- InChI
- InChI=1S/C5H11NO2S/c1-9-3-2-4(6)5(7)8/h4H,2-3,6H2,1H3,(H,7,8)/t4-/m0/s1
- InChI Key
- FFEARJCKVFRZRR-BYPYZUCNSA-N
- Formula
- C5H11NO2S
- SMILES
- CSCC[C@H](N)C(=O)O
- Molecular Weight1
- 149.22
- CAS
- 63-68-3
- Other Names
-
- (S)-(+)-methionine
- (S)-2-amino-4-(methylthio)-butanoic acid, ,
- (S)-2-amino-4-(methylthio)butanoic acid
- .gamma.-methylthio-.alpha.-aminobutyric acid
- 2-Amino-4-methylthiobutanoic acid
- 2-Amino-4-methylthiobutanoic acid (S)-
- 2-amino-4-(methylthio)butyric acid
- Acimethin
- Butanoic acid, 2-amino-4-(methylthio)-, (S)-
- Butyric acid, 2-amino-4-(methylthio)-
- Cymethion
- L(-)-Amino-«gamma»-methylthiobutyric acid
- L-(-)-methionine
- L-.alpha.-amino-.gamma.-methylthiobutyric acid
- L-2-Amino-4-(methylthio)butyric acid
- L-Homocysteine, S-methyl-
- L-«alpha»-Amino-«gamma»-methylmercaptobutyric acid
- L-«gamma»-Methylthio-«alpha»-aminobutyric acid
- Liquimeth
- Met
- Methionine
- Methionine, L-
- NSC 22946
- S-methionine
- h-Met-oh
- «gamma»-Methylthio-«alpha»-aminobutyric acid
- PAff : Proton affinity (kJ/mol).
- BasG : Gas basicity (kJ/mol).
- ΔcH°solid : Standard solid enthalpy of combustion (kJ/mol).
- Cp,gas : Ideal gas heat capacity (J/mol×K).
- ΔfH°gas : Enthalpy of formation at standard conditions (kJ/mol).
- ΔfH°solid : Solid phase enthalpy of formation at standard conditions (kJ/mol).
- ΔfusH° : Enthalpy of fusion at standard conditions (kJ/mol).
- ΔsubH° : Enthalpy of sublimation at standard conditions (kJ/mol).
- ΔsubH : Enthalpy of sublimation at a given temperature (kJ/mol).
- ΔvapH : Enthalpy of vaporization at a given temperature (kJ/mol).
- IE : Ionization energy (eV).
- log10WS : Log10 of Water solubility in mol/l.
- logPoct/wat : Octanol/Water partition coefficient.
- McVol : McGowan's characteristic volume (ml/mol).
- Pvap : Vapor pressure (kPa).
- Tfus : Normal melting (fusion) point (K).
- 1: Molecular weight from the IUPAC atomic weights tables.
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Physical Properties
| Property | Value | Unit | Source |
|---|---|---|---|
| PAff | 935.40 | kJ/mol | NIST |
| BasG | 901.50 | kJ/mol | NIST |
| ΔcH°solid | [-3564.11; -3176.00] | kJ/mol |
|
| ΔcH°solid | -3564.11 ± 0.61 | kJ/mol | NIST |
| ΔcH°solid | -3176.00 ± 0.80 | kJ/mol | NIST |
| ΔfH°gas | -413.50 ± 4.10 | kJ/mol | NIST |
| ΔfH°solid | -577.50 ± 0.70 | kJ/mol | NIST |
| ΔfusH° | 24.65 | kJ/mol | Joback Calculated Property |
| ΔsubH° | [164.00; 164.00] | kJ/mol |
|
| ΔsubH° | 164.00 ± 4.00 | kJ/mol | NIST |
| ΔsubH° | 164.00 ± 4.00 | kJ/mol | NIST |
| IE | [8.30; 9.00] | eV |
|
| IE | 8.30 | eV | NIST |
| IE | 8.63 ± 0.10 | eV | NIST |
| IE | 9.00 | eV | NIST |
| IE | 8.65 | eV | NIST |
| log10WS | -0.34 | Relay (1.0) Calculated Property | |
| logPoct/wat | 0.151 | Crippen Calculated Property | |
| McVol | 115.080 | ml/mol | McGowan Calculated Property |
| Tfus | 553.90 | K | Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value |
Cheméo can also estimate Normal Boiling Point Temperature, Critical Temperature, Critical Pressure, Critical Volume, Enthalpy of vaporization at standard conditions, Standard Gibbs free energy of formation, Acentric Factor for this compound, but they fall outside the models' validated range, so they are not shown here. Open the prediction tool to compute them on demand.
