Chemical Properties of Perfluorotetradecane (CAS 307-62-0)

InChI

InChI=1S/C14F30/c15-1(16,3(19,20)5(23,24)7(27,28)9(31,32)11(35,36)13(39,40)41)2(17,18)4(21,22)6(25,26)8(29,30)10(33,34)12(37,38)14(42,43)44

InChI Key

HYZQZWDYBKVIRI-UHFFFAOYSA-N

Formula

C14F30

SMILES

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

Molecular Weight¹

738.10

CAS

307-62-0

Other Names

• tetradecane, triacontafluoro-
• triacontafluorotetradecane

• ω : Acentric Factor.
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• IE : Ionization energy (eV).
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• I_np : Non-polar retention indices.
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• V_c : Critical Volume (m³/kmol).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	0.7653		Relay (1.0) Calculated Property
ΔfG°	-5737.54	kJ/mol	Joback Calculated Property
ΔfH°gas	-6228.49	kJ/mol	Relay (1.0) Calculated Property
ΔfusH°	31.50	kJ/mol	Applications of Correlation Gas Chromatography and Transpiration Studies for the Evaluation of the Vaporization and Sublimation Enthalpies of Some Perfluorinated Hydrocarbons
ΔvapH°	64.65	kJ/mol	Relay (1.0) Calculated Property
IE	11.96	eV	Relay (1.0) Calculated Property
logPoct/wat	9.735		Crippen Calculated Property
McVol	261.220	ml/mol	McGowan Calculated Property
Pc	752.26	kPa	Joback Calculated Property
Inp	[644.00; 644.00]
Inp	644.00		NIST
Inp	644.00		NIST
Tboil	480.49	K	Relay (1.0) Calculated Property
Tc	572.56	K	Relay (1.0) Calculated Property
Tfus	[375.00; 377.40]	K
Tfus	377.40 ± 0.20	K	NIST
Tfus	375.00 ± 1.00	K	NIST
Vc	1.216	m3/kmol	Relay (1.0) Calculated Property

Cheméo can also estimate Log10 of Water solubility in mol/l for this compound, but it falls outside the models' validated range, so it is not shown here. Open the prediction tool to compute it on demand.

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[770.17; 853.10]	J/mol×K	[452.80; 556.47]
Cp,gas	770.17	J/mol×K	452.80	Joback Calculated Property
Cp,gas	786.48	J/mol×K	470.08	Joback Calculated Property
Cp,gas	801.74	J/mol×K	487.36	Joback Calculated Property
Cp,gas	816.00	J/mol×K	504.63	Joback Calculated Property
Cp,gas	829.28	J/mol×K	521.91	Joback Calculated Property
Cp,gas	841.63	J/mol×K	539.19	Joback Calculated Property
Cp,gas	853.10	J/mol×K	556.47	Joback Calculated Property

Similar Compounds

Find more compounds similar to Perfluorotetradecane.

Sources

• Cheméo Relay (1.0)
• Crippen Method
• Crippen Method
• Applications of Correlation Gas Chromatography and Transpiration Studies for the Evaluation of the Vaporization and Sublimation Enthalpies of Some Perfluorinated Hydrocarbons
• Joback Method
• McGowan Method
• NIST Webbook

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