Chemical Properties of Hexane, tetradecafluoro- (CAS 355-42-0)

InChI

InChI=1S/C6F14/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20

InChI Key

ZJIJAJXFLBMLCK-UHFFFAOYSA-N

Formula

C6F14

SMILES

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

Molecular Weight¹

338.04

CAS

355-42-0

Other Names

• AF 0150
• Fluorinert FC72
• Flutec PP1
• Hexane, 1,1,1,2,2,3,3,4,4,5,5,6,6,6-tetradecafluoro-
• PP 1 (Fluorocarbon)
• Perflexane
• Perfluoro-compound FC-72
• flutec PP 1
• n-Perfluorohexane
• n-Tetradecafluorohexane
• perfluoro-n-hexane
• perfluorohexane
• tetradecafluorohexane

• ω : Acentric Factor.
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_fusH : Enthalpy of fusion at a given temperature (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• ν : Kinematic viscosity (m²/s).
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• ρ_c : Critical density (kg/m³).
• ρ_l : Liquid Density (kg/m³).
• c_sound,fluid : Speed of sound in fluid (m/s).
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• T_triple : Triple Point Temperature (K).
• V_c : Critical Volume (m³/kmol).
• V_m : Molar Volume (m³/mol).
• Z_c : Critical Compressibility.
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	0.5140		KDB
ΔfG°	-2710.66	kJ/mol	Joback Calculated Property
ΔfH°gas	-3003.77	kJ/mol	Relay (1.0) Calculated Property
ΔfusH°	9.93	kJ/mol	Joback Calculated Property
ΔvapH°	[31.40; 32.50]	kJ/mol
ΔvapH°	32.50 ± 0.10	kJ/mol	NIST
ΔvapH°	31.40	kJ/mol	NIST
ΔvapH°	32.40	kJ/mol	NIST
IE	12.07	eV	Relay (1.0) Calculated Property
logPoct/wat	4.652		Crippen Calculated Property
McVol	120.180	ml/mol	McGowan Calculated Property
Pc	[1868.00; 1905.00]	kPa
Pc	1868.00	kPa	KDB
Pc	1868.13 ± 20.00	kPa	NIST
Pc	1905.00	kPa	NIST
Pc	1868.10 ± 3.44	kPa	NIST
ρc	[557.77; 557.77]	kg/m3
ρc	557.77 ± 3.04	kg/m3	NIST
ρc	557.77 ± 5.58	kg/m3	NIST
Tboil	[329.80; 332.50]	K
Tboil	329.80	K	KDB
Tboil	332.20	K	NIST
Tboil	332.50 ± 0.50	K	NIST
Tboil	330.30	K	NIST
Tc	[447.65; 451.70]	K
Tc	448.77	K	KDB
Tc	448.77 ± 1.30	K	NIST
Tc	449.00	K	NIST
Tc	448.77 ± 0.20	K	NIST
Tc	Outlier 451.70 ± 0.50	K	NIST
Tc	447.65 ± 0.50	K	NIST
Tfus	[182.50; 187.10]	K
Tfus	186.00	K	KDB
Tfus	182.50 ± 0.50	K	NIST
Tfus	185.00 ± 1.00	K	NIST
Tfus	186.89 ± 0.06	K	NIST
Tfus	187.10 ± 0.10	K	NIST
Ttriple	[185.00; 187.45]	K
Ttriple	185.00 ± 2.00	K	NIST
Ttriple	187.45 ± 0.30	K	NIST
Vc	0.606	m3/kmol	KDB
Zc	0.3033810		KDB

Cheméo can also estimate Log10 of Water solubility in mol/l for this compound, but it falls outside the models' validated range, so it is not shown here. Open the prediction tool to compute it on demand.

