Chemical Properties of Piperazine (CAS 110-85-0)

Piperazine

InChI
InChI=1S/C4H10N2/c1-2-6-4-3-5-1/h5-6H,1-4H2
InChI Key
GLUUGHFHXGJENI-UHFFFAOYSA-N
Formula
C4H10N2
SMILES
C1CNCCN1
Molecular Weight1
86.14
CAS
110-85-0
Other Names
  • 1,4-Diazacyclohexane
  • 1,4-Diethylenediamine
  • 1,4-Piperazine
  • Antiren
  • Asca-Trol No. 3
  • Diethylenediamine
  • Diethyleneimine
  • Dispermine
  • Eraverm
  • Hexahydro-1,4-diazine
  • Hexahydropyrazine
  • Lumbrical
  • NSC 474
  • Piperazidine
  • Piperazin
  • Piperazine, anhydrous
  • Pipersol
  • Pyrazine hexahydride
  • Pyrazine, hexahydro-
  • UN 2579
  • Upixon
  • Uvilon
  • Vermex
  • Worm-A-Ton
  • Wurmirazin
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Physical Properties

Property Value Unit Source
ω [0.2697; 0.3127]   Show Hide
ω 0.3127 PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
ω 0.2697 ChemSep v8.3 pure component data Compiled value
PAff 943.70 kJ/mol NIST
BasG 914.70 kJ/mol NIST
ΔcH°solid [-2961.40; -2957.60] kJ/mol Show Hide
ΔcH°solid -2961.40 ± 1.10 kJ/mol NIST
ΔcH°solid -2957.60 ± 1.60 kJ/mol NIST
μ 1.47 debye ChemSep v8.3 pure component data Compiled value
ΔfG° 170.00 kJ/mol ChemSep v8.3 pure component data Compiled value
ΔfH°gas [21.20; 25.00] kJ/mol Show Hide
ΔfH°gas 22.60 kJ/mol ChemSep v8.3 pure component data Compiled value
ΔfH°gas 25.00 ± 6.30 kJ/mol NIST
ΔfH°gas 21.20 kJ/mol NIST
ΔfH°solid [-45.60; -41.80] kJ/mol Show Hide
ΔfH°solid -41.80 ± 1.10 kJ/mol NIST
ΔfH°solid -45.60 ± 1.60 kJ/mol NIST
ΔfusH° 16.06 kJ/mol Joback Calculated Property
ΔsubH° [66.80; 67.00] kJ/mol Show Hide
ΔsubH° 67.00 ± 6.30 kJ/mol NIST
ΔsubH° 66.80 kJ/mol NIST
ΔvapH° 61.47 kJ/mol Relay (1.0) Calculated Property
IE [8.72; 8.98] eV Show Hide
IE 8.98 eV NIST
IE 8.72 eV NIST
log10WS 1.07 Aq. Solubility Prediction
logPoct/wat -0.821 Crippen Calculated Property
McVol 76.320 ml/mol McGowan Calculated Property
Pc [5420.00; 5800.00] kPa Show Hide
Pc 5420.00 kPa Critical Point and Vapor Pressure Measurements for Four Compounds by a Low Residence Time Flow Method
Pc 5600.00 kPa IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 9 Compiled value
Pc 5800.00 kPa PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Pc 5420.00 kPa ChemSep v8.3 pure component data Compiled value
Pc 5800.00 ± 200.00 kPa NIST
Ptriple 26.37 kPa ChemSep v8.3 pure component data Compiled value
ρc 321.97 ± 24.98 kg/m3 NIST
Inp [813.00; 870.00]   Show Hide
Inp 813.00 NIST
Inp 852.00 NIST
Inp 870.00 NIST
Inp 840.00 NIST
Inp 813.00 NIST
Inp 852.00 NIST
Ip [1386.00; 1440.00]   Show Hide
Ip 1386.00 NIST
Ip 1390.00 NIST
Ip 1415.00 NIST
Ip 1405.00 NIST
Ip 1410.00 NIST
Ip 1440.00 NIST
Ip 1391.00 NIST
Ip 1386.00 NIST
Ip 1440.00 NIST
Tboil [415.15; 419.20] K Show Hide
Tboil 419.15 K ChemSep v8.3 pure component data Compiled value
Tboil 419.20 K NIST
Tboil 418.15 ± 2.00 K NIST
Tboil 415.15 ± 1.50 K NIST
Tc [656.30; 661.00] K Show Hide
Tc 659.00 K IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 9 Compiled value
Tc 661.00 K PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tc 656.30 K ChemSep v8.3 pure component data Compiled value
Tc 661.00 ± 2.00 K NIST
Tfus [379.15; 384.55] K Show Hide
Tfus 379.15 K Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Tfus 379.15 K ChemSep v8.3 pure component data Compiled value
Tfus 380.48 K Aq. Solubility Prediction
Tfus 383.20 ± 0.60 K NIST
Tfus 383.46 ± 0.30 K NIST
Tfus 384.55 ± 0.20 K NIST
Ttriple [379.15; 384.60] K Show Hide
Ttriple 379.15 K ChemSep v8.3 pure component data Compiled value
Ttriple 384.60 ± 0.30 K NIST
UQi 2.95 ChemSep v8.3 pure component data Compiled value
URi 3.76 ChemSep v8.3 pure component data Compiled value
Vc [0.267; 0.269] m3/kmol Show Hide
Vc 0.269 m3/kmol IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 9 Compiled value
Vc 0.267 m3/kmol PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Vc 0.267 m3/kmol ChemSep v8.3 pure component data Compiled value
Zc [0.2652000; 0.2840000]   Show Hide
Zc 0.2840000 IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 9 Compiled value
Zc 0.2652000 ChemSep v8.3 pure component data Compiled value
Zra 0.27 ChemSep v8.3 pure component data Compiled value

