Chemical Properties of Trichloroethylene (CAS 79-01-6)

InChI

InChI=1S/C2HCl3/c3-1-2(4)5/h1H

InChI Key

XSTXAVWGXDQKEL-UHFFFAOYSA-N

Formula

C2HCl3

SMILES

ClC=C(Cl)Cl

Molecular Weight¹

131.39

CAS

79-01-6

Other Names

• 1,1,2-Trichloroethene
• 1,1,2-trichloroethylene
• 1,1-Dichloro-2-chloroethylene
• 1,2,2-Trichloroethylene
• 1-Chloro-2,2-dichloroethylene
• Acetylene trichloride
• Algylen
• Anamenth
• Benzinol
• Blacosolv
• Blancosolv
• C2HCl3
• Cecolene
• Chlorilen
• Chlorylea
• Chlorylen
• Chorylen
• Circosolv
• Crawhaspol
• Densinfluat
• Distillex DS2
• Dow-tri
• Dukeron
• Ethene, 1,1,2-trichloro-
• Ethene, trichloro-
• Ethinyl trichloride
• Ethylene trichloride
• Ethylene, trichloro-
• Fleck-flip
• Flock FLIP
• Fluate
• Gemalgene
• Germalgene
• Lanadin
• Lethurin
• NCI-C04546
• Narcogen
• Narkogen
• Narkosoid
• Nialk
• Perm-A-chlor
• Perm-A-clor
• Petzinol
• Philex
• R 1120
• RCRA Waste number U228
• TCE
• Threthylen
• Threthylene
• Trethylene
• Tri
• Tri-Clene
• Tri-plus
• Tri-plus M
• Triad
• Trial
• Triasol
• Trichlooretheen
• Trichloorethyleen, tri
• Trichloraethen
• Trichloraethylen, tri
• Trichloran
• Trichloren
• Trichlorethene
• Trichlorethylene
• Trichlorethylene, tri
• Tricloretene
• Tricloroetilene
• Trielene
• Trielin
• Trielina
• Trieline
• Triklone
• Triklone N
• Trilen
• Trilene
• Triline
• Trimar
• Triol
• UN 1710
• Vestrol
• Vitran
• Westrosol
• trichloroethene