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[263.70; 328.86]	J/mol×K	[307.08; 418.08]
Cp,gas	263.70	J/mol×K	307.08	Joback Calculated Property
Cp,gas	276.21	J/mol×K	325.58	Joback Calculated Property
Cp,gas	288.03	J/mol×K	344.08	Joback Calculated Property
Cp,gas	299.18	J/mol×K	362.58	Joback Calculated Property
Cp,gas	309.69	J/mol×K	381.08	Joback Calculated Property
Cp,gas	319.57	J/mol×K	399.58	Joback Calculated Property
Cp,gas	328.86	J/mol×K	418.08	Joback Calculated Property
Cp,liquid	[173.00; 274.00]	J/mol×K	[230.00; 300.00]
Cp,liquid	173.00	J/mol×K	230.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	187.00	J/mol×K	240.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	202.00	J/mol×K	250.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	216.00	J/mol×K	260.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	231.00	J/mol×K	270.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	240.20	J/mol×K	273.00	NIST
Cp,liquid	248.00	J/mol×K	273.00	NIST
Cp,liquid	235.00	J/mol×K	273.15	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	245.00	J/mol×K	280.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	260.00	J/mol×K	290.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	272.00	J/mol×K	298.15	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	274.00	J/mol×K	300.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
ΔfusH	6.84	kJ/mol	185.00	NIST
ΔvapH	[31.50; 34.40]	kJ/mol	[297.50; 441.00]
ΔvapH	34.40	kJ/mol	297.50	NIST
ΔvapH	31.50	kJ/mol	316.50	NIST
ΔvapH	33.40	kJ/mol	441.00	NIST
ν	[0.0000003; 0.0000004]	m2/s	[298.15; 318.15]
ν	0.0000004	m2/s	298.15	Viscosities of Liquid Fluorocompounds
ν	0.0000004	m2/s	303.15	Viscosities of Liquid Fluorocompounds
ν	0.0000004	m2/s	308.15	Viscosities of Liquid Fluorocompounds
ν	0.0000004	m2/s	313.15	Viscosities of Liquid Fluorocompounds
ν	0.0000003	m2/s	318.15	Viscosities of Liquid Fluorocompounds
Pvap	[18.78; 111.39]	kPa	[288.31; 333.10]
Pvap	18.78	kPa	288.31	Densities and Vapor Pressures of Highly Fluorinated Compounds
Pvap	23.58	kPa	293.22	Densities and Vapor Pressures of Highly Fluorinated Compounds
Pvap	29.28	kPa	298.09	Densities and Vapor Pressures of Highly Fluorinated Compounds
Pvap	36.19	kPa	302.98	Densities and Vapor Pressures of Highly Fluorinated Compounds
Pvap	44.38	kPa	307.97	Densities and Vapor Pressures of Highly Fluorinated Compounds
Pvap	54.56	kPa	313.17	Densities and Vapor Pressures of Highly Fluorinated Compounds
Pvap	65.86	kPa	318.15	Densities and Vapor Pressures of Highly Fluorinated Compounds
Pvap	78.91	kPa	323.13	Densities and Vapor Pressures of Highly Fluorinated Compounds
Pvap	94.08	kPa	328.11	Densities and Vapor Pressures of Highly Fluorinated Compounds
Pvap	111.39	kPa	333.10	Densities and Vapor Pressures of Highly Fluorinated Compounds
ρl	[1590.50; 1742.50]	kg/m3	[278.15; 328.15]
ρl	1742.50	kg/m3	278.15	Liquid Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol + Perfluorocarbon + Water or Methanol at 298.15 K
ρl	1728.30	kg/m3	283.15	Liquid Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol + Perfluorocarbon + Water or Methanol at 298.15 K
ρl	1713.80	kg/m3	288.15	Liquid Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol + Perfluorocarbon + Water or Methanol at 298.15 K
ρl	1699.20	kg/m3	293.15	Liquid Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol + Perfluorocarbon + Water or Methanol at 298.15 K
ρl	1667.00	kg/m3	298.15	Phase Equilibria for Perfluoroethane + (n-Perfluorohexane or n-Perfluorooctane) Binary Systems: Measurement and Modeling
ρl	1701.00	kg/m3	298.15	VLE measurements and modelling for the binary systems of (CF4 + C6F14) and (CF4 + C8F18)
ρl	1670.07	kg/m3	298.15	Liquid-liquid equilibrium data for binary perfluoroalkane (C6 and C8) + n-alkane systems
ρl	1684.40	kg/m3	298.15	Liquid Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol + Perfluorocarbon + Water or Methanol at 298.15 K
ρl	1669.40	kg/m3	303.15	Liquid Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol + Perfluorocarbon + Water or Methanol at 298.15 K
ρl	1654.10	kg/m3	308.15	Liquid Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol + Perfluorocarbon + Water or Methanol at 298.15 K
ρl	1638.60	kg/m3	313.15	Liquid Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol + Perfluorocarbon + Water or Methanol at 298.15 K
ρl	1622.90	kg/m3	318.15	Liquid Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol + Perfluorocarbon + Water or Methanol at 298.15 K
ρl	1606.40	kg/m3	323.15	Liquid Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol + Perfluorocarbon + Water or Methanol at 298.15 K
ρl	1590.50	kg/m3	328.15	Liquid Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol + Perfluorocarbon + Water or Methanol at 298.15 K
csound,fluid	[510.70; 571.89]	m/s	[278.15; 298.15]
csound,fluid	571.89	m/s	278.15	Properties of saturated fluorocarbons: Experimental data and modeling using perturbed-chain-SAFT
csound,fluid	540.31	m/s	288.15	Properties of saturated fluorocarbons: Experimental data and modeling using perturbed-chain-SAFT
csound,fluid	510.70	m/s	298.15	Properties of saturated fluorocarbons: Experimental data and modeling using perturbed-chain-SAFT
γ	[0.01; 0.01]	N/m	[283.15; 308.15]
γ	0.01	N/m	283.15	Surface Tension of Liquid Fluorocompounds
γ	0.01	N/m	288.15	Surface Tension of Liquid Fluorocompounds
γ	0.01	N/m	293.15	Surface Tension of Liquid Fluorocompounds
γ	0.01	N/m	298.15	Surface Tension of Liquid Fluorocompounds
γ	0.01	N/m	303.15	Surface Tension of Liquid Fluorocompounds
γ	0.01	N/m	308.15	Surface Tension of Liquid Fluorocompounds