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,liquid [216.30; 237.00] J/mol×K [393.20; 413.20] Show Hide
Cp,liquid 216.30 J/mol×K 393.20 Liquid heat capacity of the solvent system (piperazine + n-methyldiethanolamine + water)
Cp,liquid 218.70 J/mol×K 398.20 Liquid heat capacity of the solvent system (piperazine + n-methyldiethanolamine + water)
Cp,liquid 220.50 J/mol×K 403.20 Liquid heat capacity of the solvent system (piperazine + n-methyldiethanolamine + water)
Cp,liquid 222.80 J/mol×K 408.20 Liquid heat capacity of the solvent system (piperazine + n-methyldiethanolamine + water)
Cp,liquid 237.00 J/mol×K 413.00 NIST
Cp,liquid 225.00 J/mol×K 413.20 Liquid heat capacity of the solvent system (piperazine + n-methyldiethanolamine + water)
Psub [6.50e-03; 0.37] kPa [279.48; 321.12] Show Hide
Psub 6.50e-03 kPa 279.48 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Psub 0.01 kPa 286.78 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Psub 0.01 kPa 286.85 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Psub 0.03 kPa 292.58 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Psub 0.05 kPa 299.16 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Psub 0.08 kPa 304.27 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Psub 0.12 kPa 308.37 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Psub 0.20 kPa 313.57 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Psub 0.30 kPa 318.25 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Psub 0.31 kPa 318.69 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols
Psub 0.37 kPa 321.12 Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols

Correlations

Property Value Unit Temperature (K) Source
Cp,gas [110.32; 299.79] J/mol×K [273.00; 1500.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is Cp,gas in J/mol×K, T in K
Coefficient A6.84630e+01
Coefficient B-7.44160e+02
Coefficient C6.64824e+00
Coefficient D-7.36980e-04
Coefficient E1.76520e-07
Temperature range, min.273.00
Temperature range, max.1500.00
Cp,gas 110.32 J/mol×K 273.00 Calculated Property
Cp,gas 163.87 J/mol×K 409.33 Calculated Property
Cp,gas 207.52 J/mol×K 545.67 Calculated Property
Cp,gas 238.60 J/mol×K 682.00 Calculated Property
Cp,gas 259.79 J/mol×K 818.33 Calculated Property
Cp,gas 274.09 J/mol×K 954.67 Calculated Property
Cp,gas 283.80 J/mol×K 1091.00 Calculated Property
Cp,gas 290.60 J/mol×K 1227.33 Calculated Property
Cp,gas 295.66 J/mol×K 1363.67 Calculated Property
Cp,gas 299.79 J/mol×K 1500.00 Calculated Property
Property Value Unit Temperature (K) Source
Cp,liquid [167.76; 333.98] J/mol×K [300.00; 638.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A + B·T + C·T² + D·T³ + E·T⁴
Y is Cp,liquid in J/mol×K, T in K
Coefficient A3.28863e+01
Coefficient B3.46619e-01
Coefficient C4.73406e-04
Coefficient D-4.34168e-07
Coefficient E0.00000e+00
Temperature range, min.300.00
Temperature range, max.638.00
Cp,liquid 167.76 J/mol×K 300.00 Calculated Property
Cp,liquid 187.13 J/mol×K 337.56 Calculated Property
Cp,liquid 206.60 J/mol×K 375.11 Calculated Property
Cp,liquid 226.03 J/mol×K 412.67 Calculated Property
Cp,liquid 245.28 J/mol×K 450.22 Calculated Property
Cp,liquid 264.21 J/mol×K 487.78 Calculated Property
Cp,liquid 282.68 J/mol×K 525.33 Calculated Property
Cp,liquid 300.56 J/mol×K 562.89 Calculated Property
Cp,liquid 317.70 J/mol×K 600.44 Calculated Property
Cp,liquid 333.98 J/mol×K 638.00 Calculated Property
Property Value Unit Temperature (K) Source
η [0.0003072; 0.0000872] Pa×s [379.15; 556.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = exp(A + B/T + C·ln(T) + D·T^E)
Y is η in Pa×s, T in K
Coefficient A2.43410e+01
Coefficient B1.05420e+02
Coefficient C-5.65370e+00
Coefficient D6.01090e-06
Coefficient E2.00000e+00
Temperature range, min.379.15
Temperature range, max.556.00
η 0.0003072 Pa×s 379.15 Calculated Property
η 0.0002496 Pa×s 398.80 Calculated Property
η 0.0002069 Pa×s 418.45 Calculated Property
η 0.0001746 Pa×s 438.10 Calculated Property
η 0.0001499 Pa×s 457.75 Calculated Property
η 0.0001307 Pa×s 477.40 Calculated Property
η 0.0001158 Pa×s 497.05 Calculated Property
η 0.0001040 Pa×s 516.70 Calculated Property
η 0.0000946 Pa×s 536.35 Calculated Property
η 0.0000872 Pa×s 556.00 Calculated Property
Property Value Unit Temperature (K) Source
ΔvapH [45.38; 14.75] kJ/mol [379.15; 638.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A·(1 − Tr)^(B + C·Tr + D·Tr² + E·Tr³), Tr = T/Tc
Y is ΔvapH in kJ/mol, T in K
Coefficient A6.69450e+01
Coefficient B9.96020e-01
Coefficient C-2.00690e+00
Coefficient D2.40180e+00
Coefficient E-9.71290e-01
Critical temperature, Tc (K)6.56300e+02
Temperature range, min.379.15
Temperature range, max.638.00
ΔvapH 45.38 kJ/mol 379.15 Calculated Property
ΔvapH 43.52 kJ/mol 407.91 Calculated Property
ΔvapH 41.45 kJ/mol 436.67 Calculated Property
ΔvapH 39.15 kJ/mol 465.43 Calculated Property
ΔvapH 36.59 kJ/mol 494.19 Calculated Property
ΔvapH 33.71 kJ/mol 522.96 Calculated Property
ΔvapH 30.43 kJ/mol 551.72 Calculated Property
ΔvapH 26.59 kJ/mol 580.48 Calculated Property
ΔvapH 21.80 kJ/mol 609.24 Calculated Property
ΔvapH 14.75 kJ/mol 638.00 Calculated Property
Property Value Unit Temperature (K) Source
Pvap [1.33; 202.66] kPa [316.52; 444.19] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.49629e+01
Coefficient B-3.59933e+03
Coefficient C-7.12570e+01
Temperature range, min.316.52
Temperature range, max.444.19
Pvap 1.33 kPa 316.52 Calculated Property
Pvap 2.97 kPa 330.71 Calculated Property
Pvap 6.11 kPa 344.89 Calculated Property
Pvap 11.67 kPa 359.08 Calculated Property
Pvap 21.01 kPa 373.26 Calculated Property
Pvap 35.86 kPa 387.45 Calculated Property
Pvap 58.46 kPa 401.63 Calculated Property
Pvap 91.54 kPa 415.82 Calculated Property
Pvap 138.36 kPa 430.00 Calculated Property
Pvap 202.66 kPa 444.19 Calculated Property
Pvap [25.56; 5536.97] kPa [379.15; 638.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = exp(A + B/T + C·ln(T) + D·T^E)
Y is Pvap in kPa, T in K
Coefficient A1.36362e+02
Coefficient B-1.12450e+04
Coefficient C-1.76570e+01