• ω : Acentric Factor.
• T_ig : Autoignition Temperature (K).
• Δ_cH°_liquid : Standard liquid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• μ : Dipole Moment (debye).
• η : Dynamic viscosity (Pa×s).
• EA : Electron affinity (eV).
• ε_r : Dielectric Constant (Relative permittivity).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• R_g : Radius of Gyration.
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fH°_liquid : Liquid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_fusH : Enthalpy of fusion at a given temperature (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• NFPA Fire : NFPA Fire Rating.
• NFPA Health : NFPA Health Rating.
• NFPA Safety : NFPA Safety Rating.
• P_c : Critical Pressure (kPa).
• P_triple : Triple Point Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• n₀ : Refractive Index.
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I_p : Polar retention indices.
• Δ_fusS : Entropy of fusion at a given temperature (J/mol×K).
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• λ_gas : Gas thermal conductivity (W/m×K).
• λ_liquid : Liquid thermal conductivity (W/m×K).
• T_fus : Normal melting (fusion) point (K).
• T_triple : Triple Point Temperature (K).
• U_Qi : UNIQUAC Qi Parameter.
• U_Ri : UNIQUAC Ri Parameter.
• V_c : Critical Volume (m³/kmol).
• Z_c : Critical Compressibility.
• Z_ra : Rackett Parameter.
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	[0.2130; 0.2166]
ω	0.2130		PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
ω	0.2166		ChemSep v8.3 pure component data Compiled value
ω	0.2130		KDB
Tig	693.15	K	NCMS SOLV-DB
ΔcH°liquid	[-956.50; -947.70]	kJ/mol
ΔcH°liquid	-947.70 ± 2.90	kJ/mol	NIST
ΔcH°liquid	-956.50 ± 8.40	kJ/mol	NIST
μ	[0.77; 0.90]	debye
μ	0.77	debye	ChemSep v8.3 pure component data Compiled value
μ	0.90	debye	KDB
η	0.0005510	Pa×s	Densities and Viscosities of Binary Liquid Mixtures of Trichloroethylene and Tetrachloroethylene with Some Polar and Nonpolar Solvents
EA	[0.30; 0.40]	eV
EA	0.40 ± 0.22	eV	NIST
EA	0.30	eV	NIST
εr	3.42		NCMS SOLV-DB
ΔfG°	[16.06; 19.89]	kJ/mol
ΔfG°	16.06	kJ/mol	ChemSep v8.3 pure component data Compiled value
ΔfG°	19.89	kJ/mol	KDB
Rg	3.7590		KDB
ΔfH°gas	[-19.10; -5.86]	kJ/mol
ΔfH°gas	-9.62	kJ/mol	ChemSep v8.3 pure component data Compiled value
ΔfH°gas	-5.86	kJ/mol	KDB
ΔfH°gas	-18.00 ± 2.00	kJ/mol	NIST
ΔfH°gas	-19.10 ± 3.00	kJ/mol	NIST
ΔfH°gas	-5.90	kJ/mol	NIST
ΔfH°liquid	[-53.10; -41.00]	kJ/mol
ΔfH°liquid	-52.00 ± 3.00	kJ/mol	NIST
ΔfH°liquid	-53.10 ± 3.00	kJ/mol	NIST
ΔfH°liquid	-41.00	kJ/mol	NIST
ΔfusH°	12.42	kJ/mol	Joback Calculated Property
ΔvapH°	[33.97; 34.70]	kJ/mol
ΔvapH°	34.27	kJ/mol	NCMS SOLV-DB
ΔvapH°	34.62	kJ/mol	NIST
ΔvapH°	34.57 ± 0.09	kJ/mol	NIST
ΔvapH°	33.97 ± 0.13	kJ/mol	NIST
ΔvapH°	34.50 ± 0.10	kJ/mol	NIST
ΔvapH°	34.70 ± 0.42	kJ/mol	NIST
IE	[9.45; 9.68]	eV
IE	9.46 ± 0.02	eV	NIST
IE	9.68	eV	NIST
IE	9.48	eV	NIST
IE	9.45 ± 0.01	eV	NIST
IE	9.45	eV	NIST
IE	9.47 ± 0.01	eV	NIST
IE	9.60	eV	NIST
log10WS	[-1.96; -1.95]
log10WS	-1.95		Aq. Solubility Prediction
log10WS	-1.96		Estimated Solubility
logPoct/wat	2.420		NCMS SOLV-DB
McVol	71.460	ml/mol	McGowan Calculated Property
NFPA Fire	[%!d(float64=1); %!d(float64=1)]
NFPA Fire	1		KDB
NFPA Fire	1		NCMS SOLV-DB
NFPA Health	[%!d(float64=2); %!d(float64=2)]
NFPA Health	2		KDB
NFPA Health	2		NCMS SOLV-DB
NFPA Safety	[%!d(float64=0); %!d(float64=1)]
NFPA Safety	1		KDB
NFPA Safety	0		NCMS SOLV-DB
Pc	[4910.00; 5020.00]	kPa
Pc	4914.26	kPa	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Pc	4910.00	kPa	ChemSep v8.3 pure component data Compiled value
Pc	5020.00	kPa	KDB
Ptriple	1.98e-03	kPa	ChemSep v8.3 pure component data Compiled value
Inp	[672.00; 722.00]
Inp	694.00		NIST
Inp	691.00		NIST
Inp	688.00		NIST
Inp	675.00		NIST
Inp	696.00		NIST
Inp	702.00		NIST
Inp	691.00		NIST
Inp	686.00		NIST
Inp	710.00		NIST
Inp	698.00		NIST
Inp	690.00		NIST
Inp	693.00		NIST
Inp	703.00		NIST
Inp	702.10		NIST
Inp	683.00		NIST
Inp	702.00		NIST
Inp	687.00		NIST
Inp	691.00		NIST
Inp	690.00		NIST
Inp	701.00		NIST
Inp	680.00		NIST
Inp	680.00		NIST
Inp	691.00		NIST
Inp	Outlier 722.00		NIST
Inp	686.00		NIST
Inp	690.00		NIST
Inp	702.00		NIST
Inp	693.00		NIST
Inp	694.00		NIST
Inp	691.00		NIST
Inp	701.00		NIST
Inp	681.00		NIST
Inp	681.00		NIST
Inp	691.00		NIST
Inp	710.00		NIST
Inp	700.00		NIST
Inp	686.00		NIST
Inp	689.00		NIST
Inp	672.00		NIST
Inp	686.00		NIST
Inp	673.00		NIST
Inp	680.00		NIST
Inp	689.00		NIST
Inp	710.00		NIST
Inp	683.00		NIST
Inp	691.00		NIST
Inp	702.00		NIST
Inp	681.00		NIST
Inp	686.00		NIST
Inp	680.00		NIST
Ip	[964.00; 1028.00]
Ip	1008.00		NIST
Ip	1019.00		NIST
Ip	1010.00		NIST
Ip	1010.70		NIST
Ip	1012.45		NIST
Ip	1007.14		NIST
Ip	999.00		NIST
Ip	993.00		NIST
Ip	1010.00		NIST
Ip	1010.00		NIST
Ip	1010.00		NIST
Ip	993.00		NIST
Ip	984.00		NIST
Ip	970.00		NIST
Ip	993.00		NIST
Ip	1028.00		NIST
Ip	999.00		NIST
Ip	1028.00		NIST
Ip	Outlier 964.00		NIST
Ip	993.00		NIST
Ip	1008.00		NIST
Ip	1007.14		NIST
Ip	1010.00		NIST
Ip	970.00		NIST
Ip	Outlier 964.00		NIST
Tboil	[359.85; 360.55]	K
Tboil	360.40	K	Excess volumes and speeds of sound of mixtures of 1,2-dibromoethane with chlorinated ethanes and ethenes at 303.15 K
Tboil	360.25	K	Excess molar enthalpies of dimethylsulfoxide with chloroethanes and chloroethenes at 298.15K
Tboil	360.25	K	Vapor-Liquid Equilibria and Excess Molar Enthalpies for N-Methyl-2-pyrrolidone with Chloroethanes and Chloroethenes
Tboil	360.25	K	Isobaric Vapor Liquid Equilibrium for Dimethylsulfoxide with Chloroethanes and Chloroethenes
Tboil	360.10	K	ChemSep v8.3 pure component data Compiled value
Tboil	360.36	K	KDB
Tboil	Outlier 359.85	K	NCMS SOLV-DB
Tboil	360.40 ± 0.30	K	NIST
Tboil	360.55 ± 0.40	K	NIST
Tboil	360.20 ± 0.40	K	NIST
Tboil	360.20	K	NIST
Tboil	360.00 ± 0.40	K	NIST
Tboil	360.22 ± 0.30	K	NIST
Tboil	360.40	K	NIST
Tboil	360.05 ± 0.20	K	NIST
Tboil	360.40 ± 0.70	K	NIST
Tboil	360.05 ± 0.30	K	NIST
Tboil	360.10 ± 0.50	K	NIST
Tboil	360.10 ± 0.50	K	NIST
Tboil	360.25 ± 0.30	K	NIST
Tc	[544.20; 571.00]	K
Tc	571.00	K	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tc	571.00	K	ChemSep v8.3 pure component data Compiled value
Tc	544.20	K	KDB
Tc	571.00	K	NIST
Tfus	[188.15; 188.50]	K
Tfus	188.15	K	Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Tfus	188.40	K	ChemSep v8.3 pure component data Compiled value
Tfus	188.40	K	KDB
Tfus	188.25	K	Aq. Solubility Prediction
Tfus	188.35	K	NCMS SOLV-DB
Tfus	188.50 ± 0.20	K	NIST
Tfus	188.35 ± 0.30	K	NIST
Ttriple	188.40	K	ChemSep v8.3 pure component data Compiled value
UQi	2.86		ChemSep v8.3 pure component data Compiled value
URi	3.31		ChemSep v8.3 pure component data Compiled value
Vc	[0.256; 0.256]	m3/kmol
Vc	0.256	m3/kmol	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Vc	0.256	m3/kmol	ChemSep v8.3 pure component data Compiled value
Vc	0.256	m3/kmol	KDB
Zc	[0.2650000; 0.2840200]
Zc	0.2650000		ChemSep v8.3 pure component data Compiled value
Zc	0.2840200		KDB
Zra	0.27		KDB

