- InChI
- InChI=1S/C4F10/c5-1(6,3(9,10)11)2(7,8)4(12,13)14
- InChI Key
- KAVGMUDTWQVPDF-UHFFFAOYSA-N
- Formula
- C4F10
- SMILES
- FC(F)(F)C(F)(F)C(F)(F)C(F)(F)F
- Molecular Weight1
- 238.03
- CAS
- 355-25-9
- Other Names
-
- Perfluoro-n-butane
- decafluorobutane
- perfluorobutane
- ω : Acentric Factor.
- Cp,gas : Ideal gas heat capacity (J/mol×K).
- Cp,liquid : Liquid phase heat capacity (J/mol×K).
- ΔfG° : Standard Gibbs free energy of formation (kJ/mol).
- ΔfH°gas : Enthalpy of formation at standard conditions (kJ/mol).
- ΔfusH° : Enthalpy of fusion at standard conditions (kJ/mol).
- ΔvapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
- ΔvapH : Enthalpy of vaporization at a given temperature (kJ/mol).
- IE : Ionization energy (eV).
- logPoct/wat : Octanol/Water partition coefficient.
- McVol : McGowan's characteristic volume (ml/mol).
- Pc : Critical Pressure (kPa).
- Pvap : Vapor pressure (kPa).
- ρc : Critical density (kg/m3).
- ρl : Liquid Density (kg/m3).
- csound,fluid : Speed of sound in fluid (m/s).
- Tboil : Normal Boiling Point Temperature (K).
- Tc : Critical Temperature (K).
- Tfus : Normal melting (fusion) point (K).
- Ttriple : Triple Point Temperature (K).
- Vc : Critical Volume (m3/kmol).
- Zc : Critical Compressibility.
- 1: Molecular weight from the IUPAC atomic weights tables.
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Physical Properties
| Property | Value | Unit | Source |
|---|---|---|---|
| ω | [0.3720; 0.3740] |
|
|
| ω | 0.3720 | PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value | |
| ω | 0.3740 | KDB | |
| ΔfG° | -1953.94 | kJ/mol | Joback Calculated Property |
| ΔfH°gas | -2184.99 | kJ/mol | Relay (1.0) Calculated Property |
| ΔfusH° | 7.26 | kJ/mol | Joback Calculated Property |
| ΔvapH° | 23.60 | kJ/mol | Relay (1.0) Calculated Property |
| IE | 12.48 | eV | Relay (1.0) Calculated Property |
| logPoct/wat | 3.382 | Crippen Calculated Property | |
| McVol | 84.920 | ml/mol | McGowan Calculated Property |
| Pc | [2289.95; 2323.38] | kPa |
|
| Pc | 2320.00 | kPa | IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 10 Compiled value |
| Pc | 2289.95 | kPa | PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value |
| Pc | 2323.00 | kPa | KDB |
| Pc | 2323.38 ± 10.13 | kPa | NIST |
| ρc | 599.83 ± 10.00 | kg/m3 | NIST |
| Tboil | [271.00; 277.20] | K |
|
| Tboil | 271.20 | K | KDB |
| Tboil | 271.00 | K | NIST |
| Tboil | 277.20 | K | NIST |
| Tboil | 271.20 ± 0.50 | K | NIST |
| Tboil | 271.15 ± 0.10 | K | NIST |
| Tc | [385.84; 386.40] | K |
|
| Tc | 386.20 | K | IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 10 Compiled value |
| Tc | 385.84 | K | PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value |
| Tc | 386.40 | K | KDB |
| Tc | 386.35 ± 0.20 | K | NIST |
| Tfus | [144.00; 144.90] | K |
|
| Tfus | 144.05 | K | Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value |
| Tfus | 144.90 | K | KDB |
| Tfus | 144.00 ± 1.00 | K | NIST |
| Ttriple | 144.97 | K | Staveley, Lobo and Calado (1981), triple points Compiled value |
| Vc | [0.372; 0.378] | m3/kmol |
|
| Vc | 0.378 | m3/kmol | IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 10 Compiled value |
| Vc | 0.372 | m3/kmol | PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value |
| Vc | 0.378 | m3/kmol | KDB |
| Zc | [0.2730000; 0.2733170] |
|
|
| Zc | 0.2730000 | IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 10 Compiled value | |
| Zc | 0.2733170 | KDB |
Cheméo can also estimate Log10 of Water solubility in mol/l for this compound, but it falls outside the models' validated range, so it is not shown here. Open the prediction tool to compute it on demand.
