Chemical Properties of d-Mannose (CAS 3458-28-4)

InChI

InChI=1S/C6H12O6/c7-1-3(9)5(11)6(12)4(10)2-8/h1,3-6,8-12H,2H2/t3-,4-,5-,6-/m1/s1

InChI Key

GZCGUPFRVQAUEE-KVTDHHQDSA-N

Formula

C6H12O6

SMILES

O=CC(O)C(O)C(O)C(O)CO

Molecular Weight¹

180.16

CAS

3458-28-4

Other Names

• Carubinose
• D-(+)-mannose (mixture of anomers)
• Mannose
• Mannose, d-
• Seminose
• d(+)-Mannose

• Δ_cH°_solid : Standard solid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,solid : Solid phase heat capacity (J/mol×K).
• η : Dynamic viscosity (Pa×s).
• Δ_fH°_solid : Solid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• T_boil : Normal Boiling Point Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ΔcH°solid	[-2813.00; -2812.67]	kJ/mol
ΔcH°solid	-2812.67 ± 0.93	kJ/mol	NIST
ΔcH°solid	-2813.00 ± 3.40	kJ/mol	NIST
ΔfH°solid	-1263.40 ± 1.20	kJ/mol	NIST
ΔfusH°	19.93	kJ/mol	Joback Calculated Property
ΔvapH°	117.40	kJ/mol	Relay (1.0) Calculated Property
log10WS	0.76		Relay (1.0) Calculated Property
logPoct/wat	-3.379		Crippen Calculated Property
McVol	126.320	ml/mol	McGowan Calculated Property
Tboil	622.14	K	Relay (1.0) Calculated Property
Tfus	399.99	K	Relay (1.0) Calculated Property

Cheméo can also estimate Critical Temperature, Critical Pressure, Critical Volume, Enthalpy of formation at standard conditions, Standard Gibbs free energy of formation, Acentric Factor, Ionization energy for this compound, but they fall outside the models' validated range, so they are not shown here. Open the prediction tool to compute them on demand.

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,solid	[188.70; 260.20]	J/mol×K	[288.15; 358.15]
Cp,solid	188.70	J/mol×K	288.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	200.70	J/mol×K	293.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	206.60	J/mol×K	298.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	214.20	J/mol×K	300.00	NIST
Cp,solid	216.00	J/mol×K	303.00	NIST
Cp,solid	215.00	J/mol×K	303.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	223.30	J/mol×K	308.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	228.20	J/mol×K	313.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	231.60	J/mol×K	318.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	234.50	J/mol×K	323.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	236.50	J/mol×K	328.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	242.10	J/mol×K	333.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	245.20	J/mol×K	338.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	249.00	J/mol×K	343.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	252.40	J/mol×K	348.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	254.10	J/mol×K	353.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
Cp,solid	260.20	J/mol×K	358.15	Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[198.92; 415.16]	J/mol×K	[273.00; 1000.00]	Joback Predicted correlation
Equation			Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is Cp,gas in J/mol×K, T in K
Coefficient A			2.85610e+01
Coefficient B			7.41900e-01
Coefficient C			-4.60400e-04
Coefficient D			1.05100e-07
Coefficient E			0.00000e+00
Temperature range, min.			273.00
Temperature range, max.			1000.00
Cp,gas	198.92	J/mol×K	273.00	Calculated Property
Cp,gas	238.06	J/mol×K	353.78	Calculated Property
Cp,gas	272.64	J/mol×K	434.56	Calculated Property
Cp,gas	303.00	J/mol×K	515.33	Calculated Property
Cp,gas	329.48	J/mol×K	596.11	Calculated Property
Cp,gas	352.39	J/mol×K	676.89	Calculated Property
Cp,gas	372.09	J/mol×K	757.67	Calculated Property
Cp,gas	388.89	J/mol×K	838.44	Calculated Property
Cp,gas	403.14	J/mol×K	919.22	Calculated Property
Cp,gas	415.16	J/mol×K	1000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
η	[0.0017994; 0.0000003]	Pa×s	[443.48; 723.98]	Joback Predicted correlation
Equation			Y = exp(A + B/T + C·ln(T) + D·T^E) Y is η in Pa×s, T in K
Coefficient A			-2.84572e+01
Coefficient B			9.81726e+03
Coefficient C			0.00000e+00
Coefficient D			0.00000e+00
Coefficient E			0.00000e+00
Comment			Liquid phase. Joback/Reid (1987), valid from Tf to 0.7·Tc.
Temperature range, min.			443.48
Temperature range, max.			723.98
η	0.0017994	Pa×s	443.48	Calculated Property
η	0.0004206	Pa×s	474.65	Calculated Property
η	0.0001176	Pa×s	505.81	Calculated Property
η	0.0000381	Pa×s	536.98	Calculated Property
η	0.0000140	Pa×s	568.15	Calculated Property
η	0.0000057	Pa×s	599.32	Calculated Property
η	0.0000025	Pa×s	630.48	Calculated Property
η	0.0000012	Pa×s	661.65	Calculated Property
η	0.0000006	Pa×s	692.82	Calculated Property
η	0.0000003	Pa×s	723.98	Calculated Property