Temperature Dependent Properties
| Property | Value | Unit | Temperature (K) | Source |
|---|---|---|---|---|
| ΔsubH | [125.00; 125.00] | kJ/mol | [455.00; 474.00] |
|
| ΔsubH | 125.00 ± 0.80 | kJ/mol | 455.00 | NIST |
| ΔsubH | 125.00 | kJ/mol | 474.00 | NIST |
| ΔvapH | 139.00 | kJ/mol | 437.00 | Enthalpies of sublimation of L-methionine and DL-methionine: Knudsen's effusion mass spectrometric study |
Correlations
| Property | Value | Unit | Temperature (K) | Source |
|---|---|---|---|---|
| Cp,gas | [165.73; 351.16] | J/mol×K | [273.00; 1000.00] |
Joback Predicted correlation
|
| Equation | Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is Cp,gas in J/mol×K, T in K | |||
| Coefficient A | 2.73520e+01 | |||
| Coefficient B | 5.91810e-01 | |||
| Coefficient C | -3.27200e-04 | |||
| Coefficient D | 5.92000e-08 | |||
| Coefficient E | 0.00000e+00 | |||
| Temperature range, min. | 273.00 | |||
| Temperature range, max. | 1000.00 | |||
| Cp,gas | 165.73 | J/mol×K | 273.00 | Calculated Property |
| Cp,gas | 198.39 | J/mol×K | 353.78 | Calculated Property |
| Cp,gas | 227.60 | J/mol×K | 434.56 | Calculated Property |
| Cp,gas | 253.54 | J/mol×K | 515.33 | Calculated Property |
| Cp,gas | 276.41 | J/mol×K | 596.11 | Calculated Property |
| Cp,gas | 296.39 | J/mol×K | 676.89 | Calculated Property |
| Cp,gas | 313.66 | J/mol×K | 757.67 | Calculated Property |
| Cp,gas | 328.43 | J/mol×K | 838.44 | Calculated Property |
| Cp,gas | 340.86 | J/mol×K | 919.22 | Calculated Property |
| Cp,gas | 351.16 | J/mol×K | 1000.00 | Calculated Property |
| Property | Value | Unit | Temperature (K) | Source |
|---|---|---|---|---|
| Pvap | [1.33; 202.66] | kPa | [559.55; 688.22] |
The Yaws Handbook of Vapor Pressure
|
| Equation | ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K | |||
| Coefficient A | 2.71590e+01 | |||
| Coefficient B | -1.50359e+04 | |||
| Coefficient C | 0.00000e+00 | |||
| Temperature range, min. | 559.55 | |||
| Temperature range, max. | 688.22 | |||
| Pvap | 1.33 | kPa | 559.55 | Calculated Property |
| Pvap | 2.60 | kPa | 573.85 | Calculated Property |
| Pvap | 4.92 | kPa | 588.14 | Calculated Property |
| Pvap | 9.03 | kPa | 602.44 | Calculated Property |
| Pvap | 16.11 | kPa | 616.74 | Calculated Property |
| Pvap | 27.98 | kPa | 631.03 | Calculated Property |
| Pvap | 47.44 | kPa | 645.33 | Calculated Property |
| Pvap | 78.61 | kPa | 659.63 | Calculated Property |
| Pvap | 127.49 | kPa | 673.92 | Calculated Property |
| Pvap | 202.66 | kPa | 688.22 | Calculated Property |
Similar Compounds
Find more compounds similar to L-Methionine.
Mixtures
- L-Methionine + Water
- L-Methionine + Methyl Alcohol + Water
- L-Methionine + Ethanol + Water
- L-Methionine + Acetone + Water
- Sucrose + L-Methionine + Water
- L-Methionine + Hydrochloric acid + Water
- sodium hydroxide + L-Methionine + Water
- L-Methionine + Ethanol
Sources
- Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) ChEDL chemicals 1.5.2, from Bradley, J.-C.; Williams, A.; Lang, A. Jean-Claude Bradley Open Melting Point Dataset. Figshare, 2014 (CC0).
- Cheméo Relay (1.0)
- Cheméo Relay (1.0, beta) Beta: served but experimental, data-limited and below our cross-validation release bar; the Joback value is recommended where available.
- Crippen Method
- Crippen Method
- Surface tension and UV-visible investigations of aggregation and adsorption behavior of NaC and NaDC in water-amino acid mixtures
- Thermodynamics of proton dissociations from aqueous L-methionine at temperatures from (278.15 to 393.15) K, molalities from (0.0125 to 1.0) mol Ae kg 1, and at the pressure 0.35 MPa: Apparent molar heat capacities and apparent molar volumes of L-methionine, methioninium chloride, and sodium methioninate
- Study of solute solute and solute solvent interactions of l-methionine in aqueous-sucrose solutions at different temperatures
- Study of the interactions of PAMAM-NH2 G4 dendrimer with selected natural amino acids in aqueous solutions
- Effect of temperature and additives on the critical micelle concentration and thermodynamics of micelle formation of sodium dodecyl benzene sulfonate and dodecyltrimethylammonium bromide in aqueous solution: A conductometric study
- Conductivity and fluorescence studies on the micellization properties of sodium cholate and sodium deoxycholate in aqueous medium at different temperatures: Effect of selected amino acids
- Determination and correlation of solubility and thermodynamic properties of L-methionine in binary solvents of water + (methanol, ethanol, acetone)
- Enthalpies of sublimation of L-methionine and DL-methionine: Knudsen's effusion mass spectrometric study
- Thermochemistry of Zn(AA)SO4*H2O(s) (AA = l-?-valine and methionine)
- APPARENT MOLAR VOLUME, COMPRESSIBILITY AND VISCOMETRIC STUDIES OF SODIUM DODECYL BENZENE SULFONATE (SDBS) AND DODECYLTRIMETHYLAMMONIUM BROMIDE (DTAB) IN AQUEOUS AMINO ACID SOLUTIONS: A THERMO-ACOUSTIC APPROACH
- Volumetric, compressibility and viscometric studies on sodium cholate/sodium deoxycholate amino acid interactions in aqueous medium
- Influence of the composition of water organic mixtures and the properties of organic solvents on thermochemical characteristics of l-methionine dissolution at 298.15 K
- Solubility of the Proteinogenic a-Amino Acids in Water, Ethanol, and Ethanol-Water Mixtures
- Surface Tension of Aqueous Solutions of Small-Chain Amino and Organic Acids
- Solubility and Metastable Zone Width of the Methionine Enantiomers and Their Mixtures in Water
- Joback Method
- McGowan Method
- NIST Webbook
- The Yaws Handbook of Vapor Pressure
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