Temperature Dependent Properties
Datasets
Speed of sound, m/s
| Fixed | Measured | |
|---|---|---|
| Temperature, K - Gas | Pressure, kPa - Gas | Speed of sound, m/s - Gas |
| 248.70 | 10.00 | 95.1 |
| 248.70 | 20.00 | 94.56 |
| 248.70 | 30.00 | 93.98 |
| 257.70 | 10.00 | 96.57 |
| 257.70 | 20.00 | 96.22 |
| 257.70 | 30.00 | 95.7 |
| 257.70 | 50.00 | 94.78 |
| 271.30 | 10.00 | 99.26 |
| 271.30 | 20.00 | 98.71 |
| 271.30 | 30.00 | 98.33 |
| 271.30 | 50.00 | 97.39 |
| 271.30 | 70.00 | 96.39 |
| 271.30 | 100.00 | 94.79 |
| 281.50 | 10.00 | 101.05 |
| 281.50 | 20.00 | 100.64 |
| 281.50 | 30.00 | 100.23 |
| 281.50 | 50.00 | 99.38 |
| 281.50 | 70.00 | 98.4 |
| 281.50 | 100.00 | 97.04 |
| 281.50 | 150.00 | 95.08 |
| 293.10 | 10.00 | 103.02 |
| 293.10 | 20.00 | 102.7 |
| 293.10 | 30.00 | 102.37 |
| 293.10 | 50.00 | 101.71 |
| 293.10 | 70.00 | 100.86 |
| 293.10 | 100.00 | 99.66 |
| 293.10 | 150.00 | 97.68 |
| 293.10 | 200.00 | 95.63 |
| 303.10 | 10.00 | 104.78 |
| 303.10 | 20.00 | 104.57 |
| 303.10 | 30.00 | 104.25 |
| 303.10 | 50.00 | 103.35 |
| 303.10 | 70.00 | 103.06 |
| 303.10 | 100.00 | 103.05 |
| 303.10 | 150.00 | 99.91 |
| 303.10 | 200.00 | 98.41 |
| 303.10 | 250.00 | 96.5 |
| 303.10 | 300.00 | 94.89 |
| Reference | ||
Correlations
| Property | Value | Unit | Temperature (K) | Source |
|---|---|---|---|---|
| Cp,gas | [166.48; 302.27] | J/mol×K | [273.00; 1000.00] |
Joback Predicted correlation
|
| Equation | Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is Cp,gas in J/mol×K, T in K | |||
| Coefficient A | -3.77300e+01 | |||
| Coefficient B | 1.00500e+00 | |||
| Coefficient C | -1.04500e-03 | |||
| Coefficient D | 3.80000e-07 | |||
| Coefficient E | 0.00000e+00 | |||
| Temperature range, min. | 273.00 | |||
| Temperature range, max. | 1000.00 | |||
| Cp,gas | 166.48 | J/mol×K | 273.00 | Calculated Property |
| Cp,gas | 203.85 | J/mol×K | 353.78 | Calculated Property |
| Cp,gas | 232.85 | J/mol×K | 434.56 | Calculated Property |
| Cp,gas | 254.67 | J/mol×K | 515.33 | Calculated Property |
| Cp,gas | 270.52 | J/mol×K | 596.11 | Calculated Property |
| Cp,gas | 281.60 | J/mol×K | 676.89 | Calculated Property |
| Cp,gas | 289.11 | J/mol×K | 757.67 | Calculated Property |
| Cp,gas | 294.26 | J/mol×K | 838.44 | Calculated Property |
| Cp,gas | 298.25 | J/mol×K | 919.22 | Calculated Property |
| Cp,gas | 302.27 | J/mol×K | 1000.00 | Calculated Property |
| Property | Value | Unit | Temperature (K) | Source |
|---|---|---|---|---|
| Pvap | [1.33; 2340.36] | kPa | [196.90; 386.33] |
The Yaws Handbook of Vapor Pressure
|
| Equation | ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K | |||
| Coefficient A | 1.42719e+01 | |||
| Coefficient B | -2.30981e+03 | |||
| Coefficient C | -3.17290e+01 | |||
| Temperature range, min. | 196.90 | |||