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[120.10; 131.12]	J/mol×K	[260.64; 329.56]
Cp,liquid	126.71	J/mol×K	260.64	Heat capacities of selected chlorohydrocarbons
Cp,liquid	126.63	J/mol×K	260.64	Heat capacities of selected chlorohydrocarbons
Cp,liquid	126.63	J/mol×K	260.64	Heat capacities of selected chlorohydrocarbons
Cp,liquid	126.63	J/mol×K	260.64	Heat capacities of selected chlorohydrocarbons
Cp,liquid	126.71	J/mol×K	265.75	Heat capacities of selected chlorohydrocarbons
Cp,liquid	126.80	J/mol×K	265.75	Heat capacities of selected chlorohydrocarbons
Cp,liquid	126.71	J/mol×K	265.75	Heat capacities of selected chlorohydrocarbons
Cp,liquid	126.96	J/mol×K	265.75	Heat capacities of selected chlorohydrocarbons
Cp,liquid	126.71	J/mol×K	270.85	Heat capacities of selected chlorohydrocarbons
Cp,liquid	126.96	J/mol×K	270.85	Heat capacities of selected chlorohydrocarbons
Cp,liquid	126.63	J/mol×K	270.85	Heat capacities of selected chlorohydrocarbons
Cp,liquid	127.04	J/mol×K	270.85	Heat capacities of selected chlorohydrocarbons
Cp,liquid	127.13	J/mol×K	275.96	Heat capacities of selected chlorohydrocarbons
Cp,liquid	127.04	J/mol×K	275.96	Heat capacities of selected chlorohydrocarbons
Cp,liquid	126.96	J/mol×K	275.96	Heat capacities of selected chlorohydrocarbons
Cp,liquid	127.38	J/mol×K	275.96	Heat capacities of selected chlorohydrocarbons
Cp,liquid	127.38	J/mol×K	281.06	Heat capacities of selected chlorohydrocarbons
Cp,liquid	127.38	J/mol×K	281.06	Heat capacities of selected chlorohydrocarbons
Cp,liquid	127.46	J/mol×K	281.06	Heat capacities of selected chlorohydrocarbons
Cp,liquid	127.79	J/mol×K	281.06	Heat capacities of selected chlorohydrocarbons
Cp,liquid	127.96	J/mol×K	286.17	Heat capacities of selected chlorohydrocarbons
Cp,liquid	127.96	J/mol×K	286.17	Heat capacities of selected chlorohydrocarbons
Cp,liquid	127.88	J/mol×K	286.17	Heat capacities of selected chlorohydrocarbons
Cp,liquid	128.38	J/mol×K	286.17	Heat capacities of selected chlorohydrocarbons
Cp,liquid	121.00	J/mol×K	290.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	128.21	J/mol×K	291.27	Heat capacities of selected chlorohydrocarbons
Cp,liquid	128.46	J/mol×K	291.27	Heat capacities of selected chlorohydrocarbons
Cp,liquid	128.38	J/mol×K	291.27	Heat capacities of selected chlorohydrocarbons
Cp,liquid	128.29	J/mol×K	291.27	Heat capacities of selected chlorohydrocarbons
Cp,liquid	128.54	J/mol×K	296.38	Heat capacities of selected chlorohydrocarbons
Cp,liquid	128.38	J/mol×K	296.38	Heat capacities of selected chlorohydrocarbons
Cp,liquid	128.46	J/mol×K	296.38	Heat capacities of selected chlorohydrocarbons
Cp,liquid	128.96	J/mol×K	296.38	Heat capacities of selected chlorohydrocarbons
Cp,liquid	124.70	J/mol×K	298.00	NIST
Cp,liquid	120.10	J/mol×K	298.00	NIST
Cp,liquid	124.00	J/mol×K	298.15	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	125.00	J/mol×K	300.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	128.79	J/mol×K	301.48	Heat capacities of selected chlorohydrocarbons
Cp,liquid	129.04	J/mol×K	301.48	Heat capacities of selected chlorohydrocarbons
Cp,liquid	128.96	J/mol×K	301.48	Heat capacities of selected chlorohydrocarbons
Cp,liquid	128.54	J/mol×K	301.48	Heat capacities of selected chlorohydrocarbons
Cp,liquid	129.21	J/mol×K	309.14	Heat capacities of selected chlorohydrocarbons
Cp,liquid	130.29	J/mol×K	309.14	Heat capacities of selected chlorohydrocarbons
Cp,liquid	129.04	J/mol×K	309.14	Heat capacities of selected chlorohydrocarbons
Cp,liquid	131.12	J/mol×K	319.35	Heat capacities of selected chlorohydrocarbons
Cp,liquid	130.29	J/mol×K	319.35	Heat capacities of selected chlorohydrocarbons
Cp,liquid	130.29	J/mol×K	319.35	Heat capacities of selected chlorohydrocarbons
Cp,liquid	130.95	J/mol×K	329.56	Heat capacities of selected chlorohydrocarbons
Cp,liquid	131.12	J/mol×K	329.56	Heat capacities of selected chlorohydrocarbons
η	0.0005320	Pa×s	298.15	NCMS SOLV-DB
ΔfusH	[8.45; 8.45]	kJ/mol	[188.50; 188.50]
ΔfusH	8.45	kJ/mol	188.50	NIST
ΔfusH	8.45	kJ/mol	188.50	NIST
ΔfusH	8.45	kJ/mol	188.50	NIST
ΔvapH	[31.38; 36.20]	kJ/mol	[324.50; 361.20]
ΔvapH	36.20	kJ/mol	324.50	NIST
ΔvapH	34.20	kJ/mol	328.50	NIST
ΔvapH	35.60	kJ/mol	329.00	NIST
ΔvapH	34.60	kJ/mol	354.00	NIST
ΔvapH	32.13	kJ/mol	360.19	NIST
ΔvapH	31.40	kJ/mol	360.40	NIST
ΔvapH	31.38	kJ/mol	361.20	KDB
Pvap	9.20	kPa	298.15	NCMS SOLV-DB
n0	[1.46900; 1.47820]		[293.15; 308.15]
n0	1.47820		293.15	Bubble points of some binary mixtures formed by o-cresol at 95.75 kPa