Coefficient D9.62360e-06
Coefficient E2.00000e+00
Temperature range, min.379.15
Temperature range, max.638.00
Pvap 25.56 kPa 379.15 Calculated Property
Pvap 70.75 kPa 407.91 Calculated Property
Pvap 164.94 kPa 436.67 Calculated Property
Pvap 337.08 kPa 465.43 Calculated Property
Pvap 622.21 kPa 494.19 Calculated Property
Pvap 1061.48 kPa 522.96 Calculated Property
Pvap 1703.59 kPa 551.72 Calculated Property
Pvap 2608.32 kPa 580.48 Calculated Property
Pvap 3852.20 kPa 609.24 Calculated Property
Pvap 5536.97 kPa 638.00 Calculated Property
Property Value Unit Temperature (K) Source
ρl [898.85; 375.32] kg/m3 [379.15; 638.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A / B^(1 + (1 − T/C)^D)
Y is ρl in kg/m3, T in K
Coefficient A1.21227e+02
Coefficient B3.23000e-01
Coefficient C6.38000e+02
Coefficient D2.85710e-01
Temperature range, min.379.15
Temperature range, max.638.00
ρl 898.85 kg/m3 379.15 Calculated Property
ρl 873.24 kg/m3 407.91 Calculated Property
ρl 846.07 kg/m3 436.67 Calculated Property
ρl 816.95 kg/m3 465.43 Calculated Property
ρl 785.33 kg/m3 494.19 Calculated Property
ρl 750.32 kg/m3 522.96 Calculated Property
ρl 710.41 kg/m3 551.72 Calculated Property
ρl 662.51 kg/m3 580.48 Calculated Property
ρl 598.21 kg/m3 609.24 Calculated Property
ρl 375.32 kg/m3 638.00 Calculated Property
Property Value Unit Temperature (K) Source
γ [0.03; 0.00] N/m [273.00; 656.30] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A·(1 − Tr)^(B + C·Tr + D·Tr² + E·Tr³), Tr = T/Tc
Y is γ in N/m, T in K
Coefficient A5.33278e-02
Coefficient B1.23200e+00
Coefficient C0.00000e+00
Coefficient D0.00000e+00
Coefficient E0.00000e+00
Critical temperature, Tc (K)6.56300e+02
Temperature range, min.273.00
Temperature range, max.656.30
γ 0.03 N/m 273.00 Calculated Property
γ 0.02 N/m 315.59 Calculated Property
γ 0.02 N/m 358.18 Calculated Property
γ 0.02 N/m 400.77 Calculated Property
γ 0.01 N/m 443.36 Calculated Property
γ 0.01 N/m 485.94 Calculated Property
γ 0.01 N/m 528.53 Calculated Property
γ 0.00 N/m 571.12 Calculated Property
γ 0.00 N/m 613.71 Calculated Property
γ 0.00 N/m 656.30 Calculated Property
Property Value Unit Temperature (K) Source
λgas [0.01; 0.09] W/m×K [274.00; 1000.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A·T^B / (1 + C/T + D/T²)
Y is λgas in W/m×K, T in K
Coefficient A1.48660e-03
Coefficient B6.31900e-01
Coefficient C-1.15510e+01
Coefficient D3.45800e+05
Temperature range, min.274.00
Temperature range, max.1000.00
λgas 0.01 W/m×K 274.00 Calculated Property
λgas 0.02 W/m×K 354.67 Calculated Property
λgas 0.02 W/m×K 435.33 Calculated Property
λgas 0.03 W/m×K 516.00 Calculated Property
λgas 0.04 W/m×K 596.67 Calculated Property
λgas 0.05 W/m×K 677.33 Calculated Property
λgas 0.06 W/m×K 758.00 Calculated Property
λgas 0.07 W/m×K 838.67 Calculated Property
λgas 0.08 W/m×K 919.33 Calculated Property
λgas 0.09 W/m×K 1000.00 Calculated Property
Property Value Unit Temperature (K) Source
λliquid [0.12; 0.11] W/m×K [379.15; 419.15] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is λliquid in W/m×K, T in K
Coefficient A2.92110e-02
Coefficient B-3.34850e+02
Coefficient C8.60340e-01
Coefficient D-7.33430e-03
Coefficient E2.93170e-06
Temperature range, min.379.15
Temperature range, max.419.15
λliquid 0.12 W/m×K 379.15 Calculated Property
λliquid 0.12 W/m×K 383.59 Calculated Property
λliquid 0.12 W/m×K 388.04 Calculated Property
λliquid 0.12 W/m×K 392.48 Calculated Property
λliquid 0.12 W/m×K 396.93 Calculated Property
λliquid 0.12 W/m×K 401.37 Calculated Property
λliquid 0.11 W/m×K 405.82 Calculated Property
λliquid 0.11 W/m×K 410.26 Calculated Property
λliquid 0.11 W/m×K 414.71 Calculated Property
λliquid 0.11 W/m×K 419.15 Calculated Property

Similar Compounds

1,2-Ethanediamine, N,N'-diethyl-. 1,2-Ethanediamine, N-ethyl-N'-methyl-. 1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-. Tetraethylenepentamine. 1,2-Ethanediamine, N-(2-aminoethyl)-. 1,2-Ethanediamine, N-ethyl-. Sym-Dimethylethylene diamine. 1,2-Ethanediamine, N'-ethyl-N,N-dimethyl-. Piperazine, 1-methyl-. 1-Ethylpiperazine. Dipiperazinylethane. 1,2-Ethanediamine, N,N,N'-triethyl-. N-[(2-Aminoethyl)2-aminoethyl]piperazine. 2-((2-[(2-Hydroxyethyl)amino]ethyl)amino)ethanol. 1-Piperazineethanamine.

Find more compounds similar to Piperazine.

Mixtures

Find more mixtures with Piperazine.

Sources

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