| Temperature range, max. | 386.33 | |||
| Pvap | 1.33 | kPa | 196.90 | Calculated Property |
| Pvap | 6.48 | kPa | 217.95 | Calculated Property |
| Pvap | 22.82 | kPa | 239.00 | Calculated Property |
| Pvap | 63.76 | kPa | 260.04 | Calculated Property |
| Pvap | 149.76 | kPa | 281.09 | Calculated Property |
| Pvap | 307.97 | kPa | 302.14 | Calculated Property |
| Pvap | 570.70 | kPa | 323.19 | Calculated Property |
| Pvap | 973.23 | kPa | 344.23 | Calculated Property |
| Pvap | 1551.58 | kPa | 365.28 | Calculated Property |
| Pvap | 2340.36 | kPa | 386.33 | Calculated Property |
| Pvap | [2.12e-03; 2284.39] | kPa | [144.95; 386.35] |
KDB Vapor Pressure Data
|
| Equation | ln(Y) = A + B/T + C·ln(T) + D·T² + E/T² Y is Pvap in kPa, T in K | |||
| Coefficient A | 7.19638e+01 | |||
| Coefficient B | -4.91335e+03 | |||
| Coefficient C | -8.93526e+00 | |||
| Coefficient D | 1.14729e-05 | |||
| Coefficient E | 0.00000e+00 | |||
| Temperature range, min. | 144.95 | |||
| Temperature range, max. | 386.35 | |||
| Pvap | 2.12e-03 | kPa | 144.95 | Calculated Property |
| Pvap | 0.10 | kPa | 171.77 | Calculated Property |
| Pvap | 1.49 | kPa | 198.59 | Calculated Property |
| Pvap | 10.37 | kPa | 225.42 | Calculated Property |
| Pvap | 44.67 | kPa | 252.24 | Calculated Property |
| Pvap | 138.68 | kPa | 279.06 | Calculated Property |
| Pvap | 342.43 | kPa | 305.88 | Calculated Property |
| Pvap | 718.02 | kPa | 332.71 | Calculated Property |
| Pvap | 1337.39 | kPa | 359.53 | Calculated Property |
| Pvap | 2284.39 | kPa | 386.35 | Calculated Property |
| Pvap | [16.63; 93.80] | kPa | [233.27; 269.24] |
NIST
|
| Equation | ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K | |||
| Coefficient A | 1.41436e+01 | |||
| Coefficient B | -2.26249e+03 | |||
| Coefficient C | -3.36240e+01 | |||
| Reference | Brown and Mears, 1958, 2 | |||
| Comment | Coefficents calculated by NIST from author's data. | |||
| Temperature range, min. | 233.27 | |||
| Temperature range, max. | 269.24 | |||
| Pvap | 16.63 | kPa | 233.27 | Calculated Property |
| Pvap | 20.77 | kPa | 237.27 | Calculated Property |
| Pvap | 25.72 | kPa | 241.26 | Calculated Property |
| Pvap | 31.60 | kPa | 245.26 | Calculated Property |
| Pvap | 38.52 | kPa | 249.26 | Calculated Property |
| Pvap | 46.63 | kPa | 253.25 | Calculated Property |
| Pvap | 56.06 | kPa | 257.25 | Calculated Property |
| Pvap | 66.95 | kPa | 261.25 | Calculated Property |
| Pvap | 79.48 | kPa | 265.24 | Calculated Property |
| Pvap | 93.80 | kPa | 269.24 | Calculated Property |
| Pvap | [16.13; 63.58] | kPa | [233.22; 259.94] |
NIST
|
| Equation | ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K | |||
| Coefficient A | 1.33351e+01 | |||
| Coefficient B | -1.88825e+03 | |||
| Coefficient C | -5.43110e+01 | |||