n0	1.47820		293.15	Excess Gibbs energies of selected binary mixtures formed by N,N-dimethyl formamide at 95.5 kPa
n0	1.47520		298.15	Density, Viscosity, Refractive Index, and Speed of Sound in the Binary Mixtures of Tri-n-butylamine + Triethylamine, + Tetrahydrofuran, + Tetradecane, + Tetrachloroethylene, + Pyridine, or + Trichloroethylene at (298.15, 303.15, and 308.15) K
n0	1.47820		298.15	Activity coefficients and excess Gibbs free energy of some binary mixtures formed by p-cresol at 95.23 kPa
n0	1.47820		298.15	Bubble Temperature Measurements on the Binary Mixtures of n-Heptane or Nitrobenzene or Chlorobenzene with Some Chloroethanes and Chloroethylenes at (94.6 to 95.8) kPa
n0	1.47500		298.15	Bubble-Temperature Measurements on Some Binary Mixtures Formed by Tetrahydrofuran or Amyl Alcohol with Hydrocarbons, Chlorohydrocarbons, or Butanols at (94.6 or 95.8) kPa
n0	1.47820		298.15	Bubble points of the binary mixtures formed by ethylbenzene with some chloroaliphatics and substituted benzenes at p = 94.7 kPa
n0	1.47600		298.15	Density, Viscosity, Refractive Index, and Speed of Sound for Binary Mixtures of 1,4-Dioxane with Different Organic Liquids at (298.15, 303.15, and 308.15) K
n0	1.47500		298.15	Densities, Excess Molar Volumes, Viscosity, and Refractive Indices of Binary Mixtures of Ethanoic Acid and Trichloroethylene with Dimethylbenzenes at Different Temperatures
n0	1.47500		298.15	NCMS SOLV-DB
n0	1.47220		303.15	Density, Viscosity, Refractive Index, and Speed of Sound in the Binary Mixtures of Tri-n-butylamine + Triethylamine, + Tetrahydrofuran, + Tetradecane, + Tetrachloroethylene, + Pyridine, or + Trichloroethylene at (298.15, 303.15, and 308.15) K
n0	1.47290		303.15	Density, Viscosity, Refractive Index, and Speed of Sound for Binary Mixtures of 1,4-Dioxane with Different Organic Liquids at (298.15, 303.15, and 308.15) K
n0	1.47500		303.15	Vapor-Liquid Equilibria of Binary Mixtures Formed by Hexan-1-ol with Chloroethanes and Chloroethenes at 95.6 kPa
n0	1.46900		308.15	Density, Viscosity, Refractive Index, and Speed of Sound in the Binary Mixtures of Tri-n-butylamine + Triethylamine, + Tetrahydrofuran, + Tetradecane, + Tetrachloroethylene, + Pyridine, or + Trichloroethylene at (298.15, 303.15, and 308.15) K
n0	1.46980		308.15	Density, Viscosity, Refractive Index, and Speed of Sound for Binary Mixtures of 1,4-Dioxane with Different Organic Liquids at (298.15, 303.15, and 308.15) K
ρl	[1430.40; 1462.00]	kg/m3	[293.00; 313.15]
ρl	1462.00	kg/m3	293.00	KDB
ρl	1455.65	kg/m3	298.15	Studies of Viscosities and Excess Molar Volumes of the Binary Mixtures of 1-Heptanol + 1,2-Dichloroethane, + 1,1,1-Trichloroethane, + 1,1,2,2-Tetrachloroethane, + Trichloroethylene and Tetrachloroethylene at (293.15, 298.15, and 303.15) K for the Liquid Region and at Ambient Pressure
ρl	1455.90	kg/m3	298.15	Excess Molar Volumes and Sound Speed in (Phenylacetonitrile + 1,2-Dichloroethane), (Phenylacetonitrile + 1,1,2-Trichloroethane), (Phenylacetonitrile + 1,1,2,2-Tetrachloroethane), (Phenylacetonitrile + Trichloroethene), and (Phenylacetonitrile + Tetrachloroethene) at Temperatures of (303.15, 308.15, and 313.15) K
ρl	1450.90	kg/m3	303.15	Excess Volumes and Excess Isentropic Compressibilities of Binary Liquid Mixtures of Trichloroethylene with Esters at 303.15 K
ρl	1447.50	kg/m3	303.15	Excess Molar Volumes and Sound Speed in (Phenylacetonitrile + 1,2-Dichloroethane), (Phenylacetonitrile + 1,1,2-Trichloroethane), (Phenylacetonitrile + 1,1,2,2-Tetrachloroethane), (Phenylacetonitrile + Trichloroethene), and (Phenylacetonitrile + Tetrachloroethene) at Temperatures of (303.15, 308.15, and 313.15) K
ρl	1437.80	kg/m3	308.15	Excess Molar Volumes and Sound Speed in (Phenylacetonitrile + 1,2-Dichloroethane), (Phenylacetonitrile + 1,1,2-Trichloroethane), (Phenylacetonitrile + 1,1,2,2-Tetrachloroethane), (Phenylacetonitrile + Trichloroethene), and (Phenylacetonitrile + Tetrachloroethene) at Temperatures of (303.15, 308.15, and 313.15) K
ρl	1430.40	kg/m3	313.15	Excess Molar Volumes and Sound Speed in (Phenylacetonitrile + 1,2-Dichloroethane), (Phenylacetonitrile + 1,1,2-Trichloroethane), (Phenylacetonitrile + 1,1,2,2-Tetrachloroethane), (Phenylacetonitrile + Trichloroethene), and (Phenylacetonitrile + Tetrachloroethene) at Temperatures of (303.15, 308.15, and 313.15) K
ΔfusS	44.80	J/mol×K	188.50	NIST
γ	[0.03; 0.03]	N/m	[293.20; 298.15]
γ	0.03	N/m	293.20	KDB
γ	0.03	N/m	298.15	NCMS SOLV-DB

