,1,2,2-Tetrachloroethane), (Phenylacetonitrile + Trichloroethene), and (Phenylacetonitrile + Tetrachloroethene) at Temperatures of (303.15, 308.15, and 313.15) K
ρl 1430.40 kg/m3 313.15 Excess Molar Volumes and Sound Speed in (Phenylacetonitrile + 1,2-Dichloroethane), (Phenylacetonitrile + 1,1,2-Trichloroethane), (Phenylacetonitrile + 1,1,2,2-Tetrachloroethane), (Phenylacetonitrile + Trichloroethene), and (Phenylacetonitrile + Tetrachloroethene) at Temperatures of (303.15, 308.15, and 313.15) K
ΔfusS 44.80 J/mol×K 188.50 NIST

Datasets

Viscosity, Pa*s

Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Viscosity, Pa*s - Liquid
308.15 101.00 0.0005
Reference

Correlations

Property Value Unit Temperature (K) Source
Pvap [1.33; 202.63] kPa [267.49; 383.80] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Pvp) = A + B/(T + C)
Coefficient A1.38164e+01
Coefficient B-2.66405e+03
Coefficient C-7.05700e+01
Temperature range, min.267.49
Temperature range, max.383.80
Pvap 1.33 kPa 267.49 Calculated Property
Pvap 3.07 kPa 280.41 Calculated Property
Pvap 6.41 kPa 293.34 Calculated Property
Pvap 12.35 kPa 306.26 Calculated Property
Pvap 22.22 kPa 319.18 Calculated Property
Pvap 37.72 kPa 332.11 Calculated Property
Pvap 60.94 kPa 345.03 Calculated Property
Pvap 94.30 kPa 357.95 Calculated Property
Pvap 140.52 kPa 370.88 Calculated Property
Pvap 202.63 kPa 383.80 Calculated Property
Pvap [2.02e-03; 4903.43] kPa [188.40; 571.00] KDB Vapor Pressure Data Show Hide
Equationln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A3.98315e+01
Coefficient B-5.14297e+03
Coefficient C-3.58643e+00
Coefficient D1.34232e-06
Temperature range, min.188.40
Temperature range, max.571.00
Pvap 2.02e-03 kPa 188.40 Calculated Property
Pvap 0.15 kPa 230.91 Calculated Property
Pvap 2.71 kPa 273.42 Calculated Property
Pvap 21.01 kPa 315.93 Calculated Property
Pvap 95.71 kPa 358.44 Calculated Property
Pvap 306.11 kPa 400.96 Calculated Property
Pvap 765.33 kPa 443.47 Calculated Property
Pvap 1602.81 kPa 485.98 Calculated Property
Pvap 2945.14 kPa 528.49 Calculated Property
Pvap 4903.43 kPa 571.00 Calculated Property

Similar Compounds

Ethylene, 1,2-dichloro-, (E)-. 1,2-Dichloroethylene. Ethylene, 1,2-dichloro-, (Z)-. Ethene, 1,1-dichloro-. Tetrachloroethylene. 1,2-Dichloro-1-fluoroethylene. Ethene, chloro-. Ethene, trichlorofluoro-. Ethene, 1-chloro-2-fluoro-. Ethylene, bromo, trichloro. Ethene, 2-chloro-1,1-difluoro-. Ethene, 1-bromo-2-chloro-. (E)-1-bromo-2-chloroethene. Ethene, 1-chloro-1-fluoro-. Dichloromethyl radical.

Find more compounds similar to Trichloroethylene.

Mixtures

Find more mixtures with Trichloroethylene.

Sources

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Outlier This icon means that the value is more than 2 standard deviations away from the property mean.
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