| Reference | Simons and Mausteller, 1952, 2 | |||
| Comment | Coefficents calculated by NIST from author's data. | |||
| Temperature range, min. | 233.22 | |||
| Temperature range, max. | 259.94 | |||
| Pvap | 16.13 | kPa | 233.22 | Calculated Property |
| Pvap | 19.17 | kPa | 236.19 | Calculated Property |
| Pvap | 22.64 | kPa | 239.16 | Calculated Property |
| Pvap | 26.61 | kPa | 242.13 | Calculated Property |
| Pvap | 31.12 | kPa | 245.10 | Calculated Property |
| Pvap | 36.21 | kPa | 248.06 | Calculated Property |
| Pvap | 41.95 | kPa | 251.03 | Calculated Property |
| Pvap | 48.39 | kPa | 254.00 | Calculated Property |
| Pvap | 55.58 | kPa | 256.97 | Calculated Property |
| Pvap | 63.58 | kPa | 259.94 | Calculated Property |
| Pvap | [16.63; 93.80] | kPa | [233.27; 269.24] |
NIST
|
| Equation | ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K | |||
| Coefficient A | 1.41436e+01 | |||
| Coefficient B | -2.26249e+03 | |||
| Coefficient C | -3.36240e+01 | |||
| Reference | Brown and Mears, 1958 | |||
| Comment | Coefficents calculated by NIST from author's data. | |||
| Temperature range, min. | 233.27 | |||
| Temperature range, max. | 269.24 | |||
| Pvap | 16.63 | kPa | 233.27 | Calculated Property |
| Pvap | 20.77 | kPa | 237.27 | Calculated Property |
| Pvap | 25.72 | kPa | 241.26 | Calculated Property |
| Pvap | 31.60 | kPa | 245.26 | Calculated Property |
| Pvap | 38.52 | kPa | 249.26 | Calculated Property |
| Pvap | 46.63 | kPa | 253.25 | Calculated Property |
| Pvap | 56.06 | kPa | 257.25 | Calculated Property |
| Pvap | 66.95 | kPa | 261.25 | Calculated Property |
| Pvap | 79.48 | kPa | 265.24 | Calculated Property |
| Pvap | 93.80 | kPa | 269.24 | Calculated Property |
| Pvap | [16.13; 63.58] | kPa | [233.22; 259.94] |
NIST
|
| Equation | ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K | |||
| Coefficient A | 1.33351e+01 | |||
| Coefficient B | -1.88825e+03 | |||
| Coefficient C | -5.43110e+01 | |||
| Reference | Simons and Mausteller, 1952 | |||
| Comment | Coefficents calculated by NIST from author's data. | |||
| Temperature range, min. | 233.22 | |||
| Temperature range, max. | 259.94 | |||
| Pvap | 16.13 | kPa | 233.22 | Calculated Property |
| Pvap | 19.17 | kPa | 236.19 | Calculated Property |
| Pvap | 22.64 | kPa | 239.16 | Calculated Property |
| Pvap | 26.61 | kPa | 242.13 | Calculated Property |
| Pvap | 31.12 | kPa | 245.10 | Calculated Property |
| Pvap | 36.21 | kPa | 248.06 | Calculated Property |
| Pvap | 41.95 | kPa | 251.03 | Calculated Property |
| Pvap | 48.39 | kPa | 254.00 | Calculated Property |
| Pvap | 55.58 | kPa | 256.97 | Calculated Property |
| Pvap | 63.58 | kPa | 259.94 | Calculated Property |
Similar Compounds
Find more compounds similar to Butane, decafluoro-.