Datasets

Viscosity, Pa*s

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Viscosity, Pa*s - Liquid
308.15	101.00	0.0005
Reference

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[57.23; 125.00]	J/mol×K	[100.00; 1500.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is Cp,gas in J/mol×K, T in K
Coefficient A			5.63050e+01
Coefficient B			-5.00680e+02
Coefficient C			4.98524e+00
Coefficient D			-5.36110e-04
Coefficient E			1.69980e-07
Temperature range, min.			100.00
Temperature range, max.			1500.00
Cp,gas	57.23	J/mol×K	100.00	Calculated Property
Cp,gas	74.48	J/mol×K	255.56	Calculated Property
Cp,gas	92.02	J/mol×K	411.11	Calculated Property
Cp,gas	103.41	J/mol×K	566.67	Calculated Property
Cp,gas	110.55	J/mol×K	722.22	Calculated Property
Cp,gas	115.17	J/mol×K	877.78	Calculated Property
Cp,gas	118.37	J/mol×K	1033.33	Calculated Property
Cp,gas	120.83	J/mol×K	1188.89	Calculated Property
Cp,gas	122.95	J/mol×K	1344.44	Calculated Property
Cp,gas	125.00	J/mol×K	1500.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[119.97; 139.22]	J/mol×K	[188.40; 419.90]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is Cp,liquid in J/mol×K, T in K
Coefficient A			1.11110e+02
Coefficient B			1.04260e+03
Coefficient C			-1.00091e+01
Coefficient D			4.30290e-02
Coefficient E			-4.08670e-05
Temperature range, min.			188.40
Temperature range, max.			419.90
Cp,liquid	119.97	J/mol×K	188.40	Calculated Property
Cp,liquid	120.13	J/mol×K	214.12	Calculated Property
Cp,liquid	121.16	J/mol×K	239.84	Calculated Property
Cp,liquid	122.84	J/mol×K	265.57	Calculated Property
Cp,liquid	125.07	J/mol×K	291.29	Calculated Property
Cp,liquid	127.78	J/mol×K	317.01	Calculated Property
Cp,liquid	130.80	J/mol×K	342.73	Calculated Property
Cp,liquid	133.91	J/mol×K	368.46	Calculated Property
Cp,liquid	136.83	J/mol×K	394.18	Calculated Property
Cp,liquid	139.22	J/mol×K	419.90	Calculated Property