Datasets

Molar volume, m3/mol

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Molar volume, m3/mol - Liquid
288.05	101.33	0.0002
Reference

Correlations

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 202.63]	kPa	[243.80; 353.65]	The Yaws Handbook of Vapor Pressure
Equation			ln(Pvp) = A + B/(T + C)
Coefficient A			1.49601e+01
Coefficient B			-3.09560e+03
Coefficient C			-3.28200e+01
Temperature range, min.			243.80
Temperature range, max.			353.65
Pvap	1.33	kPa	243.80	Calculated Property
Pvap	2.97	kPa	256.01	Calculated Property
Pvap	6.11	kPa	268.21	Calculated Property
Pvap	11.68	kPa	280.42	Calculated Property
Pvap	21.01	kPa	292.62	Calculated Property
Pvap	35.86	kPa	304.83	Calculated Property
Pvap	58.46	kPa	317.03	Calculated Property
Pvap	91.54	kPa	329.24	Calculated Property
Pvap	138.35	kPa	341.44	Calculated Property
Pvap	202.63	kPa	353.65	Calculated Property
Pvap	[7.27; 1736.48]	kPa	[270.00; 445.42]	KDB Vapor Pressure Data
Equation			ln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A			1.25737e+02
Coefficient B			-7.95388e+03
Coefficient C			-1.70953e+01
Coefficient D			1.93783e-05
Temperature range, min.			270.00
Temperature range, max.			445.42
Pvap	7.27	kPa	270.00	Calculated Property
Pvap	19.82	kPa	289.49	Calculated Property
Pvap	46.16	kPa	308.98	Calculated Property
Pvap	95.08	kPa	328.47	Calculated Property
Pvap	177.88	kPa	347.96	Calculated Property
Pvap	308.62	kPa	367.46	Calculated Property
Pvap	504.63	kPa	386.95	Calculated Property
Pvap	787.70	kPa	406.44	Calculated Property
Pvap	1185.92	kPa	425.93	Calculated Property
Pvap	1736.48	kPa	445.42	Calculated Property

Similar Compounds

Find more compounds similar to Hexane, tetradecafluoro-.