Similar Compounds

Find more compounds similar to d-Mannose.

Mixtures

• d-Mannose + Glycine + Water
• D-Alanine + d-Mannose + Water
• D-Valine + d-Mannose + Water
• d-Mannose + allo-L-isoleucine + Water
• d-Mannose + Water
• Magnesium chloride + d-Mannose + Water
• d-Mannose + L-Asparagine + Water
• d-Mannose + L-Glutamine + Water
• potassium chloride + d-Mannose + Water
• d-Mannose + Tetrahydrofuran + Water
• d-Mannose + Water + Acetic acid, sodium salt, hydrate (1:1:3)
• d-Mannose + Lithium chloride + Water
• Potassium phosphate, monobasic + d-Mannose + Water
• d-Mannose + Ethanol
• d-Mannose + Ethanol + Water
• d-Mannose + Water + Ammonium bromide
• d-Mannose + Water + Sodium borate

Sources

• Cheméo Relay (1.0)
• Cheméo Relay (1.0, beta) Beta: served but experimental, data-limited and below our cross-validation release bar; the Joback value is recommended where available.
• Crippen Method
• Crippen Method
• Modulation in physico-chemical characteristics of some polyhydroxy solutes in presence of L-glycine: Volumetric and NMR spectroscopic approach
• Osmotic properties of carbohydrate aqueous solutions
• Novel phase diagrams of aqueous two-phase systems based on tetrahydrofuran + carbohydrates + water: equilibrium data and partitioning experiments
• Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides
• Studies on volumetric properties of some saccharides in aqueous potassium chloride solutions over temperature range (288.15 to 318.15) K
• Effect of sodium acetate on the volumetric behaviour of some mono-, di-, and tri-saccharides in aqueous solutions over temperature range (288.15 to 318.15) K
• Viscometric studies on saccharides in aqueous magnesium chloride solutions at T = (288.15 to 318.15) K
• Physicochemical study of (solute + solute) and (solute + solvent) interactions of L-asparagine and L-glutamine in aqueous-D-mannose solutions at temperatures from (293.15 to 318.15) K
• Physicochemical study of solute-solute and solute-solvent interactions of glycine, L-alanine, L-valine and L-isoleucine in aqueous-D-mannose solutions at temperatures from 293.15 K to 318.15 K
• Rheological and time domain 1H NMR relaxation studies of some polyhydroxy solutes in presence of L-glycine
• Soluting-out effect of carbohydrates on the surface active ionic liquid 1-decyl-3-methylimidazolium bromide in aqueous solutions
• Viscosities of Some Saccharides in Aqueous Solutions of Phosphate-Based Inorganic Salts
• Infinite Dilution Binary Diffusion Coefficients for Six Sugars at 0.1 MPa and Temperatures from (273.2 to 353.2) K
• Solubility of Xylose, Mannose, Maltose Monohydrate, and Trehalose Dihydrate in Ethanol Water Solutions
• Volumetric and Viscometric Studies on Saccharide-Disodium Tetraborate (Borax) Interactions in Aqueous Solutions
• Studies on the Interactions of Saccharides and Methyl Glycosides with Lithium Chloride in Aqueous Solutions at (288.15 to 318.15) K
• Influence of NH4Br on Solvation Behavior of Polyhydroxy Solutes in Aqueous Solutions at Different Temperatures and Atmospheric Pressure
• Joback Method
• McGowan Method
• NIST Webbook

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