Property	Value	Unit	Temperature (K)	Source
η	[0.0014048; 0.0002382]	Pa×s	[225.00; 471.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = exp(A + B/T + C·ln(T) + D·T^E) Y is η in Pa×s, T in K
Coefficient A			-1.69470e+01
Coefficient B			1.15740e+03
Coefficient C			9.55330e-01
Coefficient D			1.20510e-06
Coefficient E			2.00000e+00
Temperature range, min.			225.00
Temperature range, max.			471.00
η	0.0014048	Pa×s	225.00	Calculated Property
η	0.0009121	Pa×s	252.33	Calculated Property
η	0.0006541	Pa×s	279.67	Calculated Property
η	0.0005043	Pa×s	307.00	Calculated Property
η	0.0004106	Pa×s	334.33	Calculated Property
η	0.0003486	Pa×s	361.67	Calculated Property
η	0.0003059	Pa×s	389.00	Calculated Property
η	0.0002757	Pa×s	416.33	Calculated Property
η	0.0002540	Pa×s	443.67	Calculated Property
η	0.0002382	Pa×s	471.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
ΔvapH	[37.73; 0.00]	kJ/mol	[188.40; 571.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A·(1 − Tr)^(B + C·Tr + D·Tr² + E·Tr³), Tr = T/Tc Y is ΔvapH in kJ/mol, T in K
Coefficient A			4.57159e+01
Coefficient B			5.81727e-01
Coefficient C			-1.22707e-01
Coefficient D			-8.42037e-01
Coefficient E			8.31632e-01
Critical temperature, Tc (K)			5.71000e+02
Temperature range, min.			188.40
Temperature range, max.			571.00
ΔvapH	37.73	kJ/mol	188.40	Calculated Property
ΔvapH	36.22	kJ/mol	230.91	Calculated Property
ΔvapH	34.74	kJ/mol	273.42	Calculated Property
ΔvapH	33.20	kJ/mol	315.93	Calculated Property
ΔvapH	31.45	kJ/mol	358.44	Calculated Property
ΔvapH	29.26	kJ/mol	400.96	Calculated Property
ΔvapH	26.33	kJ/mol	443.47	Calculated Property
ΔvapH	22.17	kJ/mol	485.98	Calculated Property
ΔvapH	15.92	kJ/mol	528.49	Calculated Property
ΔvapH	0.00	kJ/mol	571.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 202.63]	kPa	[267.49; 383.80]	The Yaws Handbook of Vapor Pressure
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.38164e+01
Coefficient B			-2.66405e+03
Coefficient C			-7.05700e+01
Temperature range, min.			267.49
Temperature range, max.			383.80
Pvap	1.33	kPa	267.49	Calculated Property
Pvap	3.07	kPa	280.41	Calculated Property
Pvap	6.41	kPa	293.34	Calculated Property
Pvap	12.35	kPa	306.26	Calculated Property
Pvap	22.22	kPa	319.18	Calculated Property
Pvap	37.72	kPa	332.11	Calculated Property
Pvap	60.94	kPa	345.03	Calculated Property
Pvap	94.30	kPa	357.95	Calculated Property
Pvap	140.52	kPa	370.88	Calculated Property
Pvap	202.63	kPa	383.80	Calculated Property
Pvap	[2.24e-03; 4910.00]	kPa	[188.40; 540.32]	ChemSep v8.3 pure component data Compiled value
Equation			Y = exp(A + B/T + C·ln(T) + D·T^E) Y is Pvap in kPa, T in K
Coefficient A			3.96540e+01
Coefficient B			-5.02197e+03
Coefficient C			-3.67516e+00
Coefficient D			4.33041e-06
Coefficient E			2.00000e+00
Comment			Range stopped where the equation exceeds Pc; ChemSep gives it to 571 K.
Temperature range, min.			188.40
Temperature range, max.			540.32
Pvap	2.24e-03	kPa	188.40	Calculated Property
Pvap	0.12	kPa	227.50	Calculated Property
Pvap	1.82	kPa	266.60	Calculated Property
Pvap	13.46	kPa	305.71	Calculated Property
Pvap	62.20	kPa	344.81	Calculated Property
Pvap	209.01	kPa	383.91	Calculated Property
Pvap	562.13	kPa	423.01	Calculated Property
Pvap	1288.50	kPa	462.11	Calculated Property
Pvap	2627.13	kPa	501.22	Calculated Property
Pvap	4910.00	kPa	540.32	Calculated Property
Pvap	[2.02e-03; 4903.43]	kPa	[188.40; 571.00]	KDB Vapor Pressure Data
Equation			ln(Y) = A + B/T + C·ln(T) + D·T² + E/T² Y is Pvap in kPa, T in K
Coefficient A			3.98315e+01
Coefficient B			-5.14297e+03
Coefficient C			-3.58643e+00
Coefficient D			1.34232e-06
Coefficient E			0.00000e+00
Temperature range, min.			188.40
Temperature range, max.			571.00
Pvap	2.02e-03	kPa	188.40	Calculated Property
Pvap	0.15	kPa	230.91	Calculated Property
Pvap	2.71	kPa	273.42	Calculated Property
Pvap	21.01	kPa	315.93	Calculated Property
Pvap	95.71	kPa	358.44	Calculated Property
Pvap	306.11	kPa	400.96	Calculated Property
Pvap	765.33	kPa	443.47	Calculated Property
Pvap	1602.81	kPa	485.98	Calculated Property
Pvap	2945.14	kPa	528.49	Calculated Property
Pvap	4903.43	kPa	571.00	Calculated Property
Pvap	[6.33; 98.69]	kPa	[290.90; 359.62]	NIST
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.27873e+01
Coefficient B			-2.24396e+03
Coefficient C			-8.58110e+01
Reference			McDonald, 1944
Comment			Coefficents calculated by NIST from author's data.
Temperature range, min.			290.90
Temperature range, max.			359.62
Pvap	6.33	kPa	290.90	Calculated Property
Pvap	9.38	kPa	298.54	Calculated Property
Pvap	13.52	kPa	306.17	Calculated Property
Pvap	19.01	kPa	313.81	Calculated Property
Pvap	26.16	kPa	321.44	Calculated Property
Pvap	35.27	kPa	329.08	Calculated Property
Pvap	46.70	kPa	336.71	Calculated Property
Pvap	60.82	kPa	344.35	Calculated Property
Pvap	78.01	kPa	351.98	Calculated Property
Pvap	98.69	kPa	359.62	Calculated Property