Mixtures
- Carbon dioxide + Butane, decafluoro-
- Butane, decafluoro- + Dimethyl ether
- Propane + Butane, decafluoro-
- 1-Butene + Butane, decafluoro-
- Butane, decafluoro- + Ethylene
- Butane, decafluoro- + 1,1,1,3,3-pentafluorobutane
- Butane, decafluoro- + Perfluoropropane
- Butane, decafluoro- + Ethane
- Methane + Butane, decafluoro-
- Butane, decafluoro- + Hydrogen sulfide
- Carbon monoxide + Butane, decafluoro-
- Nitric oxide + Butane, decafluoro-
Sources
- KDB Vapor Pressure Data
- Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) ChEDL chemicals 1.5.2, from Bradley, J.-C.; Williams, A.; Lang, A. Jean-Claude Bradley Open Melting Point Dataset. Figshare, 2014 (CC0).
- IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 10 ChEDL chemicals 1.5.2, from Marsh, K. N.; Abramson, A.; Ambrose, D.; Morton, D. W.; Nikitin, E.; Tsonopoulos, C.; Young, C. L. Vapor-Liquid Critical Properties of Elements and Compounds. 10. Organic Compounds Containing Halogens. J. Chem. Eng. Data 2007, 52, 1509-1538.
- PSRK revision IV (2005), critical constants and acentric factors of 1000 components ChEDL chemicals 1.5.2, from Horstmann, S.; Jabłoniec, A.; Krafczyk, J.; Fischer, K.; Gmehling, J. PSRK Group Contribution Equation of State: Comprehensive Revision and Extension IV, Including Critical Constants and α-Function Parameters for 1000 Components. Fluid Phase Equilib. 2005, 227, 157-164.
- Staveley, Lobo and Calado (1981), triple points ChEDL chemicals 1.5.2, from Staveley, L. A. K.; Lobo, L. Q.; Calado, J. C. G. Triple-Points of Low Melting Substances and Their Use in Cryogenic Work. Cryogenics 1981, 21, 131-144.
- Cheméo Relay (1.0)
- Crippen Method
- Crippen Method
- Properties of saturated fluorocarbons: Experimental data and modeling using perturbed-chain-SAFT
- Isothermal vapor-liquid equilibrium data for the carbon dioxide (R744) + decafluorobutane (R610) system at temperatures from 263 to 353K
- Vapor-liquid equilibrium data for the dimethyl ether (RE170) + decafluorobutane (R3-1-10) system at temperatures from 313.28 to 392.83 K and pressures up to 4.9 MPa
- Vapor-liquid equilibria of ethylene (C2H4) + decafluorobutane (C4F10) at 268 to 298 K from experiment, molecular simulation and the Peng-Robinson equation of state
- Isothermal vapor liquid equilibrium data for the decafluorobutane(R3110) + 1,1,1,3,3-pentafluorobutane (R365mfc) system attemperatures from 333 K to 441 K
- Experimental (vapour + liquid) equilibrium data and modelling for binary mixtures of decafluorobutane with propane and 1-butene
- Isothermal Vapor-Liquid Equilibrium Data for the Perfluorobutane (R610) + Ethane System at Temperatures from (263 to 353) K
- Vapor Liquid Equilibrium (VLE) Data and Thermodynamic Modeling for Binary Systems Containing Perfluorobutane (R610) with Carbon Monoxide or Nitric Oxide at (293, 313, and 333) K
- Isothermal Vapor Liquid Equilibrium Data and Thermodynamic Modeling for Binary Systems of Perfluorobutane (R610) + (Methane or Hydrogen Sulfide) at (293, 313, and 333) K
- Joback Method
- KDB
- McGowan Method
- NIST Webbook
- The Yaws Handbook of Vapor Pressure
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