Mixtures

• n-Hexane + Hexane, tetradecafluoro-
• Hexane, tetradecafluoro- + Octane
• Hexane, tetradecafluoro- + 1H,1H,7H-Dodecafluoro-1-heptanol
• Hexane, tetradecafluoro- + Di-n-propyl ether
• Hexane, tetradecafluoro- + n-Butyl ether
• Hexane, tetradecafluoro- + Butane, 1-methoxy-
• Hexane, tetradecafluoro- + Butane, 1-ethoxy-
• Hexane, tetradecafluoro- + Ethyl ether
• Hexane, tetradecafluoro- + Methyl Alcohol
• Hexane, tetradecafluoro- + Acetone
• Toluene + Hexane, tetradecafluoro-
• Hexane, tetradecafluoro- + Carbon dioxide + Methyl Alcohol
• Hexane, tetradecafluoro- + Carbon dioxide + Acetone
• Toluene + Hexane, tetradecafluoro- + Carbon dioxide
• Hexane, tetradecafluoro- + Pentane
• Hexane, tetradecafluoro- + Heptane
• Heptane, 2-methyl- + Hexane, tetradecafluoro-
• Hexane, tetradecafluoro- + Cyclohexane
• Hexane, tetradecafluoro- + Tetrafluoromethane
• Hexane, tetradecafluoro- + Nonane

Find more mixtures with Hexane, tetradecafluoro-.

Sources

• KDB Vapor Pressure Data
• Cheméo Relay (1.0)
• Crippen Method
• Crippen Method
• Liquid-Liquid Coexistence Curve of n-Perfluorohexane - n-Hexane System
• Vapor liquid liquid equilibria of perfluorohexane +CO2 + methanol, +toluene, and +acetone at 313K
• Liquid liquid equilibrium of (1H,1H,7H-perfluoroheptan-1-ol + perfluoroalkane) binary mixtures
• Thermodynamic study of perfluorohexane + ether mixtures VLE, LLE, and HE
• Properties of saturated fluorocarbons: Experimental data and modeling using perturbed-chain-SAFT
• Liquid-liquid equilibrium data for binary perfluoroalkane (C6 and C8) + n-alkane systems
• Perfluoroalkanes and perfluoroalkylalkane surfactants in solution: Partial molar volumes in n-octane and hetero-SAFT-VR modelling
• Liquid-liquid equilibria containing fluorous solvents as environmentally benign solvent
• Viscosity of liquid systems involving hydrogenated and fluorinated substances: Liquid mixtures of (hexane + perfluorohexane)
• VLE measurements and modelling for the binary systems of (CF4 + C6F14) and (CF4 + C8F18)
• New experimental VLE data for the binary mixture of carbon dioxide + perfluorohexane (CO2 + C6F14) from 273 K to 333 K
• Thermodynamic study of (perfluoroalkane + alkane) mixtures: Excess and solvation enthalpies
• Isothermal Vapor-Liquid Equilibrium (VLE) and Vapor- Liquid-Liquid Equilibrium (VLLE) Data for Two Binary Systems Containing Perfluorohexane with Carbon Monoxide or Hydrogen Sulphide at (293, 313 and 333) K
• Phase Equilibria for Perfluoroethane + (n-Perfluorohexane or n-Perfluorooctane) Binary Systems: Measurement and Modeling
• Phase Separation in Binary Mixtures Containing Linear Perfluoroalkanes
• High-Pressure Vapor-Liquid Equilbria of Some Carbon Dioxide + Organic Binary Systems
• Densities and Vapor Pressures of Highly Fluorinated Compounds
• Surface Tension of Liquid Fluorocompounds
• Liquid - Liquid Equilibria for the Ternary Systems of Per fl uorohexane + Methyl Nona fl uorobutyl Ether + Toluene, + 1,4-Dioxane, or + Dimethylformamide at 298.15 K
• Liquid Liquid Equilibria for the Ternary Systems of Perfluorohexane or Perfluamine + Hydrofluoroether + Tetrahydrofuran at 298.15 K or 273.15 K
• Liquid Liquid Equilibria for the Ternary Systems of FC3283 + HFE7300 + Hexane, FC3283 + HFE7500 + Octane, and FC72 + HFE7100 + (Acetonitrile or Ethyl Acetate) at 273.15 K, 298.15 K, and 313.15 K
• Liquid Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol + Perfluorocarbon + Water or Methanol at 298.15 K
• Viscosities of Liquid Fluorocompounds
• Joback Method
• KDB
• McGowan Method
• NIST Webbook
• The Yaws Handbook of Vapor Pressure
• Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD

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