Property	Value	Unit	Temperature (K)	Source
ρl	[1628.56; 513.25]	kg/m3	[188.40; 571.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A / B^(1 + (1 − T/C)^D) Y is ρl in kg/m3, T in K
Coefficient A			1.39692e+02
Coefficient B			2.72170e-01
Coefficient C			5.71000e+02
Coefficient D			2.98600e-01
Temperature range, min.			188.40
Temperature range, max.			571.00
ρl	1628.56	kg/m3	188.40	Calculated Property
ρl	1564.85	kg/m3	230.91	Calculated Property
ρl	1498.13	kg/m3	273.42	Calculated Property
ρl	1427.65	kg/m3	315.93	Calculated Property
ρl	1352.32	kg/m3	358.44	Calculated Property
ρl	1270.45	kg/m3	400.96	Calculated Property
ρl	1179.12	kg/m3	443.47	Calculated Property
ρl	1072.42	kg/m3	485.98	Calculated Property
ρl	934.40	kg/m3	528.49	Calculated Property
ρl	513.25	kg/m3	571.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
γ	[0.04; 2.70e-05]	N/m	[175.84; 563.49]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is γ in N/m, T in K
Coefficient A			-2.43470e-02
Coefficient B			-5.07630e+01
Coefficient C			-1.85840e+00
Coefficient D			-2.90880e-03
Coefficient E			-3.98920e-07
Comment			Range stopped where the equation turns negative; ChemSep gives it to 571 K.
Temperature range, min.			175.84
Temperature range, max.			563.49
γ	0.04	N/m	175.84	Calculated Property
γ	0.04	N/m	218.91	Calculated Property
γ	0.03	N/m	261.98	Calculated Property
γ	0.03	N/m	305.06	Calculated Property
γ	0.02	N/m	348.13	Calculated Property
γ	0.02	N/m	391.20	Calculated Property
γ	0.01	N/m	434.27	Calculated Property
γ	0.01	N/m	477.35	Calculated Property
γ	0.00	N/m	520.42	Calculated Property
γ	2.70e-05	N/m	563.49	Calculated Property

Property	Value	Unit	Temperature (K)	Source
λgas	[0.00; 0.03]	W/m×K	[188.40; 1000.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A·T^B / (1 + C/T + D/T²) Y is λgas in W/m×K, T in K
Coefficient A			5.05390e-04
Coefficient B			6.74100e-01
Coefficient C			5.84610e+02
Coefficient D			3.17740e+03
Temperature range, min.			188.40
Temperature range, max.			1000.00
λgas	0.00	W/m×K	188.40	Calculated Property
λgas	0.01	W/m×K	278.58	Calculated Property
λgas	0.01	W/m×K	368.76	Calculated Property
λgas	0.01	W/m×K	458.93	Calculated Property
λgas	0.02	W/m×K	549.11	Calculated Property
λgas	0.02	W/m×K	639.29	Calculated Property
λgas	0.02	W/m×K	729.47	Calculated Property
λgas	0.03	W/m×K	819.64	Calculated Property
λgas	0.03	W/m×K	909.82	Calculated Property
λgas	0.03	W/m×K	1000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
λliquid	[0.14; 0.09]	W/m×K	[188.40; 419.47]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is λliquid in W/m×K, T in K
Coefficient A			7.97670e-02
Coefficient B			5.22460e+02
Coefficient C			-9.49790e+00
Coefficient D			3.20210e-02
Coefficient E			-5.76900e-05
Temperature range, min.			188.40
Temperature range, max.			419.47
λliquid	0.14	W/m×K	188.40	Calculated Property
λliquid	0.14	W/m×K	214.07	Calculated Property
λliquid	0.13	W/m×K	239.75	Calculated Property
λliquid	0.13	W/m×K	265.42	Calculated Property
λliquid	0.12	W/m×K	291.10	Calculated Property
λliquid	0.11	W/m×K	316.77	Calculated Property
λliquid	0.10	W/m×K	342.45	Calculated Property
λliquid	0.10	W/m×K	368.12	Calculated Property
λliquid	0.09	W/m×K	393.80	Calculated Property
λliquid	0.09	W/m×K	419.47	Calculated Property

Similar Compounds

Find more compounds similar to Trichloroethylene.

Mixtures

• Trichloroethylene + Water
• Trichloroethylene + Phenol, 2-methyl-
• Trichloroethylene + Benzene, ethyl-
• Trichloroethylene + Formamide, N,N-dimethyl-
• Trichloroethylene + Acetamide, N-methyl-
• Trichloroethylene + PHENOL, 4-METHYL-
• Trichloroethylene + Dimethyl Sulfoxide
• Trichloroethylene + Tetradecanoic acid
• Trichloroethylene + n-Hexadecanoic acid
• Trichloroethylene + n-Decanoic acid
• Trichloroethylene + Dodecanoic acid
• Trichloroethylene + Octadecanoic acid
• Oleic Acid + Trichloroethylene
• Trichloroethylene + Ethane, 1,2-dibromo-
• Trichloroethylene + Ethyl Acetate
• Trichloroethylene + Acetic acid, propyl ester
• Trichloroethylene + Acetic acid, butyl ester
• Trichloroethylene + Benzyl nitrile
• Trichloroethylene + Ethanol + n-Hexadecanoic acid
• Trichloroethylene + 2-Propanol + n-Hexadecanoic acid

Find more mixtures with Trichloroethylene.

Sources

• KDB Vapor Pressure Data
• Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) ChEDL chemicals 1.5.2, from Bradley, J.-C.; Williams, A.; Lang, A. Jean-Claude Bradley Open Melting Point Dataset. Figshare, 2014 (CC0).
• PSRK revision IV (2005), critical constants and acentric factors of 1000 components ChEDL chemicals 1.5.2, from Horstmann, S.; Jabłoniec, A.; Krafczyk, J.; Fischer, K.; Gmehling, J. PSRK Group Contribution Equation of State: Comprehensive Revision and Extension IV, Including Critical Constants and α-Function Parameters for 1000 Components. Fluid Phase Equilib. 2005, 227, 157-164.
• ChemSep v8.3 pure component data Converted from ChemSep v8.3 pure component data, H. Kooijman and R. Taylor (2021, 2022), Artistic License 2.0; see how the values differ.
• Excess Volumes and Excess Isentropic Compressibilities of Binary Liquid Mixtures of Trichloroethylene with Esters at 303.15 K
• Bubble points of some binary mixtures formed by o-cresol at 95.75 kPa
• Excess Gibbs energies of selected binary mixtures formed by N,N-dimethyl formamide at 95.5 kPa
• Determination of vapour-liquid and vapour-liquid-liquid equilibrium of the chloroform-water and trichloroethylene-water binary mixtures
• Heat capacities of selected chlorohydrocarbons
• Using binary mixtures of dicationic ionic liquids for determination ofactivity coefficients at infinite dilution by gas-liquid chromatography
• Excess volumes and speeds of sound of mixtures of 1,2-dibromoethane with chlorinated ethanes and ethenes at 303.15 K
• Bubble points of the binary mixtures formed by ethylbenzene with some chloroaliphatics and substituted benzenes at p = 94.7 kPa
• Densities and viscosities of binary liquid mixtures of N-methylacetamide with some chloroethanes and chloroethenes at T = 308.15 K
• Activity coefficients and excess Gibbs free energy of some binary mixtures formed by p-cresol at 95.23 kPa
• Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds: Saturated fatty acids
• Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds Part II: C18 fatty acids
• Excess molar enthalpies of dimethylsulfoxide with chloroethanes and chloroethenes at 298.15K
• Dilute Vapor Absorption: A New Accurate Technique for Measurement of the Limiting Activity Coefficient of Water in Hydrophobic Solvents of Lower Volatility
• Vapor-Liquid Equilibria and Excess Molar Enthalpies for N-Methyl-2-pyrrolidone with Chloroethanes and Chloroethenes
• Measurement and Estimation of Henry's Law Constants of Chlorinated Ethylenes in Aqueous Surfactant Solutions
• Bubble Temperature Measurements on the Binary Mixtures of n-Heptane or Nitrobenzene or Chlorobenzene with Some Chloroethanes and Chloroethylenes at (94.6 to 95.8) kPa
• Bubble-Temperature Measurements on Some Binary Mixtures Formed by Tetrahydrofuran or Amyl Alcohol with Hydrocarbons, Chlorohydrocarbons, or Butanols at (94.6 or 95.8) kPa
• Density, Viscosity, Refractive Index, and Speed of Sound in the Binary Mixtures of Tri-n-butylamine + Triethylamine, + Tetrahydrofuran, + Tetradecane, + Tetrachloroethylene, + Pyridine, or + Trichloroethylene at (298.15, 303.15, and 308.15) K
• Densities and Viscosities of Binary Liquid Mixtures of Trichloroethylene and Tetrachloroethylene with Some Polar and Nonpolar Solvents
• Density, Viscosity, Refractive Index, and Speed of Sound for Binary Mixtures of 1,4-Dioxane with Different Organic Liquids at (298.15, 303.15, and 308.15) K
• Liquid-Liquid Equilibria for the Ternary Systems of (Water + Tetrahydrofuran + Polar Solvent) at 298.15 K
• Studies of Viscosities and Excess Molar Volumes of the Binary Mixtures of 1-Heptanol + 1,2-Dichloroethane, + 1,1,1-Trichloroethane, + 1,1,2,2-Tetrachloroethane, + Trichloroethylene and Tetrachloroethylene at (293.15, 298.15, and 303.15) K for the Liquid Region and at Ambient Pressure
• Activity Coefficients at Infinite Dilution in 1-Alkyl-3-methylimidazolium Tetrafluoroborate Ionic Liquids
• Activity Coefficients at Infinite Dilution in Methylimidazolium Nitrate Ionic Liquids
• Densities, Excess Molar Volumes, Viscosity, and Refractive Indices of Binary Mixtures of Ethanoic Acid and Trichloroethylene with Dimethylbenzenes at Different Temperatures
• Determination of Henry's Law Constants Using Internal Standards with Benchmark Values
• Isobaric Vapor Liquid Equilibrium for Dimethylsulfoxide with Chloroethanes and Chloroethenes
• Henry s Law Constants for Fragrance and Organic Solvent Compounds in Aqueous Industrial Surfactants
• Solubilities of Stearic Acid in Organic Solvents and in Azeotropic Solvent Mixtures
• Solubilities of Palmitic Acid in Pure Solvents and Its Mixtures
• Solubilities of Lauric Acid in n-Hexane, Acetone, Propanol, 2-Propanol, 1-Bromopropane, and Trichloroethylene from (279.0 to 315.3) K
• Vapor-Liquid Equilibria of Binary Mixtures Formed by Hexan-1-ol with Chloroethanes and Chloroethenes at 95.6 kPa
• Excess Molar Volumes and Sound Speed in (Phenylacetonitrile + 1,2-Dichloroethane), (Phenylacetonitrile + 1,1,2-Trichloroethane), (Phenylacetonitrile + 1,1,2,2-Tetrachloroethane), (Phenylacetonitrile + Trichloroethene), and (Phenylacetonitrile + Tetrachloroethene) at Temperatures of (303.15, 308.15, and 313.15) K
• Joback Method
• KDB
• Aqueous Solubility Prediction Method
• Estimated Solubility Method
• McGowan Method
• NIST Webbook
• NCMS SOLV-DB
• The Yaws Handbook of Vapor Pressure
• Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD

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